Separation Time of Aluminothermic Reduction Products for Sustainable Silicon Production [version 2; peer review: 2 approved]

Background This work was carried out within the framework of the SisAl Pilot project, which is devoted to the environmentally friendly production of silicon. This new method relies on the aluminothermic reduction of quartz in slag, offering a more sustainable alternative to the traditional reduction...

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Main Authors: Óscar Crego, Javier Bullón, Dolores Gómez, José Luis Ferrín, Luis Javier Pérez-Pérez, Iván Martínez
Format: Article
Language:English
Published: F1000 Research Ltd 2025-01-01
Series:Open Research Europe
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Online Access:https://open-research-europe.ec.europa.eu/articles/4-249/v2
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author Óscar Crego
Javier Bullón
Dolores Gómez
José Luis Ferrín
Luis Javier Pérez-Pérez
Iván Martínez
author_facet Óscar Crego
Javier Bullón
Dolores Gómez
José Luis Ferrín
Luis Javier Pérez-Pérez
Iván Martínez
author_sort Óscar Crego
collection DOAJ
description Background This work was carried out within the framework of the SisAl Pilot project, which is devoted to the environmentally friendly production of silicon. This new method relies on the aluminothermic reduction of quartz in slag, offering a more sustainable alternative to the traditional reduction of silica with carbon in submerged arc furnaces. Methods The process takes place in a rotary kiln producing silicon (Si) and alumina slag (actually, a CaO – Al2O3 slag), which must be separated at the end to extract the silicon. This separation process is analyzed through mathematical modelling and numerical simulation, as it is of industrial interest to know how much time it takes for Si and CaO – Al2O3 slag to separate once the process has ended. Generally, a multiphase flow model is used to estimate the separation time of the two components once aluminothermic reduction has ended. Results Several scenarios are considered for the numerical simulation of the separation time, namely different initial configurations and material properties of both fluids are covered. Moreover, the separation times obtained with two distinct multiphase flow models -VOF (volume of fluid) and Eulerian- are compared. Conclusions The separation times resulting from simulations using the multiphase Eulerian model are more realistic compared to those from the VOF model, which clearly tends to underestimate separation times. Furthermore, apart from the selected multiphase flow model, the density difference between silicon and alumina slag plays a critical role in determining the separation time.
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spelling doaj-art-9e591e63079640fc89c4e042b6850b0b2025-01-11T01:00:00ZengF1000 Research LtdOpen Research Europe2732-51212025-01-01420838Separation Time of Aluminothermic Reduction Products for Sustainable Silicon Production [version 2; peer review: 2 approved]Óscar Crego0Javier Bullón1Dolores Gómez2https://orcid.org/0000-0001-9722-311XJosé Luis Ferrín3https://orcid.org/0000-0002-4795-0455Luis Javier Pérez-Pérez4Iván Martínez5https://orcid.org/0000-0001-9983-2496Centro de Investigación e Tecnoloxía Matemática de Galicia, Santiago de Compostela, Galicia, 15782, SpainSilBuCam, A Coruña, SpainCentro de Investigación e Tecnoloxía Matemática de Galicia, Santiago de Compostela, Galicia, 15782, SpainCentro de Investigación e Tecnoloxía Matemática de Galicia, Santiago de Compostela, Galicia, 15782, SpainUniversidad Politecnica de Madrid Departamento de Ingenieria Geologica y Minera, Madrid, Community of Madrid, 28003, SpainCentro de Investigación e Tecnoloxía Matemática de Galicia, Santiago de Compostela, Galicia, 15782, SpainBackground This work was carried out within the framework of the SisAl Pilot project, which is devoted to the environmentally friendly production of silicon. This new method relies on the aluminothermic reduction of quartz in slag, offering a more sustainable alternative to the traditional reduction of silica with carbon in submerged arc furnaces. Methods The process takes place in a rotary kiln producing silicon (Si) and alumina slag (actually, a CaO – Al2O3 slag), which must be separated at the end to extract the silicon. This separation process is analyzed through mathematical modelling and numerical simulation, as it is of industrial interest to know how much time it takes for Si and CaO – Al2O3 slag to separate once the process has ended. Generally, a multiphase flow model is used to estimate the separation time of the two components once aluminothermic reduction has ended. Results Several scenarios are considered for the numerical simulation of the separation time, namely different initial configurations and material properties of both fluids are covered. Moreover, the separation times obtained with two distinct multiphase flow models -VOF (volume of fluid) and Eulerian- are compared. Conclusions The separation times resulting from simulations using the multiphase Eulerian model are more realistic compared to those from the VOF model, which clearly tends to underestimate separation times. Furthermore, apart from the selected multiphase flow model, the density difference between silicon and alumina slag plays a critical role in determining the separation time.https://open-research-europe.ec.europa.eu/articles/4-249/v2mathematical modelling numerical simulation rotary kiln aluminothermic reduction multiphase flow separation timeeng
spellingShingle Óscar Crego
Javier Bullón
Dolores Gómez
José Luis Ferrín
Luis Javier Pérez-Pérez
Iván Martínez
Separation Time of Aluminothermic Reduction Products for Sustainable Silicon Production [version 2; peer review: 2 approved]
Open Research Europe
mathematical modelling
numerical simulation
rotary kiln
aluminothermic reduction
multiphase flow
separation time
eng
title Separation Time of Aluminothermic Reduction Products for Sustainable Silicon Production [version 2; peer review: 2 approved]
title_full Separation Time of Aluminothermic Reduction Products for Sustainable Silicon Production [version 2; peer review: 2 approved]
title_fullStr Separation Time of Aluminothermic Reduction Products for Sustainable Silicon Production [version 2; peer review: 2 approved]
title_full_unstemmed Separation Time of Aluminothermic Reduction Products for Sustainable Silicon Production [version 2; peer review: 2 approved]
title_short Separation Time of Aluminothermic Reduction Products for Sustainable Silicon Production [version 2; peer review: 2 approved]
title_sort separation time of aluminothermic reduction products for sustainable silicon production version 2 peer review 2 approved
topic mathematical modelling
numerical simulation
rotary kiln
aluminothermic reduction
multiphase flow
separation time
eng
url https://open-research-europe.ec.europa.eu/articles/4-249/v2
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AT joseluisferrin separationtimeofaluminothermicreductionproductsforsustainablesiliconproductionversion2peerreview2approved
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