Formation mechanism of W phase and its effects on the mechanical properties of Mg−Dy−Zn alloys

The morphology and dimension of W phases play an important role in determining mechanical properties of Mg−RE−Zn (where RE denotes rare earth elements) alloys. In this study, the γ′ platelet and W particle occurred in the aged Mg−2Dy–0.5Zn (at.%) alloys were investigated by aberration-corrected scan...

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Bibliographic Details
Main Authors: J.S. Chen, C.J. Ji, Q.Y. Huang, Y.Z. Zeng, H.B. Xie, P. Chen, B.Z. Sun
Format: Article
Language:English
Published: KeAi Communications Co., Ltd. 2025-05-01
Series:Journal of Magnesium and Alloys
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Online Access:http://www.sciencedirect.com/science/article/pii/S2213956724001828
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Summary:The morphology and dimension of W phases play an important role in determining mechanical properties of Mg−RE−Zn (where RE denotes rare earth elements) alloys. In this study, the γ′ platelet and W particle occurred in the aged Mg−2Dy–0.5Zn (at.%) alloys were investigated by aberration-corrected scanning transmission electron microscopy. A novel formation mechanism of W phase was proposed, and its effects on the morphology and dimension of W particle, as well as mechanical properties of Mg−2Dy–0.5Zn alloys, were also discussed particularly. Different from other Mg−RE−Zn alloys, the nucleation and growth of W particle in Mg−Dy–Zn alloys mainly depend on the precipitated γ′ platelet. Primarily, a mass of Dy and Zn solute atoms concentrated near γ′ platelet or between two adjacent γ′ platelets can meet the composition requirement of W particle nucleation. Next, the smaller interfacial mismatch between W and γ′ facilitates the nucleation and growth of W particle. Thirdly, the growth of W particle can be achieved by consuming the surrounding γ′ platelets. The nucleation and growth mechanisms make W particles exhibit rectangular or leaf-like and remain at the nanoscale. The coexistence of γ′ platelets and nanoscale W particles, and some better interfacial relationships between phases, lead to a high strength-ductility synergy of alloy. The findings may provide some fundamental guidelines for the microstructure design and optimization of new-type Mg-based alloys.
ISSN:2213-9567