Extraction approaches for the isolation of some POPs from lipid-based environmental and food matrices: A review
This review examined various analytical approaches for extracting some persistent organic pollutants (POPs) from environmental and food matrices containing lipid components. The impact of the lipid component on the extraction of such hazardous chemicals from fatty matrices is well-known due to their...
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| Format: | Article |
| Language: | English |
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De Gruyter
2025-01-01
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| Series: | Reviews in Analytical Chemistry |
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| Online Access: | https://doi.org/10.1515/revac-2023-0081 |
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| author | Carriera Fabiana Di Fiore Cristina Iannone Alessia Maio Monica Avino Pasquale |
| author_facet | Carriera Fabiana Di Fiore Cristina Iannone Alessia Maio Monica Avino Pasquale |
| author_sort | Carriera Fabiana |
| collection | DOAJ |
| description | This review examined various analytical approaches for extracting some persistent organic pollutants (POPs) from environmental and food matrices containing lipid components. The impact of the lipid component on the extraction of such hazardous chemicals from fatty matrices is well-known due to their lipophilicity. The analysis of the scientific literature revealed different approaches, typically characterized by the use of a solvent mixture that leads to the co-extraction of lipid components, followed by one or more laborious clean-up steps to remove the interferents from the matrix. Despite the differences in the approaches used, the observed recoveries are high, >80%. Additionally, it was found that the same technique could extract different contaminants from various matrices, resulting in a loss of selectivity of the method used. The uncertainties suggested in this review consider (i) the actual extraction of POPs with polar solvents (e.g., acetonitrile) from lipid component, for which POPs may have higher retention; (ii) the use of laborious, long cleaning steps (e.g., polar and non-polar adsorbent phases) could affect recoveries; (iii) the absence of studies investigating the concrete and constant distribution of POPs between extractive solvent/lipid component and solvent/adsorbent phase. Further, the recent application of eutectic solvents was discussed as a promising approach towards a green chemistry procedure. |
| format | Article |
| id | doaj-art-9f319ae6ba4640c2bc01f1048a0639c2 |
| institution | Kabale University |
| issn | 2191-0189 |
| language | English |
| publishDate | 2025-01-01 |
| publisher | De Gruyter |
| record_format | Article |
| series | Reviews in Analytical Chemistry |
| spelling | doaj-art-9f319ae6ba4640c2bc01f1048a0639c22025-02-02T15:46:46ZengDe GruyterReviews in Analytical Chemistry2191-01892025-01-01441486410.1515/revac-2023-0081Extraction approaches for the isolation of some POPs from lipid-based environmental and food matrices: A reviewCarriera Fabiana0Di Fiore Cristina1Iannone Alessia2Maio Monica3Avino Pasquale4Department of Agriculture, Environmental and Food Sciences, via F. De Sanctis, 86100, Campobasso, ItalyDepartment of Agriculture, Environmental and Food Sciences, via F. De Sanctis, 86100, Campobasso, ItalyDepartment of Agriculture, Environmental and Food Sciences, via F. De Sanctis, 86100, Campobasso, ItalyDepartment of Agriculture, Environmental and Food Sciences, via F. De Sanctis, 86100, Campobasso, ItalyDepartment of Agriculture, Environmental and Food Sciences, via F. De Sanctis, 86100, Campobasso, ItalyThis review examined various analytical approaches for extracting some persistent organic pollutants (POPs) from environmental and food matrices containing lipid components. The impact of the lipid component on the extraction of such hazardous chemicals from fatty matrices is well-known due to their lipophilicity. The analysis of the scientific literature revealed different approaches, typically characterized by the use of a solvent mixture that leads to the co-extraction of lipid components, followed by one or more laborious clean-up steps to remove the interferents from the matrix. Despite the differences in the approaches used, the observed recoveries are high, >80%. Additionally, it was found that the same technique could extract different contaminants from various matrices, resulting in a loss of selectivity of the method used. The uncertainties suggested in this review consider (i) the actual extraction of POPs with polar solvents (e.g., acetonitrile) from lipid component, for which POPs may have higher retention; (ii) the use of laborious, long cleaning steps (e.g., polar and non-polar adsorbent phases) could affect recoveries; (iii) the absence of studies investigating the concrete and constant distribution of POPs between extractive solvent/lipid component and solvent/adsorbent phase. Further, the recent application of eutectic solvents was discussed as a promising approach towards a green chemistry procedure.https://doi.org/10.1515/revac-2023-0081extractionlipidspersistent organic pollutantsfoodenvironment |
| spellingShingle | Carriera Fabiana Di Fiore Cristina Iannone Alessia Maio Monica Avino Pasquale Extraction approaches for the isolation of some POPs from lipid-based environmental and food matrices: A review Reviews in Analytical Chemistry extraction lipids persistent organic pollutants food environment |
| title | Extraction approaches for the isolation of some POPs from lipid-based environmental and food matrices: A review |
| title_full | Extraction approaches for the isolation of some POPs from lipid-based environmental and food matrices: A review |
| title_fullStr | Extraction approaches for the isolation of some POPs from lipid-based environmental and food matrices: A review |
| title_full_unstemmed | Extraction approaches for the isolation of some POPs from lipid-based environmental and food matrices: A review |
| title_short | Extraction approaches for the isolation of some POPs from lipid-based environmental and food matrices: A review |
| title_sort | extraction approaches for the isolation of some pops from lipid based environmental and food matrices a review |
| topic | extraction lipids persistent organic pollutants food environment |
| url | https://doi.org/10.1515/revac-2023-0081 |
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