A Trinuclear Co(II) Complex Based on the Tris-Dioxolene Triphenylene Non-Innocent Bridge: Complementary Redox, Magnetic Behavior and Theoretical Calculations

A trinuclear Co(II)-containing complex was assembled using the non-innocent hexahydroxytriphenylene bridging ligand. Cyclovoltammetry and spectroelectrochemistry studies revealed that the central ligand sustained four reversible redox events, leading to different species with diverse optical behavio...

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Main Authors: Aristide Colin, Yiting Wang, François Lambert, Nathalie Bridonneau, Nicolas Suaud, Régis Guillot, Eric Rivière, Zakaria Halime, Nathalie Guihéry, Shin-ichi Ohkoshi, Talal Mallah
Format: Article
Language:English
Published: MDPI AG 2024-12-01
Series:Magnetochemistry
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Online Access:https://www.mdpi.com/2312-7481/10/12/102
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author Aristide Colin
Yiting Wang
François Lambert
Nathalie Bridonneau
Nicolas Suaud
Régis Guillot
Eric Rivière
Zakaria Halime
Nathalie Guihéry
Shin-ichi Ohkoshi
Talal Mallah
author_facet Aristide Colin
Yiting Wang
François Lambert
Nathalie Bridonneau
Nicolas Suaud
Régis Guillot
Eric Rivière
Zakaria Halime
Nathalie Guihéry
Shin-ichi Ohkoshi
Talal Mallah
author_sort Aristide Colin
collection DOAJ
description A trinuclear Co(II)-containing complex was assembled using the non-innocent hexahydroxytriphenylene bridging ligand. Cyclovoltammetry and spectroelectrochemistry studies revealed that the central ligand sustained four reversible redox events, leading to different species with diverse optical behavior. Complementary analysis of the molecular structure confirmed by ab initio theoretical calculations were consistent with the bridge in the tris-semiquinone (sq) state for the trinuclear complex. The exchange coupling among the electrons of the bridge resulted in a spin doublet (<i>s</i> = ½) localized close to one of the three Co<sup>2+</sup> ions, as suggested by the experimental magnetic data. The central doublet underwent one large antiferromagnetic exchange coupling with one Co(II) and almost no coupling with the two other metal ions.
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issn 2312-7481
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publisher MDPI AG
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series Magnetochemistry
spelling doaj-art-a007bec384964fdeb4f0d2e166782d132025-08-20T02:50:59ZengMDPI AGMagnetochemistry2312-74812024-12-01101210210.3390/magnetochemistry10120102A Trinuclear Co(II) Complex Based on the Tris-Dioxolene Triphenylene Non-Innocent Bridge: Complementary Redox, Magnetic Behavior and Theoretical CalculationsAristide Colin0Yiting Wang1François Lambert2Nathalie Bridonneau3Nicolas Suaud4Régis Guillot5Eric Rivière6Zakaria Halime7Nathalie Guihéry8Shin-ichi Ohkoshi9Talal Mallah10Institut de Chimie Moléculaire et des Matériaux d’Orsay, CNRS, Université Paris-Saclay, 17, Avenue des Sciences, 91400 Orsay, FranceInstitut de Chimie Moléculaire et des Matériaux d’Orsay, CNRS, Université Paris-Saclay, 17, Avenue des Sciences, 91400 Orsay, FranceInstitut de Chimie Moléculaire et des Matériaux d’Orsay, CNRS, Université Paris-Saclay, 17, Avenue des Sciences, 91400 Orsay, FranceInstitut de Chimie Moléculaire et des Matériaux d’Orsay, CNRS, Université Paris-Saclay, 17, Avenue des Sciences, 91400 Orsay, FranceLaboratoire de Chimie et Physique Quantiques (LCPQ), Université de Toulouse, CNRS, 118 Route de Narbonne, 31062 Toulouse, FranceInstitut de Chimie Moléculaire et des Matériaux d’Orsay, CNRS, Université Paris-Saclay, 17, Avenue des Sciences, 91400 Orsay, FranceInstitut de Chimie Moléculaire et des Matériaux d’Orsay, CNRS, Université Paris-Saclay, 17, Avenue des Sciences, 91400 Orsay, FranceInstitut de Chimie Moléculaire et des Matériaux d’Orsay, CNRS, Université Paris-Saclay, 17, Avenue des Sciences, 91400 Orsay, FranceLaboratoire de Chimie et Physique Quantiques (LCPQ), Université de Toulouse, CNRS, 118 Route de Narbonne, 31062 Toulouse, FranceDepartment of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, JapanInstitut de Chimie Moléculaire et des Matériaux d’Orsay, CNRS, Université Paris-Saclay, 17, Avenue des Sciences, 91400 Orsay, FranceA trinuclear Co(II)-containing complex was assembled using the non-innocent hexahydroxytriphenylene bridging ligand. Cyclovoltammetry and spectroelectrochemistry studies revealed that the central ligand sustained four reversible redox events, leading to different species with diverse optical behavior. Complementary analysis of the molecular structure confirmed by ab initio theoretical calculations were consistent with the bridge in the tris-semiquinone (sq) state for the trinuclear complex. The exchange coupling among the electrons of the bridge resulted in a spin doublet (<i>s</i> = ½) localized close to one of the three Co<sup>2+</sup> ions, as suggested by the experimental magnetic data. The central doublet underwent one large antiferromagnetic exchange coupling with one Co(II) and almost no coupling with the two other metal ions.https://www.mdpi.com/2312-7481/10/12/102hexahydroxytriphenylenenon-innocent bridgetrinuclear Co complexspectroelectrochemistryCo magnetismab initio calculations
spellingShingle Aristide Colin
Yiting Wang
François Lambert
Nathalie Bridonneau
Nicolas Suaud
Régis Guillot
Eric Rivière
Zakaria Halime
Nathalie Guihéry
Shin-ichi Ohkoshi
Talal Mallah
A Trinuclear Co(II) Complex Based on the Tris-Dioxolene Triphenylene Non-Innocent Bridge: Complementary Redox, Magnetic Behavior and Theoretical Calculations
Magnetochemistry
hexahydroxytriphenylene
non-innocent bridge
trinuclear Co complex
spectroelectrochemistry
Co magnetism
ab initio calculations
title A Trinuclear Co(II) Complex Based on the Tris-Dioxolene Triphenylene Non-Innocent Bridge: Complementary Redox, Magnetic Behavior and Theoretical Calculations
title_full A Trinuclear Co(II) Complex Based on the Tris-Dioxolene Triphenylene Non-Innocent Bridge: Complementary Redox, Magnetic Behavior and Theoretical Calculations
title_fullStr A Trinuclear Co(II) Complex Based on the Tris-Dioxolene Triphenylene Non-Innocent Bridge: Complementary Redox, Magnetic Behavior and Theoretical Calculations
title_full_unstemmed A Trinuclear Co(II) Complex Based on the Tris-Dioxolene Triphenylene Non-Innocent Bridge: Complementary Redox, Magnetic Behavior and Theoretical Calculations
title_short A Trinuclear Co(II) Complex Based on the Tris-Dioxolene Triphenylene Non-Innocent Bridge: Complementary Redox, Magnetic Behavior and Theoretical Calculations
title_sort trinuclear co ii complex based on the tris dioxolene triphenylene non innocent bridge complementary redox magnetic behavior and theoretical calculations
topic hexahydroxytriphenylene
non-innocent bridge
trinuclear Co complex
spectroelectrochemistry
Co magnetism
ab initio calculations
url https://www.mdpi.com/2312-7481/10/12/102
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