Inverse opal photonic crystals: synthesis techniques, unique properties, and multifunctional applications

Inverse opal photonic crystals (IOPCs) are highly ordered, porous nanostructures with unique optical, electronic, and mechanical properties, making them valuable for photonics, catalysis, and biosensing applications. This review explores the synthesis methods of IOPCs, including self-assembly, chemi...

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Main Authors: Hamsasew Hankebo Lemago, Imre Miklós Szilágyi
Format: Article
Language:English
Published: Elsevier 2025-08-01
Series:Applied Surface Science Advances
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Online Access:http://www.sciencedirect.com/science/article/pii/S2666523925001138
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author Hamsasew Hankebo Lemago
Imre Miklós Szilágyi
author_facet Hamsasew Hankebo Lemago
Imre Miklós Szilágyi
author_sort Hamsasew Hankebo Lemago
collection DOAJ
description Inverse opal photonic crystals (IOPCs) are highly ordered, porous nanostructures with unique optical, electronic, and mechanical properties, making them valuable for photonics, catalysis, and biosensing applications. This review explores the synthesis methods of IOPCs, including self-assembly, chemical vapor deposition, sol-gel, atomic layer deposition, and electrodeposition, emphasizing their role in tailoring structural and functional properties. The periodicity of these materials gives rise to photonic band gaps and slow photon effects, enhancing their optical performance. Applications of IOPCs in photocatalysis for dye degradation and water splitting, as well as in biological sensing and energy storage, highlight their potential for advanced technological solutions. The incorporation of plasmonic nanoparticles and heterojunctions into IOPCs greatly enhances light-matter interactions, resulting in previously unobserved efficiency in photocatalytic and sensing applications. Moreover, the compositing of flexible IOPC-based devices is made possible by advancements in low-temperature synthesis methods like plasma-enhanced ALD, increasing the materials' applicability in wearable optoelectronics. Future studies will focus on AI-driven design and computational modelling to optimise photonic band gap structures and improve their performance in a variety of domains. This paper provides a comprehensive overview of the fabrication strategies, fundamental properties, and emerging applications of IOPCs, demonstrating their significance in next-generation materials science and engineering.
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spelling doaj-art-9cf09a9c750d431c80e42b492cf326ce2025-08-20T03:37:31ZengElsevierApplied Surface Science Advances2666-52392025-08-012810080510.1016/j.apsadv.2025.100805Inverse opal photonic crystals: synthesis techniques, unique properties, and multifunctional applicationsHamsasew Hankebo Lemago0Imre Miklós Szilágyi1Department of Inorganic and Analytical Chemistry, Faculty of Chemical Technology and Biotechnology, Budapest University of Technology and Economics, Műegyetem rkp. 3, Budapest H-1111, Hungary; Corresponding authors.Institute of Physical Metallurgy, Metal Forming and Nanotechnology, University of Miskolc, Miskolc-Egyetemváros H-3515, Hungary; Corresponding authors.Inverse opal photonic crystals (IOPCs) are highly ordered, porous nanostructures with unique optical, electronic, and mechanical properties, making them valuable for photonics, catalysis, and biosensing applications. This review explores the synthesis methods of IOPCs, including self-assembly, chemical vapor deposition, sol-gel, atomic layer deposition, and electrodeposition, emphasizing their role in tailoring structural and functional properties. The periodicity of these materials gives rise to photonic band gaps and slow photon effects, enhancing their optical performance. Applications of IOPCs in photocatalysis for dye degradation and water splitting, as well as in biological sensing and energy storage, highlight their potential for advanced technological solutions. The incorporation of plasmonic nanoparticles and heterojunctions into IOPCs greatly enhances light-matter interactions, resulting in previously unobserved efficiency in photocatalytic and sensing applications. Moreover, the compositing of flexible IOPC-based devices is made possible by advancements in low-temperature synthesis methods like plasma-enhanced ALD, increasing the materials' applicability in wearable optoelectronics. Future studies will focus on AI-driven design and computational modelling to optimise photonic band gap structures and improve their performance in a variety of domains. This paper provides a comprehensive overview of the fabrication strategies, fundamental properties, and emerging applications of IOPCs, demonstrating their significance in next-generation materials science and engineering.http://www.sciencedirect.com/science/article/pii/S2666523925001138Inverse opal photonic crystalTiO2/ZnOALDPhotonic band gapPhotocatalysis
spellingShingle Hamsasew Hankebo Lemago
Imre Miklós Szilágyi
Inverse opal photonic crystals: synthesis techniques, unique properties, and multifunctional applications
Applied Surface Science Advances
Inverse opal photonic crystal
TiO2/ZnO
ALD
Photonic band gap
Photocatalysis
title Inverse opal photonic crystals: synthesis techniques, unique properties, and multifunctional applications
title_full Inverse opal photonic crystals: synthesis techniques, unique properties, and multifunctional applications
title_fullStr Inverse opal photonic crystals: synthesis techniques, unique properties, and multifunctional applications
title_full_unstemmed Inverse opal photonic crystals: synthesis techniques, unique properties, and multifunctional applications
title_short Inverse opal photonic crystals: synthesis techniques, unique properties, and multifunctional applications
title_sort inverse opal photonic crystals synthesis techniques unique properties and multifunctional applications
topic Inverse opal photonic crystal
TiO2/ZnO
ALD
Photonic band gap
Photocatalysis
url http://www.sciencedirect.com/science/article/pii/S2666523925001138
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