Microalgae-based treatment of produced water: A comparison between synthetic and a representative real produced water

This work evaluates the potential of microalgae Scenedesmus obliquus to treat different synthetic and real PW of different compositions. Four different synthetic PW (SPWs) were formulated using crude oil, sodium dodecyl sulfate (SDS), and xanthan gum. It was found that S. obliquus could grow in all...

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Main Authors: Hussain Ali Al Subaie, Nur Farahah Khairuddin, Muhammad Nawaz Tahir, Muslim Aqeel Alhaddad, Mohammed Omar Faruque, Shaikh Abdur Razzak, Basheer Chanbasha, Ahsan Mushir Shamsi, Muhammad Shahzad Kamal, Wasif Farooq
Format: Article
Language:English
Published: Elsevier 2025-09-01
Series:Results in Engineering
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Online Access:http://www.sciencedirect.com/science/article/pii/S259012302502746X
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author Hussain Ali Al Subaie
Nur Farahah Khairuddin
Muhammad Nawaz Tahir
Muslim Aqeel Alhaddad
Mohammed Omar Faruque
Shaikh Abdur Razzak
Basheer Chanbasha
Ahsan Mushir Shamsi
Muhammad Shahzad Kamal
Wasif Farooq
author_facet Hussain Ali Al Subaie
Nur Farahah Khairuddin
Muhammad Nawaz Tahir
Muslim Aqeel Alhaddad
Mohammed Omar Faruque
Shaikh Abdur Razzak
Basheer Chanbasha
Ahsan Mushir Shamsi
Muhammad Shahzad Kamal
Wasif Farooq
author_sort Hussain Ali Al Subaie
collection DOAJ
description This work evaluates the potential of microalgae Scenedesmus obliquus to treat different synthetic and real PW of different compositions. Four different synthetic PW (SPWs) were formulated using crude oil, sodium dodecyl sulfate (SDS), and xanthan gum. It was found that S. obliquus could grow in all SPW with low and high salinity tested in this study. The presence of crude oil in synthetic PW hinders the algae's growth. No growth was observed in 100 % real-produced water (RPW) despite supplementation with essential growth nutrients. However, the algae cells could grow in 50 % diluted RPW, supplemented with nutrients. However, the growth of algae in 50 % v/v diluted RPW was the lowest compared to all SPW, despite having the same nutrients and salinity level. These results indicate that the presence of hydrocarbons from crude oil poses a major challenge to algae-based decontamination. Total organic carbon levels increased in all samples during growth, and nitrogen consumption was positively correlated with the algal growth rate. Barium (Ba) and Copper (Cu) metals were removed from RPW during S. obliquus cultivation. Some of the hydrocarbons present in 50 % diluted RPW were removed during cultivation. These findings suggest that the lack of essential nutrients, the complex nature of organics, and the high salinity of RPW limit the potential of microalgae as a bioremediation agent for a real RPW. These findings suggest the RPW is very heterogeneous, and any synthetic or simulated PW, even if prepared using individual major constituents of PW, cannot represent the real PW across the field for bioremediation using microalgae.
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spelling doaj-art-9f0db0bbfa13435794a4549cc04fe1132025-08-20T03:36:49ZengElsevierResults in Engineering2590-12302025-09-012710667910.1016/j.rineng.2025.106679Microalgae-based treatment of produced water: A comparison between synthetic and a representative real produced waterHussain Ali Al Subaie0Nur Farahah Khairuddin1Muhammad Nawaz Tahir2Muslim Aqeel Alhaddad3Mohammed Omar Faruque4Shaikh Abdur Razzak5Basheer Chanbasha6Ahsan Mushir Shamsi7Muhammad Shahzad Kamal8Wasif Farooq9Department of Chemical Engineering, King Fahd University of Petroleum and Minerals, 31261, Dhahran, Saudi ArabiaDepartment of Chemical and Process Engineering, Faculty of Engineering and Built Environment, Universiti Kebangsaan Malaysia, 43600, Bangi, Selangor Darul Ehsan, MalaysiaDepartment of Chemistry, King Fahd University of Petroleum and Minerals, 31261, Dhahran, Saudi Arabia; Interdisciplinary Research Center for Hydrogen Technologies and Carbon Management (IRC-HTCM), King Fahd University of Petroleum and Minerals, 31261, Dhahran, Saudi ArabiaDepartment of Chemical Engineering, King Fahd University of Petroleum and Minerals, 31261, Dhahran, Saudi ArabiaDepartment of Chemical Engineering, King Fahd University of Petroleum and Minerals, 31261, Dhahran, Saudi ArabiaDepartment of Chemical Engineering, King Fahd University of Petroleum and Minerals, 31261, Dhahran, Saudi Arabia; Interdisciplinary Research Center for Membrane and Water Security (IRC-MWS), King Fahd University of Petroleum and Minerals, 31261, Dhahran, Saudi ArabiaInterdisciplinary Research Center for Membrane and Water Security (IRC-MWS), King Fahd University of Petroleum and Minerals, 31261, Dhahran, Saudi Arabia; Department of Chemistry, King Fahd University of Petroleum and Minerals, 31261, Dhahran, Saudi ArabiaApplied Research Centre for Environment and Marine Studies, King Fahd University of Petroleum & Minerals, Dhahran 31261, Saudi ArabiaCenter for Integrative Petroleum Research, King Fahd University of Petroleum & Minerals, Dhahran 31261, Saudi ArabiaDepartment of Chemical Engineering, King Fahd University of Petroleum and Minerals, 31261, Dhahran, Saudi Arabia; Interdisciplinary Research Center for Membrane and Water Security (IRC-MWS), King Fahd University of Petroleum and Minerals, 31261, Dhahran, Saudi Arabia; Corresponding author.This work evaluates the potential of microalgae Scenedesmus obliquus to treat different synthetic and real PW of different compositions. Four different synthetic PW (SPWs) were formulated using crude oil, sodium dodecyl sulfate (SDS), and xanthan gum. It was found that S. obliquus could grow in all SPW with low and high salinity tested in this study. The presence of crude oil in synthetic PW hinders the algae's growth. No growth was observed in 100 % real-produced water (RPW) despite supplementation with essential growth nutrients. However, the algae cells could grow in 50 % diluted RPW, supplemented with nutrients. However, the growth of algae in 50 % v/v diluted RPW was the lowest compared to all SPW, despite having the same nutrients and salinity level. These results indicate that the presence of hydrocarbons from crude oil poses a major challenge to algae-based decontamination. Total organic carbon levels increased in all samples during growth, and nitrogen consumption was positively correlated with the algal growth rate. Barium (Ba) and Copper (Cu) metals were removed from RPW during S. obliquus cultivation. Some of the hydrocarbons present in 50 % diluted RPW were removed during cultivation. These findings suggest that the lack of essential nutrients, the complex nature of organics, and the high salinity of RPW limit the potential of microalgae as a bioremediation agent for a real RPW. These findings suggest the RPW is very heterogeneous, and any synthetic or simulated PW, even if prepared using individual major constituents of PW, cannot represent the real PW across the field for bioremediation using microalgae.http://www.sciencedirect.com/science/article/pii/S259012302502746XMicroalgaeScenedesmus obliquusProduced WaterSustainable TreatmentHydrocarbon
spellingShingle Hussain Ali Al Subaie
Nur Farahah Khairuddin
Muhammad Nawaz Tahir
Muslim Aqeel Alhaddad
Mohammed Omar Faruque
Shaikh Abdur Razzak
Basheer Chanbasha
Ahsan Mushir Shamsi
Muhammad Shahzad Kamal
Wasif Farooq
Microalgae-based treatment of produced water: A comparison between synthetic and a representative real produced water
Results in Engineering
Microalgae
Scenedesmus obliquus
Produced Water
Sustainable Treatment
Hydrocarbon
title Microalgae-based treatment of produced water: A comparison between synthetic and a representative real produced water
title_full Microalgae-based treatment of produced water: A comparison between synthetic and a representative real produced water
title_fullStr Microalgae-based treatment of produced water: A comparison between synthetic and a representative real produced water
title_full_unstemmed Microalgae-based treatment of produced water: A comparison between synthetic and a representative real produced water
title_short Microalgae-based treatment of produced water: A comparison between synthetic and a representative real produced water
title_sort microalgae based treatment of produced water a comparison between synthetic and a representative real produced water
topic Microalgae
Scenedesmus obliquus
Produced Water
Sustainable Treatment
Hydrocarbon
url http://www.sciencedirect.com/science/article/pii/S259012302502746X
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