Zero emission heating with calcium oxide and water: development and demonstration of first pilot scale thermochemical heating system for buildings

Heat supply for residential buildings is still mainly based on fossil fuels and is thus a significant contributor to CO2 emissions. Renewable heating remains a technological challenge, often for the reason that during cold weather periods heat demand increases drastically whereas renewable productio...

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Main Authors: Matthias Schmidt, Venizelos Sourmelis, Viktor Kühl, Marc Linder
Format: Article
Language:English
Published: Frontiers Media S.A. 2025-06-01
Series:Frontiers in Energy Research
Subjects:
Online Access:https://www.frontiersin.org/articles/10.3389/fenrg.2025.1617554/full
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author Matthias Schmidt
Venizelos Sourmelis
Viktor Kühl
Marc Linder
author_facet Matthias Schmidt
Venizelos Sourmelis
Viktor Kühl
Marc Linder
author_sort Matthias Schmidt
collection DOAJ
description Heat supply for residential buildings is still mainly based on fossil fuels and is thus a significant contributor to CO2 emissions. Renewable heating remains a technological challenge, often for the reason that during cold weather periods heat demand increases drastically whereas renewable production minimizes. Reactive solids produced by renewable energy can be an energy storage and carrier to flexibly leverage the often extreme seasonal discrepancy of residential heat demand. This work demonstrates a fully integrated thermochemical heating system based on calcium oxide and water operational for the first time in a real building environment. With the extraction of the thermochemically stored energy at a temperature level of 60°C we proved that the technology can be integrated into existing heating infrastructures of buildings, by replacing fossil fuel-based burners. This work advances the technology readiness level of thermochemical energy storage to validation in relevant environment.
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institution Kabale University
issn 2296-598X
language English
publishDate 2025-06-01
publisher Frontiers Media S.A.
record_format Article
series Frontiers in Energy Research
spelling doaj-art-a609d464703c4d24a905fb16cf5be9562025-08-20T03:32:37ZengFrontiers Media S.A.Frontiers in Energy Research2296-598X2025-06-011310.3389/fenrg.2025.16175541617554Zero emission heating with calcium oxide and water: development and demonstration of first pilot scale thermochemical heating system for buildingsMatthias SchmidtVenizelos SourmelisViktor KühlMarc LinderHeat supply for residential buildings is still mainly based on fossil fuels and is thus a significant contributor to CO2 emissions. Renewable heating remains a technological challenge, often for the reason that during cold weather periods heat demand increases drastically whereas renewable production minimizes. Reactive solids produced by renewable energy can be an energy storage and carrier to flexibly leverage the often extreme seasonal discrepancy of residential heat demand. This work demonstrates a fully integrated thermochemical heating system based on calcium oxide and water operational for the first time in a real building environment. With the extraction of the thermochemically stored energy at a temperature level of 60°C we proved that the technology can be integrated into existing heating infrastructures of buildings, by replacing fossil fuel-based burners. This work advances the technology readiness level of thermochemical energy storage to validation in relevant environment.https://www.frontiersin.org/articles/10.3389/fenrg.2025.1617554/fullthermochemcial energy storageseasonal energy storagecalcium hydroxide (Ca(OH)2)calcium oxide (CaO)thermal energy storage (TES) systems
spellingShingle Matthias Schmidt
Venizelos Sourmelis
Viktor Kühl
Marc Linder
Zero emission heating with calcium oxide and water: development and demonstration of first pilot scale thermochemical heating system for buildings
Frontiers in Energy Research
thermochemcial energy storage
seasonal energy storage
calcium hydroxide (Ca(OH)2)
calcium oxide (CaO)
thermal energy storage (TES) systems
title Zero emission heating with calcium oxide and water: development and demonstration of first pilot scale thermochemical heating system for buildings
title_full Zero emission heating with calcium oxide and water: development and demonstration of first pilot scale thermochemical heating system for buildings
title_fullStr Zero emission heating with calcium oxide and water: development and demonstration of first pilot scale thermochemical heating system for buildings
title_full_unstemmed Zero emission heating with calcium oxide and water: development and demonstration of first pilot scale thermochemical heating system for buildings
title_short Zero emission heating with calcium oxide and water: development and demonstration of first pilot scale thermochemical heating system for buildings
title_sort zero emission heating with calcium oxide and water development and demonstration of first pilot scale thermochemical heating system for buildings
topic thermochemcial energy storage
seasonal energy storage
calcium hydroxide (Ca(OH)2)
calcium oxide (CaO)
thermal energy storage (TES) systems
url https://www.frontiersin.org/articles/10.3389/fenrg.2025.1617554/full
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AT venizelossourmelis zeroemissionheatingwithcalciumoxideandwaterdevelopmentanddemonstrationoffirstpilotscalethermochemicalheatingsystemforbuildings
AT viktorkuhl zeroemissionheatingwithcalciumoxideandwaterdevelopmentanddemonstrationoffirstpilotscalethermochemicalheatingsystemforbuildings
AT marclinder zeroemissionheatingwithcalciumoxideandwaterdevelopmentanddemonstrationoffirstpilotscalethermochemicalheatingsystemforbuildings