New Insights of Response Surface Methodology Approach in Optimizing Total Phenolic Content of <i>Zanthoxylum acanthopodium</i> DC. Fruit Extracted Using Microwave-Assisted Extraction and the Impact to Antioxidant Activity

Zanthoxylum acanthopodium DC., a unique spice plant from North Sumatra, is rich in beneficial secondary metabolites, particularly phenolic compounds. This study utilized the microwave-assisted extraction method to enhance the extraction of these bioactive compounds. The goal was to determine the opt...

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Main Authors: Sumaiyah Sumaiyah, Retno Murwanti, Didi Nurhadi Illian, Muhammad Fauzan Lubis, Keshia Tampubolon
Format: Article
Language:English
Published: Department of Chemistry, Universitas Gadjah Mada 2024-12-01
Series:Indonesian Journal of Chemistry
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Online Access:https://jurnal.ugm.ac.id/ijc/article/view/95922
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author Sumaiyah Sumaiyah
Retno Murwanti
Didi Nurhadi Illian
Muhammad Fauzan Lubis
Keshia Tampubolon
author_facet Sumaiyah Sumaiyah
Retno Murwanti
Didi Nurhadi Illian
Muhammad Fauzan Lubis
Keshia Tampubolon
author_sort Sumaiyah Sumaiyah
collection DOAJ
description Zanthoxylum acanthopodium DC., a unique spice plant from North Sumatra, is rich in beneficial secondary metabolites, particularly phenolic compounds. This study utilized the microwave-assisted extraction method to enhance the extraction of these bioactive compounds. The goal was to determine the optimal extraction conditions, including solvent concentration (X1), microwave power (X2), and extraction time (X3) to maximize the total phenolic content (TPC) of Z. acanthopodium fruit. A Box-Behnken design, part of response surface methodology, was used with three factors at three levels: X1 (50%, 75%, and 100% ethanol in water), X2 (180, 300, and 450 W), and X3 (3, 8.5, and 14 min). The phenolic compounds in the optimized extract were identified using LC-HRMS, and its antioxidant activity was measured using radical scavenging activity assays. The statistical analysis indicated a significant quadratic model (p-value < 0.05), with a high R2 of 86.25%. Optimal conditions for maximum TPC (159.637 ± 5.72 mg GAE/g) were achieved with 50% ethanol, 450 W, and 8.5 min, outperforming conventional extraction methods. Compared to the non-optimized extract, the optimized extract also exhibited strong antioxidant activity, particularly in DPPH radical inhibition. This method successfully optimized TPC in Z. acanthopodium fruit, enhancing its antioxidant properties.
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spelling doaj-art-a40f60d3a7bf4c0886901b37d37474622025-08-20T02:18:03ZengDepartment of Chemistry, Universitas Gadjah MadaIndonesian Journal of Chemistry1411-94202460-15782024-12-012461743175910.22146/ijc.9592236582New Insights of Response Surface Methodology Approach in Optimizing Total Phenolic Content of <i>Zanthoxylum acanthopodium</i> DC. Fruit Extracted Using Microwave-Assisted Extraction and the Impact to Antioxidant ActivitySumaiyah Sumaiyah0Retno Murwanti1Didi Nurhadi Illian2Muhammad Fauzan Lubis3Keshia Tampubolon4Department of Pharmaceutics and Pharmaceutical Technology, Faculty of Pharmacy, Universitas Sumatera Utara, Jl. Tri Dharma, Padang Bulan, Medan 20155, IndonesiaDepartment of Pharmacology and Clinical Pharmacy, Faculty of Pharmacy, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, IndonesiaDepartment of Pharmacy, Faculty of Mathematics and Natural Sciences, Universitas Syiah Kuala, Jl. Syech Abdurrauf, Kopelma Darussalam, Banda Aceh 23111, IndonesiaDepartment of Pharmaceutical Biology, Faculty of Pharmacy, Universitas Sumatera Utara, Jl. Tri Dharma, Padang Bulan, Medan 20155, IndonesiaUndergraduate Program, Faculty of Pharmacy, Universitas Sumatera Utara, Jl. Tri Dharma, Padang Bulan, Medan 20155, IndonesiaZanthoxylum acanthopodium DC., a unique spice plant from North Sumatra, is rich in beneficial secondary metabolites, particularly phenolic compounds. This study utilized the microwave-assisted extraction method to enhance the extraction of these bioactive compounds. The goal was to determine the optimal extraction conditions, including solvent concentration (X1), microwave power (X2), and extraction time (X3) to maximize the total phenolic content (TPC) of Z. acanthopodium fruit. A Box-Behnken design, part of response surface methodology, was used with three factors at three levels: X1 (50%, 75%, and 100% ethanol in water), X2 (180, 300, and 450 W), and X3 (3, 8.5, and 14 min). The phenolic compounds in the optimized extract were identified using LC-HRMS, and its antioxidant activity was measured using radical scavenging activity assays. The statistical analysis indicated a significant quadratic model (p-value < 0.05), with a high R2 of 86.25%. Optimal conditions for maximum TPC (159.637 ± 5.72 mg GAE/g) were achieved with 50% ethanol, 450 W, and 8.5 min, outperforming conventional extraction methods. Compared to the non-optimized extract, the optimized extract also exhibited strong antioxidant activity, particularly in DPPH radical inhibition. This method successfully optimized TPC in Z. acanthopodium fruit, enhancing its antioxidant properties.https://jurnal.ugm.ac.id/ijc/article/view/95922zanthoxylum acanthopodium dc.phenolresponse surface methodologymicrowave-assisted extractionantioxidant
spellingShingle Sumaiyah Sumaiyah
Retno Murwanti
Didi Nurhadi Illian
Muhammad Fauzan Lubis
Keshia Tampubolon
New Insights of Response Surface Methodology Approach in Optimizing Total Phenolic Content of <i>Zanthoxylum acanthopodium</i> DC. Fruit Extracted Using Microwave-Assisted Extraction and the Impact to Antioxidant Activity
Indonesian Journal of Chemistry
zanthoxylum acanthopodium dc.
phenol
response surface methodology
microwave-assisted extraction
antioxidant
title New Insights of Response Surface Methodology Approach in Optimizing Total Phenolic Content of <i>Zanthoxylum acanthopodium</i> DC. Fruit Extracted Using Microwave-Assisted Extraction and the Impact to Antioxidant Activity
title_full New Insights of Response Surface Methodology Approach in Optimizing Total Phenolic Content of <i>Zanthoxylum acanthopodium</i> DC. Fruit Extracted Using Microwave-Assisted Extraction and the Impact to Antioxidant Activity
title_fullStr New Insights of Response Surface Methodology Approach in Optimizing Total Phenolic Content of <i>Zanthoxylum acanthopodium</i> DC. Fruit Extracted Using Microwave-Assisted Extraction and the Impact to Antioxidant Activity
title_full_unstemmed New Insights of Response Surface Methodology Approach in Optimizing Total Phenolic Content of <i>Zanthoxylum acanthopodium</i> DC. Fruit Extracted Using Microwave-Assisted Extraction and the Impact to Antioxidant Activity
title_short New Insights of Response Surface Methodology Approach in Optimizing Total Phenolic Content of <i>Zanthoxylum acanthopodium</i> DC. Fruit Extracted Using Microwave-Assisted Extraction and the Impact to Antioxidant Activity
title_sort new insights of response surface methodology approach in optimizing total phenolic content of i zanthoxylum acanthopodium i dc fruit extracted using microwave assisted extraction and the impact to antioxidant activity
topic zanthoxylum acanthopodium dc.
phenol
response surface methodology
microwave-assisted extraction
antioxidant
url https://jurnal.ugm.ac.id/ijc/article/view/95922
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