Polybutadiene polyurethane acrylate photosensitive resin and its application in 3D printing
High-performance resins that can withstand temperature changes are required to expand the application potential of additive manufacturing (3D printing) in response to increasing demand from various fields. In this study, a novel 3D-printing polybutadiene polyurethane acrylate photosensitive resin na...
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| Format: | Article |
| Language: | English |
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Elsevier
2025-03-01
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| Series: | Journal of Science: Advanced Materials and Devices |
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S2468217924001758 |
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| author | Hang Ning Shaoyun Chen Yan'e Liu Bo Qu Yanyu Zheng Xiaoying Liu Wenjie Li Rui Wang Nairong Chen Dongxian Zhuo |
| author_facet | Hang Ning Shaoyun Chen Yan'e Liu Bo Qu Yanyu Zheng Xiaoying Liu Wenjie Li Rui Wang Nairong Chen Dongxian Zhuo |
| author_sort | Hang Ning |
| collection | DOAJ |
| description | High-performance resins that can withstand temperature changes are required to expand the application potential of additive manufacturing (3D printing) in response to increasing demand from various fields. In this study, a novel 3D-printing polybutadiene polyurethane acrylate photosensitive resin named HTPBMA was prepared by mixing hydroxyl-terminated polybutadiene (HTPB) as the base material with other active diluent monomers and photoinitiators, including hydroxypropyl methacrylate (HPMA). The resulting resins exhibited good rheological properties and rapid photocuring ability, depending on the type and proportion of diluent monomer. In particular, the tensile strength and elongation at break of the sample with a 65:35 HTPBMA:HPMA ratio at −25 °C were 32.9 MPa and 246.1%, respectively, being 2.13 and 1.58 times the values at room temperature, respectively. These results indicate that HTPBMA exhibits excellent low-temperature performance and physical properties. The enhancement mechanism can likely be attributed to introducing of a flexible carbon chain as well as increased cross-linking density (υe). These advantages suggest that the novel photosensitive resin designed and prepared in this study can be used for photocuring 3D printing and maintain excellent performance under extreme climatic conditions. Thus, the proposed HTPBMA has broad application prospects in aerospace and materials science, especially in shoe materials and tires. |
| format | Article |
| id | doaj-art-a0fc5597caf6461990e9810f949f336b |
| institution | DOAJ |
| issn | 2468-2179 |
| language | English |
| publishDate | 2025-03-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Journal of Science: Advanced Materials and Devices |
| spelling | doaj-art-a0fc5597caf6461990e9810f949f336b2025-08-20T03:11:37ZengElsevierJournal of Science: Advanced Materials and Devices2468-21792025-03-0110110084410.1016/j.jsamd.2024.100844Polybutadiene polyurethane acrylate photosensitive resin and its application in 3D printingHang Ning0Shaoyun Chen1Yan'e Liu2Bo Qu3Yanyu Zheng4Xiaoying Liu5Wenjie Li6Rui Wang7Nairong Chen8Dongxian Zhuo9College of Chemical Engineering and Materials Science, Quanzhou Normal University, Quanzhou, Fujian, 362000, PR China; College of Materials Engineering, Fujian Agriculture and Forestry University, Fuzhou, 350002, PR China; Fujian University Engineering Research Center of Polymer Functional Coating based Graphene, Fujian, 362000, PR China; Fujian Key Laboratory of New Materials for Light Textile and Chemical Industry, Fujian, 362000, PR ChinaCollege of Chemical Engineering and Materials Science, Quanzhou Normal University, Quanzhou, Fujian, 362000, PR China; College of Materials Engineering, Fujian Agriculture and Forestry University, Fuzhou, 350002, PR China; Fujian University Engineering Research Center of Polymer Functional Coating based Graphene, Fujian, 362000, PR China; Fujian Key Laboratory of New Materials for Light Textile and Chemical Industry, Fujian, 362000, PR China; Corresponding author. College of Chemical Engineering and Materials Science, Quanzhou Normal University, Quanzhou, Fujian, 362000, PR China.College of Chemical Engineering and Materials Science, Quanzhou Normal University, Quanzhou, Fujian, 362000, PR China; Fujian University Engineering Research Center of Polymer Functional Coating based Graphene, Fujian, 362000, PR China; Fujian Key Laboratory of New Materials for Light Textile and Chemical Industry, Fujian, 362000, PR ChinaCollege of Chemical Engineering and Materials Science, Quanzhou Normal University, Quanzhou, Fujian, 362000, PR China; Fujian University Engineering Research Center of Polymer Functional Coating based Graphene, Fujian, 362000, PR China; Fujian Key Laboratory of New Materials for Light Textile and Chemical Industry, Fujian, 362000, PR ChinaCollege of Chemical Engineering and Materials Science, Quanzhou Normal University, Quanzhou, Fujian, 362000, PR China; Fujian University Engineering Research Center of Polymer Functional Coating based Graphene, Fujian, 362000, PR China; Fujian Key Laboratory of New Materials for Light Textile and Chemical Industry, Fujian, 362000, PR ChinaCollege of Chemical Engineering and Materials Science, Quanzhou Normal University, Quanzhou, Fujian, 362000, PR China; Fujian University Engineering Research Center of Polymer Functional Coating based Graphene, Fujian, 362000, PR China; Fujian Key Laboratory of New Materials for Light Textile and Chemical Industry, Fujian, 362000, PR ChinaCollege of Chemical Engineering and Materials Science, Quanzhou Normal University, Quanzhou, Fujian, 362000, PR China; Fujian University Engineering Research Center of Polymer Functional Coating based Graphene, Fujian, 362000, PR China; Fujian Key Laboratory of New Materials for Light Textile and Chemical Industry, Fujian, 362000, PR ChinaCollege of Chemical Engineering and Materials Science, Quanzhou Normal University, Quanzhou, Fujian, 362000, PR China; Fujian University Engineering Research Center of Polymer Functional Coating based Graphene, Fujian, 362000, PR China; Fujian Key Laboratory of New Materials for Light Textile and Chemical Industry, Fujian, 362000, PR ChinaCollege of Materials Engineering, Fujian Agriculture and Forestry University, Fuzhou, 350002, PR China; Corresponding author. College of Materials Engineering, Fujian Agriculture and Forestry University, Fuzhou 350002, China.College of Chemical Engineering and Materials Science, Quanzhou Normal University, Quanzhou, Fujian, 362000, PR China; College of Materials Engineering, Fujian Agriculture and Forestry University, Fuzhou, 350002, PR China; Fujian University Engineering Research Center of Polymer Functional Coating based Graphene, Fujian, 362000, PR China; Fujian Key Laboratory of New Materials for Light Textile and Chemical Industry, Fujian, 362000, PR China; Corresponding author. College of Chemical Engineering and Materials Science, Quanzhou Normal University, Quanzhou, Fujian, 362000, PR China.High-performance resins that can withstand temperature changes are required to expand the application potential of additive manufacturing (3D printing) in response to increasing demand from various fields. In this study, a novel 3D-printing polybutadiene polyurethane acrylate photosensitive resin named HTPBMA was prepared by mixing hydroxyl-terminated polybutadiene (HTPB) as the base material with other active diluent monomers and photoinitiators, including hydroxypropyl methacrylate (HPMA). The resulting resins exhibited good rheological properties and rapid photocuring ability, depending on the type and proportion of diluent monomer. In particular, the tensile strength and elongation at break of the sample with a 65:35 HTPBMA:HPMA ratio at −25 °C were 32.9 MPa and 246.1%, respectively, being 2.13 and 1.58 times the values at room temperature, respectively. These results indicate that HTPBMA exhibits excellent low-temperature performance and physical properties. The enhancement mechanism can likely be attributed to introducing of a flexible carbon chain as well as increased cross-linking density (υe). These advantages suggest that the novel photosensitive resin designed and prepared in this study can be used for photocuring 3D printing and maintain excellent performance under extreme climatic conditions. Thus, the proposed HTPBMA has broad application prospects in aerospace and materials science, especially in shoe materials and tires.http://www.sciencedirect.com/science/article/pii/S2468217924001758Hydroxyl-terminated polyurethaneThree-dimensional printingMechanical propertiesTemperature resistance |
| spellingShingle | Hang Ning Shaoyun Chen Yan'e Liu Bo Qu Yanyu Zheng Xiaoying Liu Wenjie Li Rui Wang Nairong Chen Dongxian Zhuo Polybutadiene polyurethane acrylate photosensitive resin and its application in 3D printing Journal of Science: Advanced Materials and Devices Hydroxyl-terminated polyurethane Three-dimensional printing Mechanical properties Temperature resistance |
| title | Polybutadiene polyurethane acrylate photosensitive resin and its application in 3D printing |
| title_full | Polybutadiene polyurethane acrylate photosensitive resin and its application in 3D printing |
| title_fullStr | Polybutadiene polyurethane acrylate photosensitive resin and its application in 3D printing |
| title_full_unstemmed | Polybutadiene polyurethane acrylate photosensitive resin and its application in 3D printing |
| title_short | Polybutadiene polyurethane acrylate photosensitive resin and its application in 3D printing |
| title_sort | polybutadiene polyurethane acrylate photosensitive resin and its application in 3d printing |
| topic | Hydroxyl-terminated polyurethane Three-dimensional printing Mechanical properties Temperature resistance |
| url | http://www.sciencedirect.com/science/article/pii/S2468217924001758 |
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