Exploring water−macromolecule interactions at the single-molecule level: A comprehensive review

Water is ubiquitous and indispensable on the Earth. Its importance has long been recognized on a macroscopic scale. However, it took a long time to comprehend the impact of water molecules on the microscopic level. According to the hydrophilicity of matter, the impact of water can be divided into tw...

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Main Authors: Yixuan Shan, Yu Bao, Shuxun Cui
Format: Article
Language:English
Published: KeAi Communications Co., Ltd. 2024-12-01
Series:Supramolecular Materials
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Online Access:http://www.sciencedirect.com/science/article/pii/S2667240523000314
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author Yixuan Shan
Yu Bao
Shuxun Cui
author_facet Yixuan Shan
Yu Bao
Shuxun Cui
author_sort Yixuan Shan
collection DOAJ
description Water is ubiquitous and indispensable on the Earth. Its importance has long been recognized on a macroscopic scale. However, it took a long time to comprehend the impact of water molecules on the microscopic level. According to the hydrophilicity of matter, the impact of water can be divided into two categories: 1) intermolecular hydrogen bonds (H-bonds) and 2) hydrophobic interactions. In recent years, atomic force microscopy (AFM)-based single-molecule force spectroscopy (SMFS) has been used to investigate the effect of water on the single-chain properties of macromolecules. Herein, we summarize recent advances in the AFM-SMFS study on the impact of water on some kinds of synthetic polymers, biomacromolecules, and molecules containing supramolecular interactions from the two aspects of H-bonds and hydrophobic interactions. It is expected that a deeper understanding of the interactions between water molecules and macromolecules will enable the design of polymer materials with specific functionalities and properties in a bottom-up way.
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issn 2667-2405
language English
publishDate 2024-12-01
publisher KeAi Communications Co., Ltd.
record_format Article
series Supramolecular Materials
spelling doaj-art-a5a20378dbcc435eb3c45ec78774e5f52025-08-20T02:52:58ZengKeAi Communications Co., Ltd.Supramolecular Materials2667-24052024-12-01310006110.1016/j.supmat.2023.100061Exploring water−macromolecule interactions at the single-molecule level: A comprehensive reviewYixuan Shan0Yu Bao1Shuxun Cui2School of Chemistry, Key Laboratory of Advanced Technologies of Materials, Ministry of Education, Southwest Jiaotong University, Chengdu 610031, ChinaCorresponding authors.; School of Chemistry, Key Laboratory of Advanced Technologies of Materials, Ministry of Education, Southwest Jiaotong University, Chengdu 610031, ChinaCorresponding authors.; School of Chemistry, Key Laboratory of Advanced Technologies of Materials, Ministry of Education, Southwest Jiaotong University, Chengdu 610031, ChinaWater is ubiquitous and indispensable on the Earth. Its importance has long been recognized on a macroscopic scale. However, it took a long time to comprehend the impact of water molecules on the microscopic level. According to the hydrophilicity of matter, the impact of water can be divided into two categories: 1) intermolecular hydrogen bonds (H-bonds) and 2) hydrophobic interactions. In recent years, atomic force microscopy (AFM)-based single-molecule force spectroscopy (SMFS) has been used to investigate the effect of water on the single-chain properties of macromolecules. Herein, we summarize recent advances in the AFM-SMFS study on the impact of water on some kinds of synthetic polymers, biomacromolecules, and molecules containing supramolecular interactions from the two aspects of H-bonds and hydrophobic interactions. It is expected that a deeper understanding of the interactions between water molecules and macromolecules will enable the design of polymer materials with specific functionalities and properties in a bottom-up way.http://www.sciencedirect.com/science/article/pii/S2667240523000314Single moleculeAFMWaterMacromoleculesInteractions
spellingShingle Yixuan Shan
Yu Bao
Shuxun Cui
Exploring water−macromolecule interactions at the single-molecule level: A comprehensive review
Supramolecular Materials
Single molecule
AFM
Water
Macromolecules
Interactions
title Exploring water−macromolecule interactions at the single-molecule level: A comprehensive review
title_full Exploring water−macromolecule interactions at the single-molecule level: A comprehensive review
title_fullStr Exploring water−macromolecule interactions at the single-molecule level: A comprehensive review
title_full_unstemmed Exploring water−macromolecule interactions at the single-molecule level: A comprehensive review
title_short Exploring water−macromolecule interactions at the single-molecule level: A comprehensive review
title_sort exploring water macromolecule interactions at the single molecule level a comprehensive review
topic Single molecule
AFM
Water
Macromolecules
Interactions
url http://www.sciencedirect.com/science/article/pii/S2667240523000314
work_keys_str_mv AT yixuanshan exploringwatermacromoleculeinteractionsatthesinglemoleculelevelacomprehensivereview
AT yubao exploringwatermacromoleculeinteractionsatthesinglemoleculelevelacomprehensivereview
AT shuxuncui exploringwatermacromoleculeinteractionsatthesinglemoleculelevelacomprehensivereview