Effect of alkali activator and granulated blast furnace slag on the properties of lithium slag-based high-strength lightweight aggregates

Abstract This study investigated the effects of NaOH molarity (6–14 M) and ground granulated blast furnace slag (GBFS) content (0–45%) on the properties of lithium slag (LS)-based cold-bonded lightweight aggregates. Bulk density, water absorption, porosity, and cylinder compressive strength were eva...

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Main Authors: Yingda Zhang, Zhaopeng Tang, Xianliang Zhou, Yantao Zheng, Zihao Liu
Format: Article
Language:English
Published: Nature Portfolio 2025-08-01
Series:Scientific Reports
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Online Access:https://doi.org/10.1038/s41598-025-16048-8
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author Yingda Zhang
Zhaopeng Tang
Xianliang Zhou
Yantao Zheng
Zihao Liu
author_facet Yingda Zhang
Zhaopeng Tang
Xianliang Zhou
Yantao Zheng
Zihao Liu
author_sort Yingda Zhang
collection DOAJ
description Abstract This study investigated the effects of NaOH molarity (6–14 M) and ground granulated blast furnace slag (GBFS) content (0–45%) on the properties of lithium slag (LS)-based cold-bonded lightweight aggregates. Bulk density, water absorption, porosity, and cylinder compressive strength were evaluated, and microstructural characterization was conducted using SEM, XRD, FTIR, MIP, and TG/DTG. Results showed that increasing NaOH molarity and GBFS content reduced water absorption (from 15.87 to 5.88%) and porosity (from 34.79 to 13.39%), while enhancing bulk density (731–1074 kg/m³) and compressive strength. At 30% GBFS, the 28-day strength increased by 224.48%, from 3.35 MPa (M6-30) to 10.87 MPa (M14-30). At 12 M NaOH, raising GBFS content from 0 to 45% increased strength by 435.62%, from 2.33 MPa to 12.48 MPa. LS without GBFS achieved 2.33 MPa, indicating inherent pozzolanic activity. Microstructural analysis revealed that performance improvement was due to enhanced geopolymerization and reduced harmful pores (> 200 nm). The M8-30 mix (915.68 kg/m³, 5.98 MPa) showed potential for meeting high-strength lightweight aggregate criteria with mix optimization. These findings demonstrate the feasibility of valorizing LS into high-performance lightweight aggregates, contributing to waste utilization and low-carbon construction.
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spelling doaj-art-a29d4e2fe5ef412990b6801cb620ed092025-08-20T03:47:12ZengNature PortfolioScientific Reports2045-23222025-08-0115111310.1038/s41598-025-16048-8Effect of alkali activator and granulated blast furnace slag on the properties of lithium slag-based high-strength lightweight aggregatesYingda Zhang0Zhaopeng Tang1Xianliang Zhou2Yantao Zheng3Zihao Liu4School of Architecture and Civil Engineering, Xihua UniversitySchool of Architecture and Civil Engineering, Xihua UniversitySchool of Architecture and Civil Engineering, Xihua UniversityGuizhou Chengqian Mining Development Co., LtdDepartment of Architecture, Faculty of Environmental Engineering, The University of KitakyushuAbstract This study investigated the effects of NaOH molarity (6–14 M) and ground granulated blast furnace slag (GBFS) content (0–45%) on the properties of lithium slag (LS)-based cold-bonded lightweight aggregates. Bulk density, water absorption, porosity, and cylinder compressive strength were evaluated, and microstructural characterization was conducted using SEM, XRD, FTIR, MIP, and TG/DTG. Results showed that increasing NaOH molarity and GBFS content reduced water absorption (from 15.87 to 5.88%) and porosity (from 34.79 to 13.39%), while enhancing bulk density (731–1074 kg/m³) and compressive strength. At 30% GBFS, the 28-day strength increased by 224.48%, from 3.35 MPa (M6-30) to 10.87 MPa (M14-30). At 12 M NaOH, raising GBFS content from 0 to 45% increased strength by 435.62%, from 2.33 MPa to 12.48 MPa. LS without GBFS achieved 2.33 MPa, indicating inherent pozzolanic activity. Microstructural analysis revealed that performance improvement was due to enhanced geopolymerization and reduced harmful pores (> 200 nm). The M8-30 mix (915.68 kg/m³, 5.98 MPa) showed potential for meeting high-strength lightweight aggregate criteria with mix optimization. These findings demonstrate the feasibility of valorizing LS into high-performance lightweight aggregates, contributing to waste utilization and low-carbon construction.https://doi.org/10.1038/s41598-025-16048-8Cold bondingArtificial lightweight aggregateLithium slagGranulated blast furnace slagHigh-strength lightweight aggregateMicrostructural characteristics.
spellingShingle Yingda Zhang
Zhaopeng Tang
Xianliang Zhou
Yantao Zheng
Zihao Liu
Effect of alkali activator and granulated blast furnace slag on the properties of lithium slag-based high-strength lightweight aggregates
Scientific Reports
Cold bonding
Artificial lightweight aggregate
Lithium slag
Granulated blast furnace slag
High-strength lightweight aggregate
Microstructural characteristics.
title Effect of alkali activator and granulated blast furnace slag on the properties of lithium slag-based high-strength lightweight aggregates
title_full Effect of alkali activator and granulated blast furnace slag on the properties of lithium slag-based high-strength lightweight aggregates
title_fullStr Effect of alkali activator and granulated blast furnace slag on the properties of lithium slag-based high-strength lightweight aggregates
title_full_unstemmed Effect of alkali activator and granulated blast furnace slag on the properties of lithium slag-based high-strength lightweight aggregates
title_short Effect of alkali activator and granulated blast furnace slag on the properties of lithium slag-based high-strength lightweight aggregates
title_sort effect of alkali activator and granulated blast furnace slag on the properties of lithium slag based high strength lightweight aggregates
topic Cold bonding
Artificial lightweight aggregate
Lithium slag
Granulated blast furnace slag
High-strength lightweight aggregate
Microstructural characteristics.
url https://doi.org/10.1038/s41598-025-16048-8
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