An Impact of Cobalt on Freshwater Phytoplankton in Warming Polar Regions?

Abstract Polar freshwater ecosystems are sensitive to climate change, facing increasing temperatures and its consequences such as glacier retreat. Phosphorus and/or fixed nitrogen are widely expected to limit primary production in most freshwater environments, however the role of micronutrients is l...

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Main Authors: Kechen Zhu, Jana Krause, Camila Marín‐Arias, Mireia Mestre, Juan Höfer, Thomas J. Browning, Eric P. Achterberg, Mark J. Hopwood
Format: Article
Language:English
Published: Wiley 2024-12-01
Series:Geophysical Research Letters
Subjects:
Online Access:https://doi.org/10.1029/2024GL110065
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author Kechen Zhu
Jana Krause
Camila Marín‐Arias
Mireia Mestre
Juan Höfer
Thomas J. Browning
Eric P. Achterberg
Mark J. Hopwood
author_facet Kechen Zhu
Jana Krause
Camila Marín‐Arias
Mireia Mestre
Juan Höfer
Thomas J. Browning
Eric P. Achterberg
Mark J. Hopwood
author_sort Kechen Zhu
collection DOAJ
description Abstract Polar freshwater ecosystems are sensitive to climate change, facing increasing temperatures and its consequences such as glacier retreat. Phosphorus and/or fixed nitrogen are widely expected to limit primary production in most freshwater environments, however the role of micronutrients is largely un‐characterized. We measured dissolved nitrate and nitrite, phosphate, cobalt, iron, manganese and zinc in a selection of Greenland and Antarctic lakes, and report the first evaluation of cobalt regulating phytoplankton growth in these systems using bioassay incubations. Results showed cobalt potentially co‐limited phytoplankton in three of the eight sites tested. A time‐series of dissolved cobalt measured in Kobbefjord (southwest Greenland) runoff corroborated low cobalt availability during summer. This was in contrast to manganese and iron which remained at high concentrations throughout summer. We hypothesize that high manganese:cobalt and/or zinc:cobalt ratios in runoff, may impede cellular cobalt acquisition, meaning cobalt co‐limitation of primary production is plausible in many polar freshwater environments.
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publishDate 2024-12-01
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series Geophysical Research Letters
spelling doaj-art-a5943c8cdfb74aec8dc278ce550d65ec2025-08-20T02:33:52ZengWileyGeophysical Research Letters0094-82761944-80072024-12-015123n/an/a10.1029/2024GL110065An Impact of Cobalt on Freshwater Phytoplankton in Warming Polar Regions?Kechen Zhu0Jana Krause1Camila Marín‐Arias2Mireia Mestre3Juan Höfer4Thomas J. Browning5Eric P. Achterberg6Mark J. Hopwood7Department of Ocean Science and Engineering Southern University of Science and Technology Shenzhen ChinaGEOMAR Helmholtz Center for Ocean Research Kiel Kiel GermanyPrograma de magíster en oceanografía Escuela de Ciencias del Mar Pontificia Universidad Católica de Valparaíso Valparaíso ChileCentro FONDAP de investigación en Dinámica de Ecosistemas Marinos de Altas Latitudes (IDEAL) Valdivia ChileEscuela de Ciencias del Mar Pontificia Universidad Católica de Valparaíso Valparaíso ChileGEOMAR Helmholtz Center for Ocean Research Kiel Kiel GermanyGEOMAR Helmholtz Center for Ocean Research Kiel Kiel GermanyDepartment of Ocean Science and Engineering Southern University of Science and Technology Shenzhen ChinaAbstract Polar freshwater ecosystems are sensitive to climate change, facing increasing temperatures and its consequences such as glacier retreat. Phosphorus and/or fixed nitrogen are widely expected to limit primary production in most freshwater environments, however the role of micronutrients is largely un‐characterized. We measured dissolved nitrate and nitrite, phosphate, cobalt, iron, manganese and zinc in a selection of Greenland and Antarctic lakes, and report the first evaluation of cobalt regulating phytoplankton growth in these systems using bioassay incubations. Results showed cobalt potentially co‐limited phytoplankton in three of the eight sites tested. A time‐series of dissolved cobalt measured in Kobbefjord (southwest Greenland) runoff corroborated low cobalt availability during summer. This was in contrast to manganese and iron which remained at high concentrations throughout summer. We hypothesize that high manganese:cobalt and/or zinc:cobalt ratios in runoff, may impede cellular cobalt acquisition, meaning cobalt co‐limitation of primary production is plausible in many polar freshwater environments.https://doi.org/10.1029/2024GL110065trace metal biogeochemistrycobalt limitationglobal warming
spellingShingle Kechen Zhu
Jana Krause
Camila Marín‐Arias
Mireia Mestre
Juan Höfer
Thomas J. Browning
Eric P. Achterberg
Mark J. Hopwood
An Impact of Cobalt on Freshwater Phytoplankton in Warming Polar Regions?
Geophysical Research Letters
trace metal biogeochemistry
cobalt limitation
global warming
title An Impact of Cobalt on Freshwater Phytoplankton in Warming Polar Regions?
title_full An Impact of Cobalt on Freshwater Phytoplankton in Warming Polar Regions?
title_fullStr An Impact of Cobalt on Freshwater Phytoplankton in Warming Polar Regions?
title_full_unstemmed An Impact of Cobalt on Freshwater Phytoplankton in Warming Polar Regions?
title_short An Impact of Cobalt on Freshwater Phytoplankton in Warming Polar Regions?
title_sort impact of cobalt on freshwater phytoplankton in warming polar regions
topic trace metal biogeochemistry
cobalt limitation
global warming
url https://doi.org/10.1029/2024GL110065
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