Effect of self-healing of cracks in chloride ion diffusion and corrosion of engineered cementitious composites

This study investigates the chloride penetration resistance and electrochemical behavior of self-healing engineered cementitious composites (ECC). The experimental program involved exposing cracked ECC samples to NaCl solution, while monitoring chloride penetration and self-healing using water-perme...

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Main Authors: Abel Shiferaw Alemu, Gebremicael Liyew, Bang Yeon Lee, Hyeong-Ki Kim
Format: Article
Language:English
Published: Elsevier 2025-03-01
Series:Journal of Materials Research and Technology
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2238785425000389
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author Abel Shiferaw Alemu
Gebremicael Liyew
Bang Yeon Lee
Hyeong-Ki Kim
author_facet Abel Shiferaw Alemu
Gebremicael Liyew
Bang Yeon Lee
Hyeong-Ki Kim
author_sort Abel Shiferaw Alemu
collection DOAJ
description This study investigates the chloride penetration resistance and electrochemical behavior of self-healing engineered cementitious composites (ECC). The experimental program involved exposing cracked ECC samples to NaCl solution, while monitoring chloride penetration and self-healing using water-permeability tests. Electrochemical measurements, including open circuit potential, linear polarization resistance, and electrochemical impedance spectroscopy, were used to evaluate reinforcement corrosion over a 91-day period. Results show that water-tightness does not guarantee protection against chloride ingress, as cracks with widths exceeding 0.15 mm allowed chloride penetration despite self-healing. Reinforcement depassivation occurred within 1–3 days of chloride exposure, but self-healing reduced the corrosion current back to pre-crack levels within 1–2 months, highlighting its role in delaying corrosion propagation. These findings emphasize the importance of crack width control in achieving effective self-healing and suggest that electrochemical impedance spectroscopy is a useful technique for monitoring the self-healing process in reinforced ECC structures.
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institution Kabale University
issn 2238-7854
language English
publishDate 2025-03-01
publisher Elsevier
record_format Article
series Journal of Materials Research and Technology
spelling doaj-art-a09e4b1e2d2344f59ef9dea1b0a4a1ec2025-01-18T05:04:44ZengElsevierJournal of Materials Research and Technology2238-78542025-03-013510541071Effect of self-healing of cracks in chloride ion diffusion and corrosion of engineered cementitious compositesAbel Shiferaw Alemu0Gebremicael Liyew1Bang Yeon Lee2Hyeong-Ki Kim3Department of Architectural Engineering, Chosun University, Gwangju 61452, Republic of KoreaDepartment of Architectural Engineering, Chosun University, Gwangju 61452, Republic of KoreaSchool of Architecture, Chonnam National University, Gwangju 61186, Republic of KoreaDepartment of Architectural Engineering, Chosun University, Gwangju 61452, Republic of Korea; Corresponding author.This study investigates the chloride penetration resistance and electrochemical behavior of self-healing engineered cementitious composites (ECC). The experimental program involved exposing cracked ECC samples to NaCl solution, while monitoring chloride penetration and self-healing using water-permeability tests. Electrochemical measurements, including open circuit potential, linear polarization resistance, and electrochemical impedance spectroscopy, were used to evaluate reinforcement corrosion over a 91-day period. Results show that water-tightness does not guarantee protection against chloride ingress, as cracks with widths exceeding 0.15 mm allowed chloride penetration despite self-healing. Reinforcement depassivation occurred within 1–3 days of chloride exposure, but self-healing reduced the corrosion current back to pre-crack levels within 1–2 months, highlighting its role in delaying corrosion propagation. These findings emphasize the importance of crack width control in achieving effective self-healing and suggest that electrochemical impedance spectroscopy is a useful technique for monitoring the self-healing process in reinforced ECC structures.http://www.sciencedirect.com/science/article/pii/S2238785425000389Engineered cementitious composites (ECC)CorrosionSelf healingCrackChloride attackDurability
spellingShingle Abel Shiferaw Alemu
Gebremicael Liyew
Bang Yeon Lee
Hyeong-Ki Kim
Effect of self-healing of cracks in chloride ion diffusion and corrosion of engineered cementitious composites
Journal of Materials Research and Technology
Engineered cementitious composites (ECC)
Corrosion
Self healing
Crack
Chloride attack
Durability
title Effect of self-healing of cracks in chloride ion diffusion and corrosion of engineered cementitious composites
title_full Effect of self-healing of cracks in chloride ion diffusion and corrosion of engineered cementitious composites
title_fullStr Effect of self-healing of cracks in chloride ion diffusion and corrosion of engineered cementitious composites
title_full_unstemmed Effect of self-healing of cracks in chloride ion diffusion and corrosion of engineered cementitious composites
title_short Effect of self-healing of cracks in chloride ion diffusion and corrosion of engineered cementitious composites
title_sort effect of self healing of cracks in chloride ion diffusion and corrosion of engineered cementitious composites
topic Engineered cementitious composites (ECC)
Corrosion
Self healing
Crack
Chloride attack
Durability
url http://www.sciencedirect.com/science/article/pii/S2238785425000389
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AT gebremicaelliyew effectofselfhealingofcracksinchlorideiondiffusionandcorrosionofengineeredcementitiouscomposites
AT bangyeonlee effectofselfhealingofcracksinchlorideiondiffusionandcorrosionofengineeredcementitiouscomposites
AT hyeongkikim effectofselfhealingofcracksinchlorideiondiffusionandcorrosionofengineeredcementitiouscomposites