2,2′-((5,5′,6,6′-Tetramethoxy-[1,1′-biphenyl]-3,3′-diyl)bis(methanylylidene))dimalononitrile

This report discusses the synthesis of a biosourced divanillin derivative obtained by Knoevenagel condensation. The compound was fully characterized by proton (<sup>1</sup>H), carbon (<sup>13</sup>C), heteronuclear single quantum coherence (HSQC), homonuclear correlation spec...

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Main Authors: David Gendron, Josée Labrecque
Format: Article
Language:English
Published: MDPI AG 2025-04-01
Series:Molbank
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Online Access:https://www.mdpi.com/1422-8599/2025/2/M1996
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author David Gendron
Josée Labrecque
author_facet David Gendron
Josée Labrecque
author_sort David Gendron
collection DOAJ
description This report discusses the synthesis of a biosourced divanillin derivative obtained by Knoevenagel condensation. The compound was fully characterized by proton (<sup>1</sup>H), carbon (<sup>13</sup>C), heteronuclear single quantum coherence (HSQC), homonuclear correlation spectroscopy (COSY), and heteronuclear multiple bond correlation (HMBC) NMR, as well as high-resolution mass spectroscopy (HRMS). We also investigated the optical properties through UV-visible spectroscopy and Fourier-transform infrared (FTIR) spectroscopy. At last, the thermal properties of this divanillin derivative were evaluated by thermogravimetric analysis (TGA) as well as differential scanning calorimetry (DSC).
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spelling doaj-art-9d6296140f6649ce8483bfc49f492b5b2025-08-20T02:21:09ZengMDPI AGMolbank1422-85992025-04-0120252M199610.3390/M19962,2′-((5,5′,6,6′-Tetramethoxy-[1,1′-biphenyl]-3,3′-diyl)bis(methanylylidene))dimalononitrileDavid Gendron0Josée Labrecque1Kemitek, Cégep de Thetford, 835 Rue Mooney, Thetford Mines, QC G6G 0A5, CanadaKemitek, Cégep de Thetford, 835 Rue Mooney, Thetford Mines, QC G6G 0A5, CanadaThis report discusses the synthesis of a biosourced divanillin derivative obtained by Knoevenagel condensation. The compound was fully characterized by proton (<sup>1</sup>H), carbon (<sup>13</sup>C), heteronuclear single quantum coherence (HSQC), homonuclear correlation spectroscopy (COSY), and heteronuclear multiple bond correlation (HMBC) NMR, as well as high-resolution mass spectroscopy (HRMS). We also investigated the optical properties through UV-visible spectroscopy and Fourier-transform infrared (FTIR) spectroscopy. At last, the thermal properties of this divanillin derivative were evaluated by thermogravimetric analysis (TGA) as well as differential scanning calorimetry (DSC).https://www.mdpi.com/1422-8599/2025/2/M1996vanillinbiosourcedKnoevenagel condensationdyesorganic pigments
spellingShingle David Gendron
Josée Labrecque
2,2′-((5,5′,6,6′-Tetramethoxy-[1,1′-biphenyl]-3,3′-diyl)bis(methanylylidene))dimalononitrile
Molbank
vanillin
biosourced
Knoevenagel condensation
dyes
organic pigments
title 2,2′-((5,5′,6,6′-Tetramethoxy-[1,1′-biphenyl]-3,3′-diyl)bis(methanylylidene))dimalononitrile
title_full 2,2′-((5,5′,6,6′-Tetramethoxy-[1,1′-biphenyl]-3,3′-diyl)bis(methanylylidene))dimalononitrile
title_fullStr 2,2′-((5,5′,6,6′-Tetramethoxy-[1,1′-biphenyl]-3,3′-diyl)bis(methanylylidene))dimalononitrile
title_full_unstemmed 2,2′-((5,5′,6,6′-Tetramethoxy-[1,1′-biphenyl]-3,3′-diyl)bis(methanylylidene))dimalononitrile
title_short 2,2′-((5,5′,6,6′-Tetramethoxy-[1,1′-biphenyl]-3,3′-diyl)bis(methanylylidene))dimalononitrile
title_sort 2 2 5 5 6 6 tetramethoxy 1 1 biphenyl 3 3 diyl bis methanylylidene dimalononitrile
topic vanillin
biosourced
Knoevenagel condensation
dyes
organic pigments
url https://www.mdpi.com/1422-8599/2025/2/M1996
work_keys_str_mv AT davidgendron 225566tetramethoxy11biphenyl33diylbismethanylylidenedimalononitrile
AT joseelabrecque 225566tetramethoxy11biphenyl33diylbismethanylylidenedimalononitrile