Effect of Thickness on Structural, Morphological, and Optical Properties for Nanocrystalline Thin Films of Cd1-xSnxS, for Optoelectronic Applications

Thin films of Sn1-xCdxS nanocrystals (X=0,0.7, and 1) with different thicknesses  200, 300, and 400  nm were prepared on glass bases at 300  C by the participation method and chemical spray pyrolysis method (CSP).  The effect of the concentration of Sn and thickness on the structural and optical pr...

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Main Author: Lamia K. Abbas
Format: Article
Language:English
Published: University of Baghdad, College of Science for Women 2024-08-01
Series:مجلة بغداد للعلوم
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Online Access:https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/10113
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author Lamia K. Abbas
author_facet Lamia K. Abbas
author_sort Lamia K. Abbas
collection DOAJ
description Thin films of Sn1-xCdxS nanocrystals (X=0,0.7, and 1) with different thicknesses  200, 300, and 400  nm were prepared on glass bases at 300  C by the participation method and chemical spray pyrolysis method (CSP).  The effect of the concentration of Sn and thickness on the structural and optical properties of the prepared films was studied. The films were characterized to evaluate the structure, transmittance, and optical energy band gap. X-ray diffraction (XRD) studies showed that the films were polycrystalline with hexagonal and orthogonal structures. XRD and atomic force measurement results showed that the grain size increases with its thickness. The optical band gap energies and optical transmission and absorption types of the membranes were determined from the optical transmittance spectra. Optical absorption studies in the wavelength range  200-1100 nm  showed that the energy gap values of the films decrease from  2.48-1.95 eV,  2.41-1.92 eV, and  2.3- 1,89 eV with increasing Sn concentration and with increase the thickness  200, 300, and 400 nm respectively. The best properties of the prepared material were determined for its possible use in the manufacture of solar cells.
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series مجلة بغداد للعلوم
spelling doaj-art-a768fbc6c03345ef8267042a859bbecb2025-08-20T03:35:53ZengUniversity of Baghdad, College of Science for Womenمجلة بغداد للعلوم2078-86652411-79862024-08-0121810.21123/bsj.2024.10113Effect of Thickness on Structural, Morphological, and Optical Properties for Nanocrystalline Thin Films of Cd1-xSnxS, for Optoelectronic ApplicationsLamia K. Abbas0Department of Physics, College of science, University of Baghdad, Baghdad, Iraq. Thin films of Sn1-xCdxS nanocrystals (X=0,0.7, and 1) with different thicknesses  200, 300, and 400  nm were prepared on glass bases at 300  C by the participation method and chemical spray pyrolysis method (CSP).  The effect of the concentration of Sn and thickness on the structural and optical properties of the prepared films was studied. The films were characterized to evaluate the structure, transmittance, and optical energy band gap. X-ray diffraction (XRD) studies showed that the films were polycrystalline with hexagonal and orthogonal structures. XRD and atomic force measurement results showed that the grain size increases with its thickness. The optical band gap energies and optical transmission and absorption types of the membranes were determined from the optical transmittance spectra. Optical absorption studies in the wavelength range  200-1100 nm  showed that the energy gap values of the films decrease from  2.48-1.95 eV,  2.41-1.92 eV, and  2.3- 1,89 eV with increasing Sn concentration and with increase the thickness  200, 300, and 400 nm respectively. The best properties of the prepared material were determined for its possible use in the manufacture of solar cells. https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/10113Cd1-xSnxS nanocrystallain, CdS nanoparticle, Chemical spray pyrolysis, Sn, Thin films
spellingShingle Lamia K. Abbas
Effect of Thickness on Structural, Morphological, and Optical Properties for Nanocrystalline Thin Films of Cd1-xSnxS, for Optoelectronic Applications
مجلة بغداد للعلوم
Cd1-xSnxS nanocrystallain, CdS nanoparticle, Chemical spray pyrolysis, Sn, Thin films
title Effect of Thickness on Structural, Morphological, and Optical Properties for Nanocrystalline Thin Films of Cd1-xSnxS, for Optoelectronic Applications
title_full Effect of Thickness on Structural, Morphological, and Optical Properties for Nanocrystalline Thin Films of Cd1-xSnxS, for Optoelectronic Applications
title_fullStr Effect of Thickness on Structural, Morphological, and Optical Properties for Nanocrystalline Thin Films of Cd1-xSnxS, for Optoelectronic Applications
title_full_unstemmed Effect of Thickness on Structural, Morphological, and Optical Properties for Nanocrystalline Thin Films of Cd1-xSnxS, for Optoelectronic Applications
title_short Effect of Thickness on Structural, Morphological, and Optical Properties for Nanocrystalline Thin Films of Cd1-xSnxS, for Optoelectronic Applications
title_sort effect of thickness on structural morphological and optical properties for nanocrystalline thin films of cd1 xsnxs for optoelectronic applications
topic Cd1-xSnxS nanocrystallain, CdS nanoparticle, Chemical spray pyrolysis, Sn, Thin films
url https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/10113
work_keys_str_mv AT lamiakabbas effectofthicknessonstructuralmorphologicalandopticalpropertiesfornanocrystallinethinfilmsofcd1xsnxsforoptoelectronicapplications