Functional biosynthetic stereodivergence in a gene cluster via a dihydrosydnone N-oxide

Functional biosynthetic stereodivergence in a gene cluster via a dihydrosydnone N-oxide

Abstract Chirality plays a critical role in the biochemistry of life and often only one enantiomeric series is observed (homochirality). Only a few natural products have been obtained as racemates, e.g. the signalling molecule valdiazen produced by Burkholderia cenocepacia H111. In this study, we in...

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Bibliographic Details
Main Authors: Jiajun Ren, Anugraha Mathew, María Rodríguez-García, Tobias Kohler, Olivier Blacque, Anthony Linden, Leo Eberl, Simon Sieber, Karl Gademann
Format: Article
Language:English
Published: Nature Portfolio 2024-12-01
Series:Communications Chemistry
Online Access:https://doi.org/10.1038/s42004-024-01372-3
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