Efficient, One-Pot Synthesis of Tetrahydrobenzo[a]xanthen-11-ones and Dibenzo[a,j]xanthenes Using Trichloroacetic Acid as a Solid Heterogeneous Catalyst Under Solvent-Free Conditions

A simple and efficient method have been described for the synthesis of 12-aryl-8,9,10,12-tetrahydrobenzo[a]xanthen-11-one derivatives employing a one-pot, three-component reaction of aryl aldehydes, 2-naphthol and dimedone in the presence of trichloroacetic acid under solvent-free conditions. Also...

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Main Authors: Zahed Karimi Jaber, S. Zoleykha Abbasi, Baharak Pooladian, Marziyeh Jokar
Format: Article
Language:English
Published: Wiley 2011-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2011/359175
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author Zahed Karimi Jaber
S. Zoleykha Abbasi
Baharak Pooladian
Marziyeh Jokar
author_facet Zahed Karimi Jaber
S. Zoleykha Abbasi
Baharak Pooladian
Marziyeh Jokar
author_sort Zahed Karimi Jaber
collection DOAJ
description A simple and efficient method have been described for the synthesis of 12-aryl-8,9,10,12-tetrahydrobenzo[a]xanthen-11-one derivatives employing a one-pot, three-component reaction of aryl aldehydes, 2-naphthol and dimedone in the presence of trichloroacetic acid under solvent-free conditions. Also the condensation of 2-naphthol with alkyl or aryl aldehydes in the presence of trichloroacetic acid under solvent-free media to afford the corresponding 14-aryl or alkyl -14H-dibenzo [a.j]xanthenes in excellent yields and short reaction times is described.
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institution Kabale University
issn 0973-4945
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language English
publishDate 2011-01-01
publisher Wiley
record_format Article
series E-Journal of Chemistry
spelling doaj-art-a5f92c7b0c0c42c3b111fa5ba6d8223b2025-08-20T03:38:45ZengWileyE-Journal of Chemistry0973-49452090-98102011-01-01841895189910.1155/2011/359175Efficient, One-Pot Synthesis of Tetrahydrobenzo[a]xanthen-11-ones and Dibenzo[a,j]xanthenes Using Trichloroacetic Acid as a Solid Heterogeneous Catalyst Under Solvent-Free ConditionsZahed Karimi Jaber0S. Zoleykha Abbasi1Baharak Pooladian2Marziyeh Jokar3Department of Chemistry, Firoozabad Branch, Islamic Azad University, P.O. Box 74715-117 Firoozabad, Fars, IranDepartment of Chemistry, Firoozabad Branch, Islamic Azad University, P.O. Box 74715-117 Firoozabad, Fars, IranDepartment of Chemistry, Firoozabad Branch, Islamic Azad University, P.O. Box 74715-117 Firoozabad, Fars, IranDepartment of Chemistry, Firoozabad Branch, Islamic Azad University, P.O. Box 74715-117 Firoozabad, Fars, IranA simple and efficient method have been described for the synthesis of 12-aryl-8,9,10,12-tetrahydrobenzo[a]xanthen-11-one derivatives employing a one-pot, three-component reaction of aryl aldehydes, 2-naphthol and dimedone in the presence of trichloroacetic acid under solvent-free conditions. Also the condensation of 2-naphthol with alkyl or aryl aldehydes in the presence of trichloroacetic acid under solvent-free media to afford the corresponding 14-aryl or alkyl -14H-dibenzo [a.j]xanthenes in excellent yields and short reaction times is described.http://dx.doi.org/10.1155/2011/359175
spellingShingle Zahed Karimi Jaber
S. Zoleykha Abbasi
Baharak Pooladian
Marziyeh Jokar
Efficient, One-Pot Synthesis of Tetrahydrobenzo[a]xanthen-11-ones and Dibenzo[a,j]xanthenes Using Trichloroacetic Acid as a Solid Heterogeneous Catalyst Under Solvent-Free Conditions
E-Journal of Chemistry
title Efficient, One-Pot Synthesis of Tetrahydrobenzo[a]xanthen-11-ones and Dibenzo[a,j]xanthenes Using Trichloroacetic Acid as a Solid Heterogeneous Catalyst Under Solvent-Free Conditions
title_full Efficient, One-Pot Synthesis of Tetrahydrobenzo[a]xanthen-11-ones and Dibenzo[a,j]xanthenes Using Trichloroacetic Acid as a Solid Heterogeneous Catalyst Under Solvent-Free Conditions
title_fullStr Efficient, One-Pot Synthesis of Tetrahydrobenzo[a]xanthen-11-ones and Dibenzo[a,j]xanthenes Using Trichloroacetic Acid as a Solid Heterogeneous Catalyst Under Solvent-Free Conditions
title_full_unstemmed Efficient, One-Pot Synthesis of Tetrahydrobenzo[a]xanthen-11-ones and Dibenzo[a,j]xanthenes Using Trichloroacetic Acid as a Solid Heterogeneous Catalyst Under Solvent-Free Conditions
title_short Efficient, One-Pot Synthesis of Tetrahydrobenzo[a]xanthen-11-ones and Dibenzo[a,j]xanthenes Using Trichloroacetic Acid as a Solid Heterogeneous Catalyst Under Solvent-Free Conditions
title_sort efficient one pot synthesis of tetrahydrobenzo a xanthen 11 ones and dibenzo a j xanthenes using trichloroacetic acid as a solid heterogeneous catalyst under solvent free conditions
url http://dx.doi.org/10.1155/2011/359175
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