Photovoltaic Performance of ZnO Nanorod and ZnO : CdO Nanocomposite Layers in Dye-Sensitized Solar Cells (DSSCs)

Triphenylene diamine sensitizer comprising donor, electron conducting, and anchoring group is synthesized for a potential application in dye-sensitized solar cells. Absorption spectrum, electrochemical and photovoltaic properties of triphenylene diamine have been investigated. Two different electrod...

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Main Author: Sule Erten-Ela
Format: Article
Language:English
Published: Wiley 2013-01-01
Series:International Journal of Photoenergy
Online Access:http://dx.doi.org/10.1155/2013/436831
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author Sule Erten-Ela
author_facet Sule Erten-Ela
author_sort Sule Erten-Ela
collection DOAJ
description Triphenylene diamine sensitizer comprising donor, electron conducting, and anchoring group is synthesized for a potential application in dye-sensitized solar cells. Absorption spectrum, electrochemical and photovoltaic properties of triphenylene diamine have been investigated. Two different electrodes are used for dye-sensitized solar cells. The performances of ZnO nanorod electrodes are compared to ZnO : CdO nanocomposite electrode. Also, the theoretical calculations for HOMO and LUMO orbitals are used to estimate the photovoltaic properties of organic sensitizer in the design stage. ZnO : CdO nanocomposite electrode-based dye-sensitized solar cell sensitized with organic sensitizer exhibits higher efficiencies than ZnO nanorod electrode. For a typical device, a solar energy conversion efficiency (η) of 0.80 based on ZnO : CdO nanocomposite is achieved under simulated AM 1.5 solar irradiation (100 mW cm−2) with a short circuit photocurrent density (Jsc) of 3.10 mA/cm2, an open-circuit voltage (Voc) of 480 mV, and a fill factor (FF) of 0.57. These results suggest that the ZnO : CdO nanocomposite system is a good selection and a promising candidate for electrode system in dye-sensitized solar cells.
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spelling doaj-art-a4b360e1d61849778d7d427d5c0046712025-08-20T02:23:05ZengWileyInternational Journal of Photoenergy1110-662X1687-529X2013-01-01201310.1155/2013/436831436831Photovoltaic Performance of ZnO Nanorod and ZnO : CdO Nanocomposite Layers in Dye-Sensitized Solar Cells (DSSCs)Sule Erten-Ela0Ege University, Solar Energy Institute, Bornova, 35100 Izmir, TurkeyTriphenylene diamine sensitizer comprising donor, electron conducting, and anchoring group is synthesized for a potential application in dye-sensitized solar cells. Absorption spectrum, electrochemical and photovoltaic properties of triphenylene diamine have been investigated. Two different electrodes are used for dye-sensitized solar cells. The performances of ZnO nanorod electrodes are compared to ZnO : CdO nanocomposite electrode. Also, the theoretical calculations for HOMO and LUMO orbitals are used to estimate the photovoltaic properties of organic sensitizer in the design stage. ZnO : CdO nanocomposite electrode-based dye-sensitized solar cell sensitized with organic sensitizer exhibits higher efficiencies than ZnO nanorod electrode. For a typical device, a solar energy conversion efficiency (η) of 0.80 based on ZnO : CdO nanocomposite is achieved under simulated AM 1.5 solar irradiation (100 mW cm−2) with a short circuit photocurrent density (Jsc) of 3.10 mA/cm2, an open-circuit voltage (Voc) of 480 mV, and a fill factor (FF) of 0.57. These results suggest that the ZnO : CdO nanocomposite system is a good selection and a promising candidate for electrode system in dye-sensitized solar cells.http://dx.doi.org/10.1155/2013/436831
spellingShingle Sule Erten-Ela
Photovoltaic Performance of ZnO Nanorod and ZnO : CdO Nanocomposite Layers in Dye-Sensitized Solar Cells (DSSCs)
International Journal of Photoenergy
title Photovoltaic Performance of ZnO Nanorod and ZnO : CdO Nanocomposite Layers in Dye-Sensitized Solar Cells (DSSCs)
title_full Photovoltaic Performance of ZnO Nanorod and ZnO : CdO Nanocomposite Layers in Dye-Sensitized Solar Cells (DSSCs)
title_fullStr Photovoltaic Performance of ZnO Nanorod and ZnO : CdO Nanocomposite Layers in Dye-Sensitized Solar Cells (DSSCs)
title_full_unstemmed Photovoltaic Performance of ZnO Nanorod and ZnO : CdO Nanocomposite Layers in Dye-Sensitized Solar Cells (DSSCs)
title_short Photovoltaic Performance of ZnO Nanorod and ZnO : CdO Nanocomposite Layers in Dye-Sensitized Solar Cells (DSSCs)
title_sort photovoltaic performance of zno nanorod and zno cdo nanocomposite layers in dye sensitized solar cells dsscs
url http://dx.doi.org/10.1155/2013/436831
work_keys_str_mv AT suleertenela photovoltaicperformanceofznonanorodandznocdonanocompositelayersindyesensitizedsolarcellsdsscs