A Diagnostic Method for a Multi-Connected PEM-type Electrolysis System by Current Sweeping

Water electrolysis is a power-to-gas technology that can be used to decrease the effect of global warming. To reduce its overall cost, we have designed a water electrolysis system containing serially connected water electrolyzers that reduce the site area and increase energy efficiency. One of the i...

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Main Authors: Jiachen GE, Shinji FUJITA, Akira GUNJI, Motoyuki HIROOKA, Masatoshi SUGIMASA, Hiromu KAKUYA
Format: Article
Language:English
Published: The Electrochemical Society of Japan 2025-01-01
Series:Electrochemistry
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Online Access:https://www.jstage.jst.go.jp/article/electrochemistry/93/1/93_24-00107/_html/-char/en
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author Jiachen GE
Shinji FUJITA
Akira GUNJI
Motoyuki HIROOKA
Masatoshi SUGIMASA
Hiromu KAKUYA
author_facet Jiachen GE
Shinji FUJITA
Akira GUNJI
Motoyuki HIROOKA
Masatoshi SUGIMASA
Hiromu KAKUYA
author_sort Jiachen GE
collection DOAJ
description Water electrolysis is a power-to-gas technology that can be used to decrease the effect of global warming. To reduce its overall cost, we have designed a water electrolysis system containing serially connected water electrolyzers that reduce the site area and increase energy efficiency. One of the issues remaining to be solved is to develop a method that can diagnose the degradation state of the water electrolyzer during operation without significantly changing the current supply. In this study, a diagnostic method, named the sweep method, was developed. A typical procedure of this method is described as follows. A linear sweeping current is applied to the multi-connected water electrolysis system. Then, swept current and response voltage measurements are collected and subjected to linear and nonlinear regression based on an equivalent circuit, -R0-(R1, C1)-, to obtain its circuit parameters. The electrical resistance R0 is elected as the evaluation criteria of the degradation, and the diagnostic results of sweep method are found to be close to those of an impedance analysis. As the method can be conducted without a significant current change, we believe that it can be applied to a large-scale water electrolysis system.
format Article
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institution Kabale University
issn 2186-2451
language English
publishDate 2025-01-01
publisher The Electrochemical Society of Japan
record_format Article
series Electrochemistry
spelling doaj-art-a78244632f4e4f5a9a452b1a84e762632025-01-23T01:11:02ZengThe Electrochemical Society of JapanElectrochemistry2186-24512025-01-0193101700201700210.5796/electrochemistry.24-00107electrochemistryA Diagnostic Method for a Multi-Connected PEM-type Electrolysis System by Current SweepingJiachen GE0https://orcid.org/0009-0001-6042-2032Shinji FUJITA1Akira GUNJI2Motoyuki HIROOKA3Masatoshi SUGIMASA4Hiromu KAKUYA5Environmental Systems Research Department, Decarbonized Energy Innovation Center, Center for Sustainability, R&D Group, Hitachi, Ltd.Environmental Systems Research Department, Decarbonized Energy Innovation Center, Center for Sustainability, R&D Group, Hitachi, Ltd.Environmental Systems Research Department, Decarbonized Energy Innovation Center, Center for Sustainability, R&D Group, Hitachi, Ltd.Environmental Systems Research Department, Decarbonized Energy Innovation Center, Center for Sustainability, R&D Group, Hitachi, Ltd.Environmental Systems Research Department, Decarbonized Energy Innovation Center, Center for Sustainability, R&D Group, Hitachi, Ltd.Environmental Systems Research Department, Decarbonized Energy Innovation Center, Center for Sustainability, R&D Group, Hitachi, Ltd.Water electrolysis is a power-to-gas technology that can be used to decrease the effect of global warming. To reduce its overall cost, we have designed a water electrolysis system containing serially connected water electrolyzers that reduce the site area and increase energy efficiency. One of the issues remaining to be solved is to develop a method that can diagnose the degradation state of the water electrolyzer during operation without significantly changing the current supply. In this study, a diagnostic method, named the sweep method, was developed. A typical procedure of this method is described as follows. A linear sweeping current is applied to the multi-connected water electrolysis system. Then, swept current and response voltage measurements are collected and subjected to linear and nonlinear regression based on an equivalent circuit, -R0-(R1, C1)-, to obtain its circuit parameters. The electrical resistance R0 is elected as the evaluation criteria of the degradation, and the diagnostic results of sweep method are found to be close to those of an impedance analysis. As the method can be conducted without a significant current change, we believe that it can be applied to a large-scale water electrolysis system.https://www.jstage.jst.go.jp/article/electrochemistry/93/1/93_24-00107/_html/-char/enpolymer electrolyte membranemulti-connected water electrolysis systemdiagnostic method
spellingShingle Jiachen GE
Shinji FUJITA
Akira GUNJI
Motoyuki HIROOKA
Masatoshi SUGIMASA
Hiromu KAKUYA
A Diagnostic Method for a Multi-Connected PEM-type Electrolysis System by Current Sweeping
Electrochemistry
polymer electrolyte membrane
multi-connected water electrolysis system
diagnostic method
title A Diagnostic Method for a Multi-Connected PEM-type Electrolysis System by Current Sweeping
title_full A Diagnostic Method for a Multi-Connected PEM-type Electrolysis System by Current Sweeping
title_fullStr A Diagnostic Method for a Multi-Connected PEM-type Electrolysis System by Current Sweeping
title_full_unstemmed A Diagnostic Method for a Multi-Connected PEM-type Electrolysis System by Current Sweeping
title_short A Diagnostic Method for a Multi-Connected PEM-type Electrolysis System by Current Sweeping
title_sort diagnostic method for a multi connected pem type electrolysis system by current sweeping
topic polymer electrolyte membrane
multi-connected water electrolysis system
diagnostic method
url https://www.jstage.jst.go.jp/article/electrochemistry/93/1/93_24-00107/_html/-char/en
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