Novel oligocarbosilazanes bearing promesogenic end groups

A series of novel oligomers with promesogenic groups on both termini were prepared by a hydrosilylation reaction between well-defined telechelic oligocarbosilazanes end-fitted with vinylsilane (SiVi) groups and promesogenic compounds containing one reactive hydrosilane (SiH) group. We investigated t...

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Format: Article
Language:English
Published: Budapest University of Technology and Economics 2009-07-01
Series:eXPRESS Polymer Letters
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Online Access:http://www.expresspolymlett.com/letolt.php?file=EPL-0000966&mi=cd
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description A series of novel oligomers with promesogenic groups on both termini were prepared by a hydrosilylation reaction between well-defined telechelic oligocarbosilazanes end-fitted with vinylsilane (SiVi) groups and promesogenic compounds containing one reactive hydrosilane (SiH) group. We investigated the correlations between the structure of the resulting mesogen end-capped oligomers and their phase behavior as examined by differential scanning calorimetry (DSC) and polarizing optical microscopy (POM).
format Article
id doaj-art-9c24118edfa7457fa8f7ff448f479018
institution Kabale University
issn 1788-618X
language English
publishDate 2009-07-01
publisher Budapest University of Technology and Economics
record_format Article
series eXPRESS Polymer Letters
spelling doaj-art-9c24118edfa7457fa8f7ff448f4790182025-08-20T03:57:08ZengBudapest University of Technology and EconomicseXPRESS Polymer Letters1788-618X2009-07-013744645110.3144/expresspolymlett.2009.54Novel oligocarbosilazanes bearing promesogenic end groupsA series of novel oligomers with promesogenic groups on both termini were prepared by a hydrosilylation reaction between well-defined telechelic oligocarbosilazanes end-fitted with vinylsilane (SiVi) groups and promesogenic compounds containing one reactive hydrosilane (SiH) group. We investigated the correlations between the structure of the resulting mesogen end-capped oligomers and their phase behavior as examined by differential scanning calorimetry (DSC) and polarizing optical microscopy (POM).http://www.expresspolymlett.com/letolt.php?file=EPL-0000966&mi=cdPolymer synthesis, molecular etelechelic oligomerscarbosilazane unitsphase behavior
spellingShingle Novel oligocarbosilazanes bearing promesogenic end groups
eXPRESS Polymer Letters
Polymer synthesis, molecular e
telechelic oligomers
carbosilazane units
phase behavior
title Novel oligocarbosilazanes bearing promesogenic end groups
title_full Novel oligocarbosilazanes bearing promesogenic end groups
title_fullStr Novel oligocarbosilazanes bearing promesogenic end groups
title_full_unstemmed Novel oligocarbosilazanes bearing promesogenic end groups
title_short Novel oligocarbosilazanes bearing promesogenic end groups
title_sort novel oligocarbosilazanes bearing promesogenic end groups
topic Polymer synthesis, molecular e
telechelic oligomers
carbosilazane units
phase behavior
url http://www.expresspolymlett.com/letolt.php?file=EPL-0000966&mi=cd