Physico-Chemical Studies on the Coordination Compounds of Thiazolidin-4-One
A dry benzene solution of the Schiff base, N-(2-hydroxyphenyl)-3′-carboxy-2′-hydroxybenzylideneimine upon reacting with mercaptoacetic acid undergoes cyclization and forms N-(2-hydroxyphenyl)-C-(3′-carboxy-2′-hydroxyphenyl)thiazolidin-4-one, LH3 (I). A MeOH solution of I reacts with , , , and Mo i...
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| Language: | English |
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Wiley
2013-01-01
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| Series: | Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2013/870325 |
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| author | Dinesh Kumar Amit Kumar Jyoti Sharma |
| author_facet | Dinesh Kumar Amit Kumar Jyoti Sharma |
| author_sort | Dinesh Kumar |
| collection | DOAJ |
| description | A dry benzene solution of the Schiff base, N-(2-hydroxyphenyl)-3′-carboxy-2′-hydroxybenzylideneimine upon reacting with mercaptoacetic acid undergoes cyclization and forms N-(2-hydroxyphenyl)-C-(3′-carboxy-2′-hydroxyphenyl)thiazolidin-4-one, LH3 (I). A MeOH solution of I reacts with ,
, , and Mo ions and forms the monomeric coordination compounds, [Mn(LH)(MeOH)3] (II), [Cu(LH)(MeOH)] (III), [Zn(LH)(MeOH)] (IV), [FeCl(LH)(MeOH)2] (V), and [MoO2(LH)(MeOH)](VI). The coordination compounds have been characterized on the basis of elemental analyses, molar conductance, molecular weight, spectral (IR, reflectance, ESR) studies, and magnetic susceptibility measurements. I behaves as a dibasic tridentate OOS donor ligand in these compounds. The compounds are nonelectrolytes ( = 6.2–13.8 mho cm2 mol−1) in DMF. A square-planar structure for III; a tetrahedral structure for IV and an octahedral structure for II, V, and VI are suggested. |
| format | Article |
| id | doaj-art-a16b3d8f44304a41b17060f5465cad1d |
| institution | Kabale University |
| issn | 2090-9063 2090-9071 |
| language | English |
| publishDate | 2013-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Journal of Chemistry |
| spelling | doaj-art-a16b3d8f44304a41b17060f5465cad1d2025-08-20T03:38:34ZengWileyJournal of Chemistry2090-90632090-90712013-01-01201310.1155/2013/870325870325Physico-Chemical Studies on the Coordination Compounds of Thiazolidin-4-OneDinesh Kumar0Amit Kumar1Jyoti Sharma2Department of Chemistry, National Institute of Technology, Haryana, Kurukshetra 136119, IndiaDepartment of Chemistry, Haryana College of Technology & Management, Haryana, Kaithal 136027, IndiaDepartment of Chemistry, International Institute of Engineering and Technology, Haryana, Kurukshetra 136118, IndiaA dry benzene solution of the Schiff base, N-(2-hydroxyphenyl)-3′-carboxy-2′-hydroxybenzylideneimine upon reacting with mercaptoacetic acid undergoes cyclization and forms N-(2-hydroxyphenyl)-C-(3′-carboxy-2′-hydroxyphenyl)thiazolidin-4-one, LH3 (I). A MeOH solution of I reacts with , , , and Mo ions and forms the monomeric coordination compounds, [Mn(LH)(MeOH)3] (II), [Cu(LH)(MeOH)] (III), [Zn(LH)(MeOH)] (IV), [FeCl(LH)(MeOH)2] (V), and [MoO2(LH)(MeOH)](VI). The coordination compounds have been characterized on the basis of elemental analyses, molar conductance, molecular weight, spectral (IR, reflectance, ESR) studies, and magnetic susceptibility measurements. I behaves as a dibasic tridentate OOS donor ligand in these compounds. The compounds are nonelectrolytes ( = 6.2–13.8 mho cm2 mol−1) in DMF. A square-planar structure for III; a tetrahedral structure for IV and an octahedral structure for II, V, and VI are suggested.http://dx.doi.org/10.1155/2013/870325 |
| spellingShingle | Dinesh Kumar Amit Kumar Jyoti Sharma Physico-Chemical Studies on the Coordination Compounds of Thiazolidin-4-One Journal of Chemistry |
| title | Physico-Chemical Studies on the Coordination Compounds of Thiazolidin-4-One |
| title_full | Physico-Chemical Studies on the Coordination Compounds of Thiazolidin-4-One |
| title_fullStr | Physico-Chemical Studies on the Coordination Compounds of Thiazolidin-4-One |
| title_full_unstemmed | Physico-Chemical Studies on the Coordination Compounds of Thiazolidin-4-One |
| title_short | Physico-Chemical Studies on the Coordination Compounds of Thiazolidin-4-One |
| title_sort | physico chemical studies on the coordination compounds of thiazolidin 4 one |
| url | http://dx.doi.org/10.1155/2013/870325 |
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