Aloe Vera–Assisted Synthesis of Dy-Doped MgNb2O6 for Sustainable Sensing and Photocatalytic Applications

This study introduces a novel, cost-effective, and combustion synthesis approach for synthesizing dysprosium-doped magnesium niobium oxide (Dy: MNbO) nanoparticles (NPs) via a solution combustion method utilizing aloe vera gel as a green fuel. The use of aloe vera gel not only simplifies the synthes...

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Main Authors: N. Basavaraju, H. N. Shwetha, C. R. Ravikumar, Syed Khasim, K. B. Tan, Kiflom Gebremedhn Kelele, K. Y. Chan, H. C. Ananda Murthy
Format: Article
Language:English
Published: Wiley 2025-01-01
Series:Journal of Nanotechnology
Online Access:http://dx.doi.org/10.1155/jnt/6674176
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author N. Basavaraju
H. N. Shwetha
C. R. Ravikumar
Syed Khasim
K. B. Tan
Kiflom Gebremedhn Kelele
K. Y. Chan
H. C. Ananda Murthy
author_facet N. Basavaraju
H. N. Shwetha
C. R. Ravikumar
Syed Khasim
K. B. Tan
Kiflom Gebremedhn Kelele
K. Y. Chan
H. C. Ananda Murthy
author_sort N. Basavaraju
collection DOAJ
description This study introduces a novel, cost-effective, and combustion synthesis approach for synthesizing dysprosium-doped magnesium niobium oxide (Dy: MNbO) nanoparticles (NPs) via a solution combustion method utilizing aloe vera gel as a green fuel. The use of aloe vera gel not only simplifies the synthesis process but also enhances the ecocompatibility of the method, making it a significant advancement over conventional techniques. Advanced spectral techniques were employed to characterize the Dy: MNbO NPs. PXRD analysis revealed that the average crystalline size of the NPs was approximately 45 nm. The energy band gap of the synthesized Dy: MNbO NPs was determined to be in the range of 4-5 eV. SEM analysis showed the presence of distinctly agglomerated, lump-like structures. The photocatalytic performance of Dy: MNbO NPs was evaluated for the degradation of industrial dyes, specifically direct green (DG) dye, under UV light irradiation. Among different doping concentrations, the 4 mol% Dy: MNbO NPs exhibited the highest photocatalytic efficiency, achieving an 82% degradation. In comparison, the degradation rates for other doping concentrations were 58% for 2 mol%, 62% for 6 mol%, and 75% for 8 mol%. Electrochemical analyses using 4 mol% Dy: MNbO NPs as a modified electrode were performed in a 0.1 M HCl electrolyte solution. Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) confirmed the reversibility of the electrode reaction. The sample demonstrated excellent performance in electrochemical sensing applications, specifically for detecting ibuprofen and glucose molecules.
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spelling doaj-art-9ed98019768a4dc8997d37fe62ecc8c02025-08-20T03:49:18ZengWileyJournal of Nanotechnology1687-95112025-01-01202510.1155/jnt/6674176Aloe Vera–Assisted Synthesis of Dy-Doped MgNb2O6 for Sustainable Sensing and Photocatalytic ApplicationsN. Basavaraju0H. N. Shwetha1C. R. Ravikumar2Syed Khasim3K. B. Tan4Kiflom Gebremedhn Kelele5K. Y. Chan6H. C. Ananda Murthy7Department of Basic ScienceDepartment of MathematicsDepartment of Basic ScienceDepartment of PhysicsDepartment of ChemistryDepartment of ChemistryCentre for Advanced Devices and SystemsSchool of Applied SciencesThis study introduces a novel, cost-effective, and combustion synthesis approach for synthesizing dysprosium-doped magnesium niobium oxide (Dy: MNbO) nanoparticles (NPs) via a solution combustion method utilizing aloe vera gel as a green fuel. The use of aloe vera gel not only simplifies the synthesis process but also enhances the ecocompatibility of the method, making it a significant advancement over conventional techniques. Advanced spectral techniques were employed to characterize the Dy: MNbO NPs. PXRD analysis revealed that the average crystalline size of the NPs was approximately 45 nm. The energy band gap of the synthesized Dy: MNbO NPs was determined to be in the range of 4-5 eV. SEM analysis showed the presence of distinctly agglomerated, lump-like structures. The photocatalytic performance of Dy: MNbO NPs was evaluated for the degradation of industrial dyes, specifically direct green (DG) dye, under UV light irradiation. Among different doping concentrations, the 4 mol% Dy: MNbO NPs exhibited the highest photocatalytic efficiency, achieving an 82% degradation. In comparison, the degradation rates for other doping concentrations were 58% for 2 mol%, 62% for 6 mol%, and 75% for 8 mol%. Electrochemical analyses using 4 mol% Dy: MNbO NPs as a modified electrode were performed in a 0.1 M HCl electrolyte solution. Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) confirmed the reversibility of the electrode reaction. The sample demonstrated excellent performance in electrochemical sensing applications, specifically for detecting ibuprofen and glucose molecules.http://dx.doi.org/10.1155/jnt/6674176
spellingShingle N. Basavaraju
H. N. Shwetha
C. R. Ravikumar
Syed Khasim
K. B. Tan
Kiflom Gebremedhn Kelele
K. Y. Chan
H. C. Ananda Murthy
Aloe Vera–Assisted Synthesis of Dy-Doped MgNb2O6 for Sustainable Sensing and Photocatalytic Applications
Journal of Nanotechnology
title Aloe Vera–Assisted Synthesis of Dy-Doped MgNb2O6 for Sustainable Sensing and Photocatalytic Applications
title_full Aloe Vera–Assisted Synthesis of Dy-Doped MgNb2O6 for Sustainable Sensing and Photocatalytic Applications
title_fullStr Aloe Vera–Assisted Synthesis of Dy-Doped MgNb2O6 for Sustainable Sensing and Photocatalytic Applications
title_full_unstemmed Aloe Vera–Assisted Synthesis of Dy-Doped MgNb2O6 for Sustainable Sensing and Photocatalytic Applications
title_short Aloe Vera–Assisted Synthesis of Dy-Doped MgNb2O6 for Sustainable Sensing and Photocatalytic Applications
title_sort aloe vera assisted synthesis of dy doped mgnb2o6 for sustainable sensing and photocatalytic applications
url http://dx.doi.org/10.1155/jnt/6674176
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