The Elevated-Temperature Nano-Mechanical Properties of a PDMS–Silica-Based Superhydrophobic Nanocomposite Coating

This study investigates the elevated-temperature mechanical and viscoelastic properties of a PDMS–silica-based superhydrophobic nanocomposite coating using nanoindentation and a nano-dynamic mechanical analysis over a temperature range of 24 °C to 160 °C. The nanoindentation load–displacement curves...

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Main Authors: Chun-Wei Yao, Ian Lian, Jiang Zhou, Paul Bernazzani, Mien Jao
Format: Article
Language:English
Published: MDPI AG 2025-06-01
Series:Nanomaterials
Subjects:
Online Access:https://www.mdpi.com/2079-4991/15/12/898
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author Chun-Wei Yao
Ian Lian
Jiang Zhou
Paul Bernazzani
Mien Jao
author_facet Chun-Wei Yao
Ian Lian
Jiang Zhou
Paul Bernazzani
Mien Jao
author_sort Chun-Wei Yao
collection DOAJ
description This study investigates the elevated-temperature mechanical and viscoelastic properties of a PDMS–silica-based superhydrophobic nanocomposite coating using nanoindentation and a nano-dynamic mechanical analysis over a temperature range of 24 °C to 160 °C. The nanoindentation load–displacement curves exhibited consistent hysteresis, indicating a stable energy dissipation across the temperature range. Creep tests revealed an increased displacement and accelerated deformation at elevated temperatures, displaying a two-stage creep profile characterized by rapid primary and steady-state secondary creep. The hardness decreased with the creep time, while the strain rate sensitivity remained relatively stable, suggesting consistent deformation mechanisms. A time-dependent creep model incorporating linear and logarithmic terms accurately captured the experimental data. The nano-dynamic mechanical analysis results showed a decrease in the storage modulus with depth, while the loss modulus and tan δ peaked at shallow depths. These findings are crucial for the evaluation and design of superhydrophobic nanocomposite coatings.
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institution Kabale University
issn 2079-4991
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publishDate 2025-06-01
publisher MDPI AG
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series Nanomaterials
spelling doaj-art-a1db84376a884c45a7bfe5d1007607fa2025-08-20T03:29:35ZengMDPI AGNanomaterials2079-49912025-06-01151289810.3390/nano15120898The Elevated-Temperature Nano-Mechanical Properties of a PDMS–Silica-Based Superhydrophobic Nanocomposite CoatingChun-Wei Yao0Ian Lian1Jiang Zhou2Paul Bernazzani3Mien Jao4Department of Mechanical Engineering, Lamar University, Beaumont, TX 77710, USADepartment of Biology, Lamar University, Beaumont, TX 77710, USADepartment of Mechanical Engineering, Lamar University, Beaumont, TX 77710, USADepartment of Chemistry and Biochemistry, Lamar University, Beaumont, TX 77710, USADepartment of Civil and Environmental Engineering, Lamar University, Beaumont, TX 77710, USAThis study investigates the elevated-temperature mechanical and viscoelastic properties of a PDMS–silica-based superhydrophobic nanocomposite coating using nanoindentation and a nano-dynamic mechanical analysis over a temperature range of 24 °C to 160 °C. The nanoindentation load–displacement curves exhibited consistent hysteresis, indicating a stable energy dissipation across the temperature range. Creep tests revealed an increased displacement and accelerated deformation at elevated temperatures, displaying a two-stage creep profile characterized by rapid primary and steady-state secondary creep. The hardness decreased with the creep time, while the strain rate sensitivity remained relatively stable, suggesting consistent deformation mechanisms. A time-dependent creep model incorporating linear and logarithmic terms accurately captured the experimental data. The nano-dynamic mechanical analysis results showed a decrease in the storage modulus with depth, while the loss modulus and tan δ peaked at shallow depths. These findings are crucial for the evaluation and design of superhydrophobic nanocomposite coatings.https://www.mdpi.com/2079-4991/15/12/898nanocompositenanocreepnanoscale dynamic mechanical analysis
spellingShingle Chun-Wei Yao
Ian Lian
Jiang Zhou
Paul Bernazzani
Mien Jao
The Elevated-Temperature Nano-Mechanical Properties of a PDMS–Silica-Based Superhydrophobic Nanocomposite Coating
Nanomaterials
nanocomposite
nanocreep
nanoscale dynamic mechanical analysis
title The Elevated-Temperature Nano-Mechanical Properties of a PDMS–Silica-Based Superhydrophobic Nanocomposite Coating
title_full The Elevated-Temperature Nano-Mechanical Properties of a PDMS–Silica-Based Superhydrophobic Nanocomposite Coating
title_fullStr The Elevated-Temperature Nano-Mechanical Properties of a PDMS–Silica-Based Superhydrophobic Nanocomposite Coating
title_full_unstemmed The Elevated-Temperature Nano-Mechanical Properties of a PDMS–Silica-Based Superhydrophobic Nanocomposite Coating
title_short The Elevated-Temperature Nano-Mechanical Properties of a PDMS–Silica-Based Superhydrophobic Nanocomposite Coating
title_sort elevated temperature nano mechanical properties of a pdms silica based superhydrophobic nanocomposite coating
topic nanocomposite
nanocreep
nanoscale dynamic mechanical analysis
url https://www.mdpi.com/2079-4991/15/12/898
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