Geographical origin traceability of kiwifruit products using stable isotope and multi-element analysis with multivariate modeling: Feature extraction, selection of model and variable, and discrimination

The mislabeling of kiwifruit origin frequently disturbs market competition and governmental supervision, significantly undermines brand reputation and consumer rights. In this work, a total of 370 kiwifruits from 8 different countries in global were collected, and 6 stable isotope ratios (SIRs), 10...

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Main Authors: Wang Shuanhui, Chen Chang, Tian Jing, Liu Zhi, Mei Xianxian, Zhou Jialu, Wang Dongguang, Zhu Shaohua
Format: Article
Language:English
Published: Elsevier 2025-02-01
Series:Food Chemistry: X
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Online Access:http://www.sciencedirect.com/science/article/pii/S2590157525000781
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author Wang Shuanhui
Chen Chang
Tian Jing
Liu Zhi
Mei Xianxian
Zhou Jialu
Wang Dongguang
Zhu Shaohua
author_facet Wang Shuanhui
Chen Chang
Tian Jing
Liu Zhi
Mei Xianxian
Zhou Jialu
Wang Dongguang
Zhu Shaohua
author_sort Wang Shuanhui
collection DOAJ
description The mislabeling of kiwifruit origin frequently disturbs market competition and governmental supervision, significantly undermines brand reputation and consumer rights. In this work, a total of 370 kiwifruits from 8 different countries in global were collected, and 6 stable isotope ratios (SIRs), 10 mineral elements (MEs), and 16 rare earth elements (REEs) were determined for origin traceability study. One-way analysis of variance (ANOVA) showed that regional differences of 32 variables are at significant level (P value =0.00). Supervised methods, partial least squares-discriminant analysis (PLS-DA) and its derivative algorithm (OPLS-DA), linear discriminant analysis (LDA), enhanced identification performance and finally elevated the accuracies to 100 % for all kiwifruit origins. Lu, Tb, Eu, Ho, Pm, Y, δ34S, δ2H, δ15N, Mg, Se were main contributive variables for LDA modeling (AUC value >0.5). A blind test was conducted using 63 samples randomly selected from Chinese market. The predicted result indicated a significantly high probability of origin mislabeling of imported kiwifruit products, with percentages ranging from 30.0 % to 90.0 %. This study may provide technical supports for combating origin mislabeling conduct, and ensuring food authenticity of kiwifruit in global trade.
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institution Kabale University
issn 2590-1575
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publishDate 2025-02-01
publisher Elsevier
record_format Article
series Food Chemistry: X
spelling doaj-art-a41362e361a249b9a8729289bcabd3cb2025-02-11T04:35:25ZengElsevierFood Chemistry: X2590-15752025-02-0126102231Geographical origin traceability of kiwifruit products using stable isotope and multi-element analysis with multivariate modeling: Feature extraction, selection of model and variable, and discriminationWang Shuanhui0Chen Chang1Tian Jing2Liu Zhi3Mei Xianxian4Zhou Jialu5Wang Dongguang6Zhu Shaohua7College of Agriculture and Biotechnology, Hunan University of Humanities, Science and Technology, Loudi 417000, ChinaCollege of Agriculture and Biotechnology, Hunan University of Humanities, Science and Technology, Loudi 417000, ChinaCollege of Agriculture and Biotechnology, Hunan University of Humanities, Science and Technology, Loudi 417000, ChinaCollege of Agriculture and Biotechnology, Hunan University of Humanities, Science and Technology, Loudi 417000, China; Changsha Xichu Information Technology Co. LTD, Changsha 417000, China; Corresponding authors at: College of Agriculture and Biotechnology, Hunan University of Humanities, Science and Technology, Loudi 417000, China.College of Agriculture and Biotechnology, Hunan University of Humanities, Science and Technology, Loudi 417000, ChinaCollege of Agriculture and Biotechnology, Hunan University of Humanities, Science and Technology, Loudi 417000, ChinaCollege of Agriculture and Biotechnology, Hunan University of Humanities, Science and Technology, Loudi 417000, China; Corresponding authors at: College of Agriculture and Biotechnology, Hunan University of Humanities, Science and Technology, Loudi 417000, China.Import and Export Food Safety Department of Changsha Customs, Changsha 410201, ChinaThe mislabeling of kiwifruit origin frequently disturbs market competition and governmental supervision, significantly undermines brand reputation and consumer rights. In this work, a total of 370 kiwifruits from 8 different countries in global were collected, and 6 stable isotope ratios (SIRs), 10 mineral elements (MEs), and 16 rare earth elements (REEs) were determined for origin traceability study. One-way analysis of variance (ANOVA) showed that regional differences of 32 variables are at significant level (P value =0.00). Supervised methods, partial least squares-discriminant analysis (PLS-DA) and its derivative algorithm (OPLS-DA), linear discriminant analysis (LDA), enhanced identification performance and finally elevated the accuracies to 100 % for all kiwifruit origins. Lu, Tb, Eu, Ho, Pm, Y, δ34S, δ2H, δ15N, Mg, Se were main contributive variables for LDA modeling (AUC value >0.5). A blind test was conducted using 63 samples randomly selected from Chinese market. The predicted result indicated a significantly high probability of origin mislabeling of imported kiwifruit products, with percentages ranging from 30.0 % to 90.0 %. This study may provide technical supports for combating origin mislabeling conduct, and ensuring food authenticity of kiwifruit in global trade.http://www.sciencedirect.com/science/article/pii/S2590157525000781KiwifruitStable isotope and multi- elementMultivariate modelingOrigin traceabilityFood integrity
spellingShingle Wang Shuanhui
Chen Chang
Tian Jing
Liu Zhi
Mei Xianxian
Zhou Jialu
Wang Dongguang
Zhu Shaohua
Geographical origin traceability of kiwifruit products using stable isotope and multi-element analysis with multivariate modeling: Feature extraction, selection of model and variable, and discrimination
Food Chemistry: X
Kiwifruit
Stable isotope and multi- element
Multivariate modeling
Origin traceability
Food integrity
title Geographical origin traceability of kiwifruit products using stable isotope and multi-element analysis with multivariate modeling: Feature extraction, selection of model and variable, and discrimination
title_full Geographical origin traceability of kiwifruit products using stable isotope and multi-element analysis with multivariate modeling: Feature extraction, selection of model and variable, and discrimination
title_fullStr Geographical origin traceability of kiwifruit products using stable isotope and multi-element analysis with multivariate modeling: Feature extraction, selection of model and variable, and discrimination
title_full_unstemmed Geographical origin traceability of kiwifruit products using stable isotope and multi-element analysis with multivariate modeling: Feature extraction, selection of model and variable, and discrimination
title_short Geographical origin traceability of kiwifruit products using stable isotope and multi-element analysis with multivariate modeling: Feature extraction, selection of model and variable, and discrimination
title_sort geographical origin traceability of kiwifruit products using stable isotope and multi element analysis with multivariate modeling feature extraction selection of model and variable and discrimination
topic Kiwifruit
Stable isotope and multi- element
Multivariate modeling
Origin traceability
Food integrity
url http://www.sciencedirect.com/science/article/pii/S2590157525000781
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