The Natural Anthraquinone Parietin Inactivates <i>Candida tropicalis</i> Biofilm by Photodynamic Mechanisms

<b>Background/Objectives</b>: Parietin (PTN), a blue-light absorbing pigment from <i>Teloschistes</i> spp. lichens, exhibit photosensitizing properties via Type I (superoxide anion, O<sub>2</sub><sup>•−</sup>) and Type II (singlet oxygen, <sup>1&...

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Main Authors: Juliana Marioni, Bianca C. Romero, Ma. Laura Mugas, Florencia Martinez, Tomas I. Gómez, Jesús M. N. Morales, Brenda S. Konigheim, Claudio D. Borsarelli, Susana C. Nuñez-Montoya
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Language:English
Published: MDPI AG 2025-04-01
Series:Pharmaceutics
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Online Access:https://www.mdpi.com/1999-4923/17/5/548
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author Juliana Marioni
Bianca C. Romero
Ma. Laura Mugas
Florencia Martinez
Tomas I. Gómez
Jesús M. N. Morales
Brenda S. Konigheim
Claudio D. Borsarelli
Susana C. Nuñez-Montoya
author_facet Juliana Marioni
Bianca C. Romero
Ma. Laura Mugas
Florencia Martinez
Tomas I. Gómez
Jesús M. N. Morales
Brenda S. Konigheim
Claudio D. Borsarelli
Susana C. Nuñez-Montoya
author_sort Juliana Marioni
collection DOAJ
description <b>Background/Objectives</b>: Parietin (PTN), a blue-light absorbing pigment from <i>Teloschistes</i> spp. lichens, exhibit photosensitizing properties via Type I (superoxide anion, O<sub>2</sub><sup>•−</sup>) and Type II (singlet oxygen, <sup>1</sup>O<sub>2</sub>) mechanisms, inactivating bacteria in vitro after photoexcitation. We evaluate the in vitro antifungal activity of PTN against <i>Candida tropicalis</i> biofilms under actinic irradiation, its role in O<sub>2</sub><sup>•−</sup> and <sup>1</sup>O<sub>2</sub> production, and the cellular stress response. <b>Methods</b>: Minimum inhibitory concentration (MIC) of PTN was determined in <i>C. tropicalis</i> NCPF 3111 under dark and actinic light conditions. Biofilm susceptibility was assessed at MIC/2, MIC, MICx2, MICx4, and MICx6 in the same conditions, and viability was measured by colony-forming units. Photodynamic mechanisms were examined using Tiron (O<sub>2</sub><sup>•−</sup> scavenger) or sodium azide (<sup>1</sup>O<sub>2</sub> quencher). O<sub>2</sub><sup>•−</sup> production was measured by the nitro-blue tetrazolium (NBT) reduction and nitric oxide (NO) generation by Griess assay. Total antioxidant capacity was studied by FRAP (Ferrous Reduction Antioxidant Potency) assay and superoxide dismutase (SOD) activity by NBT assay. <b>Results</b>: Photoexcitation of PTN reduced <i>C. tropicalis</i> biofilm viability by four logs at MICx2. Sodium azide partially reversed the effect, whereas Tiron fully inhibited it, indicating the critical role of O<sub>2</sub><sup>•−</sup>. PTN also increased O<sub>2</sub><sup>•−</sup> and NO levels, enhancing SOD activity and FRAP. However, this antioxidant response was insufficient to prevent biofilm photoinactivation. <b>Conclusions</b>: Photoinactivation of <i>C. tropicalis</i> biofilms by PTN is primarily mediated by O<sub>2</sub><sup>•−</sup>, with a minor contribution from <sup>1</sup>O<sub>2</sub> and an imbalance in NO levels. These findings suggest PTN is a promising photosensitizer for antifungal photodynamic therapy.
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spelling doaj-art-a6ffd4c49df9456db147dfa5762a406e2025-08-20T03:14:35ZengMDPI AGPharmaceutics1999-49232025-04-0117554810.3390/pharmaceutics17050548The Natural Anthraquinone Parietin Inactivates <i>Candida tropicalis</i> Biofilm by Photodynamic MechanismsJuliana Marioni0Bianca C. Romero1Ma. Laura Mugas2Florencia Martinez3Tomas I. Gómez4Jesús M. N. Morales5Brenda S. Konigheim6Claudio D. Borsarelli7Susana C. Nuñez-Montoya8Departamento de Ciencias Farmacéuticas, Facultad de Ciencias Químicas, Universidad Nacional de Córdoba, Haya de la Torre y Medina Allende, Ciudad Universitaria, Córdoba X5000HUA, ArgentinaDepartamento de Ciencias Farmacéuticas, Facultad de Ciencias Químicas, Universidad Nacional de Córdoba, Haya de la Torre y Medina Allende, Ciudad Universitaria, Córdoba X5000HUA, ArgentinaDepartamento de Ciencias Farmacéuticas, Facultad de Ciencias Químicas, Universidad Nacional de Córdoba, Haya de la Torre y Medina Allende, Ciudad Universitaria, Córdoba X5000HUA, ArgentinaInstituto de Virología “Dr. J. M. Vanella”, Facultad de Ciencias Médicas, Universidad Nacional de Córdoba, Córdoba X5000HUA, ArgentinaDepartamento de Ciencias Farmacéuticas, Facultad de Ciencias Químicas, Universidad Nacional de Córdoba, Haya de la Torre y Medina Allende, Ciudad Universitaria, Córdoba X5000HUA, ArgentinaInstituto de Bionanotecnología del NOA (INBIONATEC), Universidad Nacional de Santiago del Estero—CONICET, RN9, Km 1125, Santiago del Estero G4206XCP, ArgentinaInstituto de Virología “Dr. J. M. Vanella”, Facultad de Ciencias Médicas, Universidad Nacional de Córdoba, Córdoba X5000HUA, ArgentinaInstituto de Bionanotecnología del NOA (INBIONATEC), Universidad Nacional de Santiago del Estero—CONICET, RN9, Km 1125, Santiago del Estero G4206XCP, ArgentinaDepartamento de Ciencias Farmacéuticas, Facultad de Ciencias Químicas, Universidad Nacional de Córdoba, Haya de la Torre y Medina Allende, Ciudad Universitaria, Córdoba X5000HUA, Argentina<b>Background/Objectives</b>: Parietin (PTN), a blue-light absorbing pigment from <i>Teloschistes</i> spp. lichens, exhibit photosensitizing properties via Type I (superoxide anion, O<sub>2</sub><sup>•−</sup>) and Type II (singlet oxygen, <sup>1</sup>O<sub>2</sub>) mechanisms, inactivating bacteria in vitro after photoexcitation. We evaluate the in vitro antifungal activity of PTN against <i>Candida tropicalis</i> biofilms under actinic irradiation, its role in O<sub>2</sub><sup>•−</sup> and <sup>1</sup>O<sub>2</sub> production, and the cellular stress response. <b>Methods</b>: Minimum inhibitory concentration (MIC) of PTN was determined in <i>C. tropicalis</i> NCPF 3111 under dark and actinic light conditions. Biofilm susceptibility was assessed at MIC/2, MIC, MICx2, MICx4, and MICx6 in the same conditions, and viability was measured by colony-forming units. Photodynamic mechanisms were examined using Tiron (O<sub>2</sub><sup>•−</sup> scavenger) or sodium azide (<sup>1</sup>O<sub>2</sub> quencher). O<sub>2</sub><sup>•−</sup> production was measured by the nitro-blue tetrazolium (NBT) reduction and nitric oxide (NO) generation by Griess assay. Total antioxidant capacity was studied by FRAP (Ferrous Reduction Antioxidant Potency) assay and superoxide dismutase (SOD) activity by NBT assay. <b>Results</b>: Photoexcitation of PTN reduced <i>C. tropicalis</i> biofilm viability by four logs at MICx2. Sodium azide partially reversed the effect, whereas Tiron fully inhibited it, indicating the critical role of O<sub>2</sub><sup>•−</sup>. PTN also increased O<sub>2</sub><sup>•−</sup> and NO levels, enhancing SOD activity and FRAP. However, this antioxidant response was insufficient to prevent biofilm photoinactivation. <b>Conclusions</b>: Photoinactivation of <i>C. tropicalis</i> biofilms by PTN is primarily mediated by O<sub>2</sub><sup>•−</sup>, with a minor contribution from <sup>1</sup>O<sub>2</sub> and an imbalance in NO levels. These findings suggest PTN is a promising photosensitizer for antifungal photodynamic therapy.https://www.mdpi.com/1999-4923/17/5/548natural anthraquinonesuperoxide anionsinglet oxygen<i>Candida</i> biofilmphotodynamic therapyphotoinactivation
spellingShingle Juliana Marioni
Bianca C. Romero
Ma. Laura Mugas
Florencia Martinez
Tomas I. Gómez
Jesús M. N. Morales
Brenda S. Konigheim
Claudio D. Borsarelli
Susana C. Nuñez-Montoya
The Natural Anthraquinone Parietin Inactivates <i>Candida tropicalis</i> Biofilm by Photodynamic Mechanisms
Pharmaceutics
natural anthraquinone
superoxide anion
singlet oxygen
<i>Candida</i> biofilm
photodynamic therapy
photoinactivation
title The Natural Anthraquinone Parietin Inactivates <i>Candida tropicalis</i> Biofilm by Photodynamic Mechanisms
title_full The Natural Anthraquinone Parietin Inactivates <i>Candida tropicalis</i> Biofilm by Photodynamic Mechanisms
title_fullStr The Natural Anthraquinone Parietin Inactivates <i>Candida tropicalis</i> Biofilm by Photodynamic Mechanisms
title_full_unstemmed The Natural Anthraquinone Parietin Inactivates <i>Candida tropicalis</i> Biofilm by Photodynamic Mechanisms
title_short The Natural Anthraquinone Parietin Inactivates <i>Candida tropicalis</i> Biofilm by Photodynamic Mechanisms
title_sort natural anthraquinone parietin inactivates i candida tropicalis i biofilm by photodynamic mechanisms
topic natural anthraquinone
superoxide anion
singlet oxygen
<i>Candida</i> biofilm
photodynamic therapy
photoinactivation
url https://www.mdpi.com/1999-4923/17/5/548
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