Machine Learning for the Prediction of Thermodynamic Properties in Amorphous Silicon

This study integrated molecular dynamics (MD) simulations with machine learning techniques, specifically Linear, Ridge, and Support Vector Regression, to predict the thermodynamic properties of amorphous silicon (a-Si) under varying conditions. The MD simulations provided a detailed dataset that cap...

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Main Author: Nicolás Amigo
Format: Article
Language:English
Published: MDPI AG 2025-05-01
Series:Applied Sciences
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Online Access:https://www.mdpi.com/2076-3417/15/10/5574
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author Nicolás Amigo
author_facet Nicolás Amigo
author_sort Nicolás Amigo
collection DOAJ
description This study integrated molecular dynamics (MD) simulations with machine learning techniques, specifically Linear, Ridge, and Support Vector Regression, to predict the thermodynamic properties of amorphous silicon (a-Si) under varying conditions. The MD simulations provided a detailed dataset that captured the atomic-level behavior of the a-Si, which enabled exploration of how thermodynamic factors, such as the cooling rate, temperature, and pressure, affect the material’s density, internal energy, and enthalpy. Machine learning models were trained on this dataset and demonstrated exceptional predictive accuracy with <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msup><mi>R</mi><mn>2</mn></msup></semantics></math></inline-formula> values that exceeded 0.95 and minimal root-mean-square errors. The results reveal that the temperature and pressure significantly influenced the thermodynamic properties of the a-Si, while the cooling rate had a minor effect. The models generated isobaric and isothermal curves, which offered deeper insights into the thermodynamic behavior of the a-Si and complemented traditional MD simulations by providing a more efficient means to explore thermodynamic states. This work highlights the potential of machine learning to accelerate the study of materials by enabling faster exploration of thermodynamic behavior and the generation of additional data. This approach enhances the understanding of the equation of state of a-Si and opens new avenues for applying this hybrid modeling technique to other materials.
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spelling doaj-art-a3900ac2069c4e6c9596f269e6560c8e2025-08-20T02:33:43ZengMDPI AGApplied Sciences2076-34172025-05-011510557410.3390/app15105574Machine Learning for the Prediction of Thermodynamic Properties in Amorphous SiliconNicolás Amigo0Departamento de Física, Facultad de Ciencias Naturales, Matemática y del Medio Ambiente, Universidad Tecnológica Metropolitana, Las Palmeras 3360, Ñuñoa, Santiago 7800003, ChileThis study integrated molecular dynamics (MD) simulations with machine learning techniques, specifically Linear, Ridge, and Support Vector Regression, to predict the thermodynamic properties of amorphous silicon (a-Si) under varying conditions. The MD simulations provided a detailed dataset that captured the atomic-level behavior of the a-Si, which enabled exploration of how thermodynamic factors, such as the cooling rate, temperature, and pressure, affect the material’s density, internal energy, and enthalpy. Machine learning models were trained on this dataset and demonstrated exceptional predictive accuracy with <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msup><mi>R</mi><mn>2</mn></msup></semantics></math></inline-formula> values that exceeded 0.95 and minimal root-mean-square errors. The results reveal that the temperature and pressure significantly influenced the thermodynamic properties of the a-Si, while the cooling rate had a minor effect. The models generated isobaric and isothermal curves, which offered deeper insights into the thermodynamic behavior of the a-Si and complemented traditional MD simulations by providing a more efficient means to explore thermodynamic states. This work highlights the potential of machine learning to accelerate the study of materials by enabling faster exploration of thermodynamic behavior and the generation of additional data. This approach enhances the understanding of the equation of state of a-Si and opens new avenues for applying this hybrid modeling technique to other materials.https://www.mdpi.com/2076-3417/15/10/5574thermodynamic propertiesmachine learningstatisticsmolecular dynamics
spellingShingle Nicolás Amigo
Machine Learning for the Prediction of Thermodynamic Properties in Amorphous Silicon
Applied Sciences
thermodynamic properties
machine learning
statistics
molecular dynamics
title Machine Learning for the Prediction of Thermodynamic Properties in Amorphous Silicon
title_full Machine Learning for the Prediction of Thermodynamic Properties in Amorphous Silicon
title_fullStr Machine Learning for the Prediction of Thermodynamic Properties in Amorphous Silicon
title_full_unstemmed Machine Learning for the Prediction of Thermodynamic Properties in Amorphous Silicon
title_short Machine Learning for the Prediction of Thermodynamic Properties in Amorphous Silicon
title_sort machine learning for the prediction of thermodynamic properties in amorphous silicon
topic thermodynamic properties
machine learning
statistics
molecular dynamics
url https://www.mdpi.com/2076-3417/15/10/5574
work_keys_str_mv AT nicolasamigo machinelearningforthepredictionofthermodynamicpropertiesinamorphoussilicon