A Near-Ultraviolet Photodetector Based on the TaC: Cu/4 H Silicon Carbide Heterostructure

Photodetectors (PDs) based on 4H silicon carbide (SiC) have garnered significant interest due to their exceptional optoelectronic properties. However, their photoresponse is typically restricted to the ultraviolet (UV) region, with limited light absorption beyond 380 nm, which constrains their utili...

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Main Authors: Salah Abdo, Khalil As’ham, Ambali Alade Odebowale, Sanjida Akter, Amer Abdulghani, Ibrahim A. M. Al Ani, Haroldo Hattori, Andrey E. Miroshnichenko
Format: Article
Language:English
Published: MDPI AG 2025-01-01
Series:Applied Sciences
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Online Access:https://www.mdpi.com/2076-3417/15/2/970
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author Salah Abdo
Khalil As’ham
Ambali Alade Odebowale
Sanjida Akter
Amer Abdulghani
Ibrahim A. M. Al Ani
Haroldo Hattori
Andrey E. Miroshnichenko
author_facet Salah Abdo
Khalil As’ham
Ambali Alade Odebowale
Sanjida Akter
Amer Abdulghani
Ibrahim A. M. Al Ani
Haroldo Hattori
Andrey E. Miroshnichenko
author_sort Salah Abdo
collection DOAJ
description Photodetectors (PDs) based on 4H silicon carbide (SiC) have garnered significant interest due to their exceptional optoelectronic properties. However, their photoresponse is typically restricted to the ultraviolet (UV) region, with limited light absorption beyond 380 nm, which constrains their utility in visible light detection applications. To overcome this limitation, an efficient photodetector was developed using an alloy with TaC (80%) and Cu (20%) on a 4H n-type SiC substrate, enabling effective light detection at 405 nm. The device exhibited high performance with a high photoresponsivity of 1.66 <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msup><mrow><mi mathvariant="normal">A</mi><mi mathvariant="normal">W</mi></mrow><mrow><mo>−</mo><mn>1</mn></mrow></msup></mrow></semantics></math></inline-formula> and a specific detectivity of <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><mn>2.69</mn><mo>×</mo><msup><mrow><mn>10</mn></mrow><mrow><mn>8</mn></mrow></msup></mrow></semantics></math></inline-formula> Jones at 405 nm. The superior performance of the device is ascribed to the enhanced electrical conductivity and optical absorption of the TaC: Cu layer on the 4H SiC substrate, particularly in the near-ultraviolet region. This photodetector combines ease of fabrication with significant performance improvements, expanding the potential applications of 4H SiC in high-temperature optoelectronics. It also introduces a promising pathway for enhancing 4H SiC-based photodetection capabilities across broader spectral ranges.
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spelling doaj-art-a4b9d89d3e954479bbef7d3f7bcb07c62025-01-24T13:21:32ZengMDPI AGApplied Sciences2076-34172025-01-0115297010.3390/app15020970A Near-Ultraviolet Photodetector Based on the TaC: Cu/4 H Silicon Carbide HeterostructureSalah Abdo0Khalil As’ham1Ambali Alade Odebowale2Sanjida Akter3Amer Abdulghani4Ibrahim A. M. Al Ani5Haroldo Hattori6Andrey E. Miroshnichenko7School of Engineering and Information Technology, University of New South Wales at Canberra, Northcott Drive, Canberra, ACT 2610, AustraliaSchool of Engineering and Information Technology, University of New South Wales at Canberra, Northcott Drive, Canberra, ACT 2610, AustraliaSchool of Engineering and Information Technology, University of New South Wales at Canberra, Northcott Drive, Canberra, ACT 2610, AustraliaSchool of Engineering and Information Technology, University of New South Wales at Canberra, Northcott Drive, Canberra, ACT 2610, AustraliaSchool of Engineering and Information Technology, University of New South Wales at Canberra, Northcott Drive, Canberra, ACT 2610, AustraliaSchool of Engineering and Information Technology, University of New South Wales at Canberra, Northcott Drive, Canberra, ACT 2610, AustraliaSchool of Engineering and Information Technology, University of New South Wales at Canberra, Northcott Drive, Canberra, ACT 2610, AustraliaSchool of Engineering and Information Technology, University of New South Wales at Canberra, Northcott Drive, Canberra, ACT 2610, AustraliaPhotodetectors (PDs) based on 4H silicon carbide (SiC) have garnered significant interest due to their exceptional optoelectronic properties. However, their photoresponse is typically restricted to the ultraviolet (UV) region, with limited light absorption beyond 380 nm, which constrains their utility in visible light detection applications. To overcome this limitation, an efficient photodetector was developed using an alloy with TaC (80%) and Cu (20%) on a 4H n-type SiC substrate, enabling effective light detection at 405 nm. The device exhibited high performance with a high photoresponsivity of 1.66 <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msup><mrow><mi mathvariant="normal">A</mi><mi mathvariant="normal">W</mi></mrow><mrow><mo>−</mo><mn>1</mn></mrow></msup></mrow></semantics></math></inline-formula> and a specific detectivity of <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><mn>2.69</mn><mo>×</mo><msup><mrow><mn>10</mn></mrow><mrow><mn>8</mn></mrow></msup></mrow></semantics></math></inline-formula> Jones at 405 nm. The superior performance of the device is ascribed to the enhanced electrical conductivity and optical absorption of the TaC: Cu layer on the 4H SiC substrate, particularly in the near-ultraviolet region. This photodetector combines ease of fabrication with significant performance improvements, expanding the potential applications of 4H SiC in high-temperature optoelectronics. It also introduces a promising pathway for enhancing 4H SiC-based photodetection capabilities across broader spectral ranges.https://www.mdpi.com/2076-3417/15/2/9704H silicon carbide (SiC)tantalum carbide (TaC)near ultraviolet (NUV) photodetectorresponsivity
spellingShingle Salah Abdo
Khalil As’ham
Ambali Alade Odebowale
Sanjida Akter
Amer Abdulghani
Ibrahim A. M. Al Ani
Haroldo Hattori
Andrey E. Miroshnichenko
A Near-Ultraviolet Photodetector Based on the TaC: Cu/4 H Silicon Carbide Heterostructure
Applied Sciences
4H silicon carbide (SiC)
tantalum carbide (TaC)
near ultraviolet (NUV) photodetector
responsivity
title A Near-Ultraviolet Photodetector Based on the TaC: Cu/4 H Silicon Carbide Heterostructure
title_full A Near-Ultraviolet Photodetector Based on the TaC: Cu/4 H Silicon Carbide Heterostructure
title_fullStr A Near-Ultraviolet Photodetector Based on the TaC: Cu/4 H Silicon Carbide Heterostructure
title_full_unstemmed A Near-Ultraviolet Photodetector Based on the TaC: Cu/4 H Silicon Carbide Heterostructure
title_short A Near-Ultraviolet Photodetector Based on the TaC: Cu/4 H Silicon Carbide Heterostructure
title_sort near ultraviolet photodetector based on the tac cu 4 h silicon carbide heterostructure
topic 4H silicon carbide (SiC)
tantalum carbide (TaC)
near ultraviolet (NUV) photodetector
responsivity
url https://www.mdpi.com/2076-3417/15/2/970
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