Impact of Ag2O on physical and electrical properties of Li2O-MgO-Bi2O3-SiO2 glass system as promising solid state electrolytes
Abstract The intrinsic aim of this work is to understand the influence of composition change on the physical-electrical parameters of glasses with the composition (20-Y) Li2O-YAg2O–20MgO–10Bi2O3-50SiO2 (Y = 0.25, 0.5, 1.0, 2.0 and 4.0 mol%). The results of the physical parameters indicate a growth i...
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| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2025-02-01
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| Series: | Scientific Reports |
| Subjects: | |
| Online Access: | https://doi.org/10.1038/s41598-025-87463-0 |
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| Summary: | Abstract The intrinsic aim of this work is to understand the influence of composition change on the physical-electrical parameters of glasses with the composition (20-Y) Li2O-YAg2O–20MgO–10Bi2O3-50SiO2 (Y = 0.25, 0.5, 1.0, 2.0 and 4.0 mol%). The results of the physical parameters indicate a growth in the strength of the glass structure with the increase replacement of Li2O by Ag2O. However, the decrease in loss factor ε″, and AC conductivity σ ac of glasses may be attributed to the decrease in the space charge polarization (scp). AC conductivities exhibit simple power law variation. The s values essentially lie in the range of 0.67–0.92, which is typical of conductors in Jonscher regime. Dielectric properties (constant ε′, loss ε″ and ac conductivity σac, over a range of frequency 100–100 kHz and temperature RT (Room Temperature)–200 °C and frequency exponent s) of these glasses have been studied The results indicate a great potential of the prepared glasses as promising materials that can be used for solid state electrolytes. |
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| ISSN: | 2045-2322 |