Potentially toxic elements (PTEs) in the Carboniferous coal-bearing series of the Lublin Coal Basin (Poland), a case study

During the coal mining process, large amounts of mining waste are produced and disposed of on the surface. This could result in significant quantities of toxic substances being released into the environment. The research material consisted of sedimentary rocks from the Lublin Coal Basin, which are p...

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Main Author: Ewa Krzeszowska
Format: Article
Language:English
Published: Elsevier 2024-12-01
Series:Case Studies in Chemical and Environmental Engineering
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2666016424003785
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author Ewa Krzeszowska
author_facet Ewa Krzeszowska
author_sort Ewa Krzeszowska
collection DOAJ
description During the coal mining process, large amounts of mining waste are produced and disposed of on the surface. This could result in significant quantities of toxic substances being released into the environment. The research material consisted of sedimentary rocks from the Lublin Coal Basin, which are potential waste geomaterial. The research included the chemical composition (SiO2, Al2O3, Fe2O3, CaO, Na2O, K2O, P2O5, MnO, TiO2, and Cr2O3 contents) obtained by XRF and the concentrations of potentially toxic elements (PTEs), such as As, Cd, Cu, Cr, Ni, Pb, and Zn, analyzed by ICP/MS The contents of total carbon and total sulfur obtained by the LECO analyzer. Furthermore, the article discusses the associations between toxic elements, as well as between toxic elements and Al, Si, (TOT/C), and (TOT/S). Analysis of potentially toxic elements (PTEs) as well as Fe concentrations revealed significant heterogeneity in the distribution of these elements in the vertical profile of the formation. The results indicated that the concentrations of toxic elements were As (1–25 ppm), Cd (0.1–0.3 ppm), Cu (2.1–77.9 ppm), Cr (21–179 ppm), Ni (11.2–230.1 ppm), Pb (10.0–52.8 ppm), and Zn (13–178 ppm). It was also found that PTEs concentrations are lower than the permissible values in soils, even in urban and recreational areas (in accordance with Polish legal standards). This indicates that the potential mining waste is not hazardous to the environment during its disposal or utilization.
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spelling doaj-art-a19863cecd50405785c3ab4b09e57c8a2025-08-20T02:17:58ZengElsevierCase Studies in Chemical and Environmental Engineering2666-01642024-12-011010098410.1016/j.cscee.2024.100984Potentially toxic elements (PTEs) in the Carboniferous coal-bearing series of the Lublin Coal Basin (Poland), a case studyEwa Krzeszowska0Silesian University of Technology, 44-100, Gliwice, PolandDuring the coal mining process, large amounts of mining waste are produced and disposed of on the surface. This could result in significant quantities of toxic substances being released into the environment. The research material consisted of sedimentary rocks from the Lublin Coal Basin, which are potential waste geomaterial. The research included the chemical composition (SiO2, Al2O3, Fe2O3, CaO, Na2O, K2O, P2O5, MnO, TiO2, and Cr2O3 contents) obtained by XRF and the concentrations of potentially toxic elements (PTEs), such as As, Cd, Cu, Cr, Ni, Pb, and Zn, analyzed by ICP/MS The contents of total carbon and total sulfur obtained by the LECO analyzer. Furthermore, the article discusses the associations between toxic elements, as well as between toxic elements and Al, Si, (TOT/C), and (TOT/S). Analysis of potentially toxic elements (PTEs) as well as Fe concentrations revealed significant heterogeneity in the distribution of these elements in the vertical profile of the formation. The results indicated that the concentrations of toxic elements were As (1–25 ppm), Cd (0.1–0.3 ppm), Cu (2.1–77.9 ppm), Cr (21–179 ppm), Ni (11.2–230.1 ppm), Pb (10.0–52.8 ppm), and Zn (13–178 ppm). It was also found that PTEs concentrations are lower than the permissible values in soils, even in urban and recreational areas (in accordance with Polish legal standards). This indicates that the potential mining waste is not hazardous to the environment during its disposal or utilization.http://www.sciencedirect.com/science/article/pii/S2666016424003785Potentially toxic elementsWaste geomaterialUtilizationChemical propertiesGeochemistry
spellingShingle Ewa Krzeszowska
Potentially toxic elements (PTEs) in the Carboniferous coal-bearing series of the Lublin Coal Basin (Poland), a case study
Case Studies in Chemical and Environmental Engineering
Potentially toxic elements
Waste geomaterial
Utilization
Chemical properties
Geochemistry
title Potentially toxic elements (PTEs) in the Carboniferous coal-bearing series of the Lublin Coal Basin (Poland), a case study
title_full Potentially toxic elements (PTEs) in the Carboniferous coal-bearing series of the Lublin Coal Basin (Poland), a case study
title_fullStr Potentially toxic elements (PTEs) in the Carboniferous coal-bearing series of the Lublin Coal Basin (Poland), a case study
title_full_unstemmed Potentially toxic elements (PTEs) in the Carboniferous coal-bearing series of the Lublin Coal Basin (Poland), a case study
title_short Potentially toxic elements (PTEs) in the Carboniferous coal-bearing series of the Lublin Coal Basin (Poland), a case study
title_sort potentially toxic elements ptes in the carboniferous coal bearing series of the lublin coal basin poland a case study
topic Potentially toxic elements
Waste geomaterial
Utilization
Chemical properties
Geochemistry
url http://www.sciencedirect.com/science/article/pii/S2666016424003785
work_keys_str_mv AT ewakrzeszowska potentiallytoxicelementsptesinthecarboniferouscoalbearingseriesofthelublincoalbasinpolandacasestudy