Polyvinylpolypyrrolidoniume tribromide (PVP-Br3) as efficient and metal-free agent for the selective oxidation of alcohols, trimethylsilyl ethers and oximes under mild conditions
Polyvinylpolypyrrolidoniume tribromide (PVP-Br3) was found to be a metal-free and highly efficient oxidizing polymer for the selective oxidation of a variety of benzylic alcohols, deprotection and selective oxidation of trimethylsilyl ethers and oximes to the corresponding aldehydes and ketones at r...
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| Format: | Article |
| Language: | English |
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Springer
2017-05-01
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| Series: | Journal of Saudi Chemical Society |
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S1319610315000988 |
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| author | Arash Ghorbani-Choghamarani Mohsen Nikoorazm Bahman Tahmasbi Masoomeh Norouzi |
| author_facet | Arash Ghorbani-Choghamarani Mohsen Nikoorazm Bahman Tahmasbi Masoomeh Norouzi |
| author_sort | Arash Ghorbani-Choghamarani |
| collection | DOAJ |
| description | Polyvinylpolypyrrolidoniume tribromide (PVP-Br3) was found to be a metal-free and highly efficient oxidizing polymer for the selective oxidation of a variety of benzylic alcohols, deprotection and selective oxidation of trimethylsilyl ethers and oximes to the corresponding aldehydes and ketones at room temperature in moderate to high yields. The main advantages of this procedure are selective oxidation, efficient, milder reaction conditions, shorter reaction times, and easier work-up. |
| format | Article |
| id | doaj-art-9ea46e5ab7884bab9c4247eb82e28fda |
| institution | Kabale University |
| issn | 1319-6103 |
| language | English |
| publishDate | 2017-05-01 |
| publisher | Springer |
| record_format | Article |
| series | Journal of Saudi Chemical Society |
| spelling | doaj-art-9ea46e5ab7884bab9c4247eb82e28fda2025-08-20T03:52:02ZengSpringerJournal of Saudi Chemical Society1319-61032017-05-0121440841410.1016/j.jscs.2015.08.002Polyvinylpolypyrrolidoniume tribromide (PVP-Br3) as efficient and metal-free agent for the selective oxidation of alcohols, trimethylsilyl ethers and oximes under mild conditionsArash Ghorbani-ChoghamaraniMohsen NikoorazmBahman TahmasbiMasoomeh NorouziPolyvinylpolypyrrolidoniume tribromide (PVP-Br3) was found to be a metal-free and highly efficient oxidizing polymer for the selective oxidation of a variety of benzylic alcohols, deprotection and selective oxidation of trimethylsilyl ethers and oximes to the corresponding aldehydes and ketones at room temperature in moderate to high yields. The main advantages of this procedure are selective oxidation, efficient, milder reaction conditions, shorter reaction times, and easier work-up.http://www.sciencedirect.com/science/article/pii/S1319610315000988AlcoholOximeTrimethylsilyl etherPolyvinylpolypyrrolidoniume tribromideOxidationAldehydeKetone |
| spellingShingle | Arash Ghorbani-Choghamarani Mohsen Nikoorazm Bahman Tahmasbi Masoomeh Norouzi Polyvinylpolypyrrolidoniume tribromide (PVP-Br3) as efficient and metal-free agent for the selective oxidation of alcohols, trimethylsilyl ethers and oximes under mild conditions Journal of Saudi Chemical Society Alcohol Oxime Trimethylsilyl ether Polyvinylpolypyrrolidoniume tribromide Oxidation Aldehyde Ketone |
| title | Polyvinylpolypyrrolidoniume tribromide (PVP-Br3) as efficient and metal-free agent for the selective oxidation of alcohols, trimethylsilyl ethers and oximes under mild conditions |
| title_full | Polyvinylpolypyrrolidoniume tribromide (PVP-Br3) as efficient and metal-free agent for the selective oxidation of alcohols, trimethylsilyl ethers and oximes under mild conditions |
| title_fullStr | Polyvinylpolypyrrolidoniume tribromide (PVP-Br3) as efficient and metal-free agent for the selective oxidation of alcohols, trimethylsilyl ethers and oximes under mild conditions |
| title_full_unstemmed | Polyvinylpolypyrrolidoniume tribromide (PVP-Br3) as efficient and metal-free agent for the selective oxidation of alcohols, trimethylsilyl ethers and oximes under mild conditions |
| title_short | Polyvinylpolypyrrolidoniume tribromide (PVP-Br3) as efficient and metal-free agent for the selective oxidation of alcohols, trimethylsilyl ethers and oximes under mild conditions |
| title_sort | polyvinylpolypyrrolidoniume tribromide pvp br3 as efficient and metal free agent for the selective oxidation of alcohols trimethylsilyl ethers and oximes under mild conditions |
| topic | Alcohol Oxime Trimethylsilyl ether Polyvinylpolypyrrolidoniume tribromide Oxidation Aldehyde Ketone |
| url | http://www.sciencedirect.com/science/article/pii/S1319610315000988 |
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