Preparation, Characterization, and Antimicrobial Activities of Bimetallic Complexes of Sarcosine with Zn(II) and Sn(IV)
Heterobimetallic complexes of Zn(II) and Sn(IV) with sarcosine have been synthesized at room temperature under stirring conditions by the reaction of sarcosine and zinc acetate in 2 : 1 molar ratio followed by the stepwise addition of CS2 and organotin(IV) halides, where R = Me, n-Bu, and Ph. The co...
Saved in:
Main Authors: | , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
Wiley
2013-01-01
|
Series: | Bioinorganic Chemistry and Applications |
Online Access: | http://dx.doi.org/10.1155/2013/351262 |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
_version_ | 1832553350303842304 |
---|---|
author | Yasir Arafat Saqib Ali Saira Shahzadi Muhammad Shahid |
author_facet | Yasir Arafat Saqib Ali Saira Shahzadi Muhammad Shahid |
author_sort | Yasir Arafat |
collection | DOAJ |
description | Heterobimetallic complexes of Zn(II) and Sn(IV) with sarcosine have been synthesized at room temperature under stirring conditions by the reaction of sarcosine and zinc acetate in 2 : 1 molar ratio followed by the stepwise addition of CS2 and organotin(IV) halides, where R = Me, n-Bu, and Ph. The complexes were characterized by elemental analysis, FT-IR and NMR (1H, 13C) spectroscopy. IR data showed that the ligand acts in a bidentate manner. NMR data revealed the four coordinate geometry in solution state. In vitro antimicrobial activities data showed that complexes (3) and (4) were effective against bacterial and fungal strains with few exceptions. |
format | Article |
id | doaj-art-9f952e9bf2834d5a8658e2effe890045 |
institution | Kabale University |
issn | 1565-3633 1687-479X |
language | English |
publishDate | 2013-01-01 |
publisher | Wiley |
record_format | Article |
series | Bioinorganic Chemistry and Applications |
spelling | doaj-art-9f952e9bf2834d5a8658e2effe8900452025-02-03T05:54:14ZengWileyBioinorganic Chemistry and Applications1565-36331687-479X2013-01-01201310.1155/2013/351262351262Preparation, Characterization, and Antimicrobial Activities of Bimetallic Complexes of Sarcosine with Zn(II) and Sn(IV)Yasir Arafat0Saqib Ali1Saira Shahzadi2Muhammad Shahid3Department of Chemistry, GC University, Faisalabad 38000, PakistanDepartment of Chemistry, Quaid-i-Azam University, Islamabad 45320, PakistanDepartment of Chemistry, GC University, Faisalabad 38000, PakistanDepartment of Chemistry and Biochemistry, University of Agriculture, Faisalabad 38000, PakistanHeterobimetallic complexes of Zn(II) and Sn(IV) with sarcosine have been synthesized at room temperature under stirring conditions by the reaction of sarcosine and zinc acetate in 2 : 1 molar ratio followed by the stepwise addition of CS2 and organotin(IV) halides, where R = Me, n-Bu, and Ph. The complexes were characterized by elemental analysis, FT-IR and NMR (1H, 13C) spectroscopy. IR data showed that the ligand acts in a bidentate manner. NMR data revealed the four coordinate geometry in solution state. In vitro antimicrobial activities data showed that complexes (3) and (4) were effective against bacterial and fungal strains with few exceptions.http://dx.doi.org/10.1155/2013/351262 |
spellingShingle | Yasir Arafat Saqib Ali Saira Shahzadi Muhammad Shahid Preparation, Characterization, and Antimicrobial Activities of Bimetallic Complexes of Sarcosine with Zn(II) and Sn(IV) Bioinorganic Chemistry and Applications |
title | Preparation, Characterization, and Antimicrobial Activities of Bimetallic Complexes of Sarcosine with Zn(II) and Sn(IV) |
title_full | Preparation, Characterization, and Antimicrobial Activities of Bimetallic Complexes of Sarcosine with Zn(II) and Sn(IV) |
title_fullStr | Preparation, Characterization, and Antimicrobial Activities of Bimetallic Complexes of Sarcosine with Zn(II) and Sn(IV) |
title_full_unstemmed | Preparation, Characterization, and Antimicrobial Activities of Bimetallic Complexes of Sarcosine with Zn(II) and Sn(IV) |
title_short | Preparation, Characterization, and Antimicrobial Activities of Bimetallic Complexes of Sarcosine with Zn(II) and Sn(IV) |
title_sort | preparation characterization and antimicrobial activities of bimetallic complexes of sarcosine with zn ii and sn iv |
url | http://dx.doi.org/10.1155/2013/351262 |
work_keys_str_mv | AT yasirarafat preparationcharacterizationandantimicrobialactivitiesofbimetalliccomplexesofsarcosinewithzniiandsniv AT saqibali preparationcharacterizationandantimicrobialactivitiesofbimetalliccomplexesofsarcosinewithzniiandsniv AT sairashahzadi preparationcharacterizationandantimicrobialactivitiesofbimetalliccomplexesofsarcosinewithzniiandsniv AT muhammadshahid preparationcharacterizationandantimicrobialactivitiesofbimetalliccomplexesofsarcosinewithzniiandsniv |