An Effective Pt-Cu/SiO2 Catalyst for the Selective Hydrogenation of Cinnamaldehyde

The bimetal catalyst Pt-Cu/SiO2 was prepared by the impregnation method. Its catalytic performance was investigated by the selective hydrogenation of cinnamaldehyde. Pt-Cu/SiO2 exhibited much higher selectivity (64.1%) to cinnamyl alcohol than Pt/SiO2 (3.7%), while they showed similar conversion of...

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Main Authors: Dong Wang, Yujun Zhu
Format: Article
Language:English
Published: Wiley 2018-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2018/5608243
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author Dong Wang
Yujun Zhu
author_facet Dong Wang
Yujun Zhu
author_sort Dong Wang
collection DOAJ
description The bimetal catalyst Pt-Cu/SiO2 was prepared by the impregnation method. Its catalytic performance was investigated by the selective hydrogenation of cinnamaldehyde. Pt-Cu/SiO2 exhibited much higher selectivity (64.1%) to cinnamyl alcohol than Pt/SiO2 (3.7%), while they showed similar conversion of cinnamaldehyde. This enhancement was attributed to the increase in the amount of the Pt0 species on the Pt-Cu/SiO2 surface, which is derived from the interaction between Pt and Cu revealed by XRD and XPS.
format Article
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institution OA Journals
issn 2090-9063
2090-9071
language English
publishDate 2018-01-01
publisher Wiley
record_format Article
series Journal of Chemistry
spelling doaj-art-9dade53d72034135a3e84d959334fefa2025-08-20T02:20:30ZengWileyJournal of Chemistry2090-90632090-90712018-01-01201810.1155/2018/56082435608243An Effective Pt-Cu/SiO2 Catalyst for the Selective Hydrogenation of CinnamaldehydeDong Wang0Yujun Zhu1School of Chemical and Environmental Engineering, Hanshan Normal University, Chaozhou 521041, ChinaKey Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, School of Chemistry and Materials, Heilongjiang University, Harbin 150080, ChinaThe bimetal catalyst Pt-Cu/SiO2 was prepared by the impregnation method. Its catalytic performance was investigated by the selective hydrogenation of cinnamaldehyde. Pt-Cu/SiO2 exhibited much higher selectivity (64.1%) to cinnamyl alcohol than Pt/SiO2 (3.7%), while they showed similar conversion of cinnamaldehyde. This enhancement was attributed to the increase in the amount of the Pt0 species on the Pt-Cu/SiO2 surface, which is derived from the interaction between Pt and Cu revealed by XRD and XPS.http://dx.doi.org/10.1155/2018/5608243
spellingShingle Dong Wang
Yujun Zhu
An Effective Pt-Cu/SiO2 Catalyst for the Selective Hydrogenation of Cinnamaldehyde
Journal of Chemistry
title An Effective Pt-Cu/SiO2 Catalyst for the Selective Hydrogenation of Cinnamaldehyde
title_full An Effective Pt-Cu/SiO2 Catalyst for the Selective Hydrogenation of Cinnamaldehyde
title_fullStr An Effective Pt-Cu/SiO2 Catalyst for the Selective Hydrogenation of Cinnamaldehyde
title_full_unstemmed An Effective Pt-Cu/SiO2 Catalyst for the Selective Hydrogenation of Cinnamaldehyde
title_short An Effective Pt-Cu/SiO2 Catalyst for the Selective Hydrogenation of Cinnamaldehyde
title_sort effective pt cu sio2 catalyst for the selective hydrogenation of cinnamaldehyde
url http://dx.doi.org/10.1155/2018/5608243
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AT yujunzhu aneffectiveptcusio2catalystfortheselectivehydrogenationofcinnamaldehyde
AT dongwang effectiveptcusio2catalystfortheselectivehydrogenationofcinnamaldehyde
AT yujunzhu effectiveptcusio2catalystfortheselectivehydrogenationofcinnamaldehyde