A Review of End‐of‐Life Silicon Solar Photovoltaic Modules and the Potential for Electrochemical Recycling

The mass deployment of solar energy technology has been inspired by sustainable energy objectives. However, end‐of‐life solar photovoltaic modules present the growing dilemma of solar waste management. A circular economy approach should therefore be applied to the solar industry due to the valuable...

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Main Authors: Jackson Lee, Noel Duffy, Jessica Allen
Format: Article
Language:English
Published: Wiley-VCH 2025-02-01
Series:Advanced Energy & Sustainability Research
Subjects:
Online Access:https://doi.org/10.1002/aesr.202400254
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author Jackson Lee
Noel Duffy
Jessica Allen
author_facet Jackson Lee
Noel Duffy
Jessica Allen
author_sort Jackson Lee
collection DOAJ
description The mass deployment of solar energy technology has been inspired by sustainable energy objectives. However, end‐of‐life solar photovoltaic modules present the growing dilemma of solar waste management. A circular economy approach should therefore be applied to the solar industry due to the valuable materials contained within modules, and their upfront emissions and energy intensity. Solar module recycling has to date been delineated into three phases: disassembly, delamination, and extraction. Disassembly has been commercially established; delamination has experienced some progression with further development required to liberate the valuable solar cell material, while extraction has had more limited exploration, predominantly through a hydrometallurgical lens. Extraction via electrochemical methods, however, has received some recent attention in the literature with promising outcomes for both metal extraction and process electrification. Electrochemical approaches offer new methods for more advanced processing options. For example, high‐temperature molten salt electrorefining has been investigated for metallurgical‐grade silicon and could prove to be an effective process for recovering silicon. This review provides an overview of solar module recovery methods, with focus on novel and emerging electrochemical approaches including the applicability of electrorefining to upgrade recovered silicon from photovoltaic waste.
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spelling doaj-art-a08a5799888140a1a169aa9ce4517fa82025-02-06T18:50:31ZengWiley-VCHAdvanced Energy & Sustainability Research2699-94122025-02-0162n/an/a10.1002/aesr.202400254A Review of End‐of‐Life Silicon Solar Photovoltaic Modules and the Potential for Electrochemical RecyclingJackson Lee0Noel Duffy1Jessica Allen2Chemical Engineering University of Newcastle Callaghan NSW 2308 AustraliaCSIRO Energy Clayton Victoria 3168 AustraliaChemical Engineering University of Newcastle Callaghan NSW 2308 AustraliaThe mass deployment of solar energy technology has been inspired by sustainable energy objectives. However, end‐of‐life solar photovoltaic modules present the growing dilemma of solar waste management. A circular economy approach should therefore be applied to the solar industry due to the valuable materials contained within modules, and their upfront emissions and energy intensity. Solar module recycling has to date been delineated into three phases: disassembly, delamination, and extraction. Disassembly has been commercially established; delamination has experienced some progression with further development required to liberate the valuable solar cell material, while extraction has had more limited exploration, predominantly through a hydrometallurgical lens. Extraction via electrochemical methods, however, has received some recent attention in the literature with promising outcomes for both metal extraction and process electrification. Electrochemical approaches offer new methods for more advanced processing options. For example, high‐temperature molten salt electrorefining has been investigated for metallurgical‐grade silicon and could prove to be an effective process for recovering silicon. This review provides an overview of solar module recovery methods, with focus on novel and emerging electrochemical approaches including the applicability of electrorefining to upgrade recovered silicon from photovoltaic waste.https://doi.org/10.1002/aesr.202400254circular economyelectrochemicalelectrorefiningphotovoltaicsrecycling
spellingShingle Jackson Lee
Noel Duffy
Jessica Allen
A Review of End‐of‐Life Silicon Solar Photovoltaic Modules and the Potential for Electrochemical Recycling
Advanced Energy & Sustainability Research
circular economy
electrochemical
electrorefining
photovoltaics
recycling
title A Review of End‐of‐Life Silicon Solar Photovoltaic Modules and the Potential for Electrochemical Recycling
title_full A Review of End‐of‐Life Silicon Solar Photovoltaic Modules and the Potential for Electrochemical Recycling
title_fullStr A Review of End‐of‐Life Silicon Solar Photovoltaic Modules and the Potential for Electrochemical Recycling
title_full_unstemmed A Review of End‐of‐Life Silicon Solar Photovoltaic Modules and the Potential for Electrochemical Recycling
title_short A Review of End‐of‐Life Silicon Solar Photovoltaic Modules and the Potential for Electrochemical Recycling
title_sort review of end of life silicon solar photovoltaic modules and the potential for electrochemical recycling
topic circular economy
electrochemical
electrorefining
photovoltaics
recycling
url https://doi.org/10.1002/aesr.202400254
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