Evaluation of the Strontium Isotope Ratios in Soil–Plant–Fruit: A Comprehensive Study on Vignola Cherry (Ciliegia di Vignola PGI)

This study investigates the potential of strontium isotopes as a geographical tracer for Vignola cherries. Despite several studies having employed this indicator to trace the origin of food products, the mechanisms underlying the fractionation and translocation of strontium from soil to edible parts...

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Main Authors: Lisa Lancellotti, Veronica D’Eusanio, Daniela Manzini, Caterina Durante, Andrea Marchetti, Lorenzo Tassi
Format: Article
Language:English
Published: MDPI AG 2025-04-01
Series:Foods
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Online Access:https://www.mdpi.com/2304-8158/14/9/1492
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author Lisa Lancellotti
Veronica D’Eusanio
Daniela Manzini
Caterina Durante
Andrea Marchetti
Lorenzo Tassi
author_facet Lisa Lancellotti
Veronica D’Eusanio
Daniela Manzini
Caterina Durante
Andrea Marchetti
Lorenzo Tassi
author_sort Lisa Lancellotti
collection DOAJ
description This study investigates the potential of strontium isotopes as a geographical tracer for Vignola cherries. Despite several studies having employed this indicator to trace the origin of food products, the mechanisms underlying the fractionation and translocation of strontium from soil to edible parts remain poorly understood. In this study, the <sup>91</sup>Zr/<sup>90</sup>Zr ratio was used as a normalization pair to correct measurements of <sup>87</sup>Sr/<sup>86</sup>Sr and <sup>88</sup>Sr/<sup>86</sup>Sr (δ<sup>88</sup>Sr). Soil, cherry branches, and fruit samples were collected from various producers and locations. Isotopic analyses were carried out using a double-focusing multi-collector–inductively coupled plasma/mass spectrometer (MC-ICP/MS). External correction was applied using the <sup>91</sup>Zr/<sup>90</sup>Zr ratio, assuming both equal and different fractionation factors for Sr and Zr isotopes. Results from both correction models showed improved accuracy by accounting for fluctuations in instrumental mass bias. Regarding the translocation of strontium, the data indicate an increase in <sup>88</sup>Sr of approximately 0.2‰ from soil to plant tissue. This trend was consistent across all sampled locations.
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spelling doaj-art-a2a160cdedde4089b069c1802aafc3ee2025-08-20T02:58:44ZengMDPI AGFoods2304-81582025-04-01149149210.3390/foods14091492Evaluation of the Strontium Isotope Ratios in Soil–Plant–Fruit: A Comprehensive Study on Vignola Cherry (Ciliegia di Vignola PGI)Lisa Lancellotti0Veronica D’Eusanio1Daniela Manzini2Caterina Durante3Andrea Marchetti4Lorenzo Tassi5Centro Interdipartimentale Grandi Strumenti (CIGS), University of Modena and Reggio Emilia, Via G. Campi 213/A, 41125 Modena, ItalyDepartment of Chemical and Geological Sciences, University of Modena and Reggio Emilia, Via G. Campi 103, 41125 Modena, ItalyCentro Interdipartimentale Grandi Strumenti (CIGS), University of Modena and Reggio Emilia, Via G. Campi 213/A, 41125 Modena, ItalyDepartment of Chemical and Geological Sciences, University of Modena and Reggio Emilia, Via G. Campi 103, 41125 Modena, ItalyDepartment of Chemical and Geological Sciences, University of Modena and Reggio Emilia, Via G. Campi 103, 41125 Modena, ItalyDepartment of Chemical and Geological Sciences, University of Modena and Reggio Emilia, Via G. Campi 103, 41125 Modena, ItalyThis study investigates the potential of strontium isotopes as a geographical tracer for Vignola cherries. Despite several studies having employed this indicator to trace the origin of food products, the mechanisms underlying the fractionation and translocation of strontium from soil to edible parts remain poorly understood. In this study, the <sup>91</sup>Zr/<sup>90</sup>Zr ratio was used as a normalization pair to correct measurements of <sup>87</sup>Sr/<sup>86</sup>Sr and <sup>88</sup>Sr/<sup>86</sup>Sr (δ<sup>88</sup>Sr). Soil, cherry branches, and fruit samples were collected from various producers and locations. Isotopic analyses were carried out using a double-focusing multi-collector–inductively coupled plasma/mass spectrometer (MC-ICP/MS). External correction was applied using the <sup>91</sup>Zr/<sup>90</sup>Zr ratio, assuming both equal and different fractionation factors for Sr and Zr isotopes. Results from both correction models showed improved accuracy by accounting for fluctuations in instrumental mass bias. Regarding the translocation of strontium, the data indicate an increase in <sup>88</sup>Sr of approximately 0.2‰ from soil to plant tissue. This trend was consistent across all sampled locations.https://www.mdpi.com/2304-8158/14/9/1492mass dependent fractionationMC-HR-ICP/MSstrontium isotope ratiosVignola PGI Cherrygeographic traceability
spellingShingle Lisa Lancellotti
Veronica D’Eusanio
Daniela Manzini
Caterina Durante
Andrea Marchetti
Lorenzo Tassi
Evaluation of the Strontium Isotope Ratios in Soil–Plant–Fruit: A Comprehensive Study on Vignola Cherry (Ciliegia di Vignola PGI)
Foods
mass dependent fractionation
MC-HR-ICP/MS
strontium isotope ratios
Vignola PGI Cherry
geographic traceability
title Evaluation of the Strontium Isotope Ratios in Soil–Plant–Fruit: A Comprehensive Study on Vignola Cherry (Ciliegia di Vignola PGI)
title_full Evaluation of the Strontium Isotope Ratios in Soil–Plant–Fruit: A Comprehensive Study on Vignola Cherry (Ciliegia di Vignola PGI)
title_fullStr Evaluation of the Strontium Isotope Ratios in Soil–Plant–Fruit: A Comprehensive Study on Vignola Cherry (Ciliegia di Vignola PGI)
title_full_unstemmed Evaluation of the Strontium Isotope Ratios in Soil–Plant–Fruit: A Comprehensive Study on Vignola Cherry (Ciliegia di Vignola PGI)
title_short Evaluation of the Strontium Isotope Ratios in Soil–Plant–Fruit: A Comprehensive Study on Vignola Cherry (Ciliegia di Vignola PGI)
title_sort evaluation of the strontium isotope ratios in soil plant fruit a comprehensive study on vignola cherry ciliegia di vignola pgi
topic mass dependent fractionation
MC-HR-ICP/MS
strontium isotope ratios
Vignola PGI Cherry
geographic traceability
url https://www.mdpi.com/2304-8158/14/9/1492
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