Organocatalytic Cascade Reaction of Aliphatic Enals and Benzoylnitromethane: Synthesis of Enantioenriched Tetrasubstituted Cyclohexene Carbaldehyde
A new example of the reactivity of enals with benzoylnitromethane was studied in a Michael-Michael-Aldol-Dehydration quadruple organocascade reaction. The reaction unexpectedly yielded a tetrasubstituted cyclohexene carbaldehyde with excellent enantiomeric excess when crotonaldehyde was used as the...
Saved in:
Main Authors: | Fredy A. David Rodriguez, Mauricio Maldonado Villamil, James Guevara-Pulido |
---|---|
Format: | Article |
Language: | English |
Published: |
Wiley
2020-01-01
|
Series: | Journal of Chemistry |
Online Access: | http://dx.doi.org/10.1155/2020/9248793 |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
Similar Items
-
Recent advances in organocatalytic atroposelective reactions
by: Henrich Szabados, et al.
Published: (2025-01-01) -
2-Chloroquinoline-3-carbaldehyde II: Synthesis, Reactions, and Applications
by: Bakr F. Abdel-Wahab, et al.
Published: (2013-01-01) -
One-Pot Synthesis of Tetrasubstituted Imidazoles Catalyzed by Preyssler-Type Heteropoly Acid
by: Ali Javid, et al.
Published: (2011-01-01) -
Physicochemical Characterization and Asymmetric Catalytic Properties of New Biobased Organocatalytic Surfactants
by: Elliot Calbrix, et al.
Published: (2025-01-01) -
Organocatalytic Packed-Bed Reactors for the Enantioselective Flow Synthesis of Quaternary Isotetronic Acids by Direct Aldol Reactions of Pyruvates
by: Lorenzo Poletti, et al.
Published: (2025-01-01)