Dynamics of electrocrystallization of dendritic zinc deposits in galvanostatic and potentiostatic modes

In the work the dynamics of growth of zinc dendritic deposits in the galvanostatic and potentiostatic modes from an electrolyte containing 0.3 mol/L of ZnO, and 4 mol/L of NaOH has been studied. It has been shown that in galvanostatic conditions decrease in the elongation rate of dendrites and chang...

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Main Authors: V. S. Nikitin, T. N. Ostanina, V. M. Rudoi, A. S. Farlenkov
Format: Article
Language:English
Published: Ural Federal University 2015-10-01
Series:Chimica Techno Acta
Subjects:
Online Access:https://chimicatechnoacta.ru/article/view/1277
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author V. S. Nikitin
T. N. Ostanina
V. M. Rudoi
A. S. Farlenkov
author_facet V. S. Nikitin
T. N. Ostanina
V. M. Rudoi
A. S. Farlenkov
author_sort V. S. Nikitin
collection DOAJ
description In the work the dynamics of growth of zinc dendritic deposits in the galvanostatic and potentiostatic modes from an electrolyte containing 0.3 mol/L of ZnO, and 4 mol/L of NaOH has been studied. It has been shown that in galvanostatic conditions decrease in the elongation rate of dendrites and change in the deposit structure from dendritic to compact accompanied by increasing density and decreasing through-thickness porosity are observed. In potentiostatic modes dendrites grow at a constant rate and the structure of the deposit varies little. The results have been confirmed by electron microscopic studies of morphology of zinc particles.
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spelling doaj-art-9e9811becdf44c0f901ad7a0d9e27ccd2025-08-20T03:18:58ZengUral Federal UniversityChimica Techno Acta2411-14142015-10-012320821710.15826/chimtech.2015.2.3.0221521Dynamics of electrocrystallization of dendritic zinc deposits in galvanostatic and potentiostatic modesV. S. Nikitin0T. N. Ostanina1V. M. Rudoi2A. S. Farlenkov3Уральский федеральный университет, ЕкатеринбургУральский федеральный университет, ЕкатеринбургУральский федеральный университет, ЕкатеринбургУральский федеральный университет, ЕкатеринбургIn the work the dynamics of growth of zinc dendritic deposits in the galvanostatic and potentiostatic modes from an electrolyte containing 0.3 mol/L of ZnO, and 4 mol/L of NaOH has been studied. It has been shown that in galvanostatic conditions decrease in the elongation rate of dendrites and change in the deposit structure from dendritic to compact accompanied by increasing density and decreasing through-thickness porosity are observed. In potentiostatic modes dendrites grow at a constant rate and the structure of the deposit varies little. The results have been confirmed by electron microscopic studies of morphology of zinc particles.https://chimicatechnoacta.ru/article/view/1277электрокристаллизацияцинкдендритыэлектрохимия
spellingShingle V. S. Nikitin
T. N. Ostanina
V. M. Rudoi
A. S. Farlenkov
Dynamics of electrocrystallization of dendritic zinc deposits in galvanostatic and potentiostatic modes
Chimica Techno Acta
электрокристаллизация
цинк
дендриты
электрохимия
title Dynamics of electrocrystallization of dendritic zinc deposits in galvanostatic and potentiostatic modes
title_full Dynamics of electrocrystallization of dendritic zinc deposits in galvanostatic and potentiostatic modes
title_fullStr Dynamics of electrocrystallization of dendritic zinc deposits in galvanostatic and potentiostatic modes
title_full_unstemmed Dynamics of electrocrystallization of dendritic zinc deposits in galvanostatic and potentiostatic modes
title_short Dynamics of electrocrystallization of dendritic zinc deposits in galvanostatic and potentiostatic modes
title_sort dynamics of electrocrystallization of dendritic zinc deposits in galvanostatic and potentiostatic modes
topic электрокристаллизация
цинк
дендриты
электрохимия
url https://chimicatechnoacta.ru/article/view/1277
work_keys_str_mv AT vsnikitin dynamicsofelectrocrystallizationofdendriticzincdepositsingalvanostaticandpotentiostaticmodes
AT tnostanina dynamicsofelectrocrystallizationofdendriticzincdepositsingalvanostaticandpotentiostaticmodes
AT vmrudoi dynamicsofelectrocrystallizationofdendriticzincdepositsingalvanostaticandpotentiostaticmodes
AT asfarlenkov dynamicsofelectrocrystallizationofdendriticzincdepositsingalvanostaticandpotentiostaticmodes