Sustainable Flame Retardant Coatings Derived from Chinese Lacquer Blend with Synergistic Flame Retardant Silicon-Modified Ammonium Polyphosphate
The intumescent flame retardant has a high efficiency of carbonization, oxygen barrier, and thermal interruption effect, which is considered to be a promising green and environmentally friendly flame retardant. Herein, we demonstrated a new approach to improve the flame retardant performance of Chin...
Saved in:
| Main Authors: | , , , , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Wiley
2023-01-01
|
| Series: | Advances in Materials Science and Engineering |
| Online Access: | http://dx.doi.org/10.1155/2023/9973474 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1832546549600616448 |
|---|---|
| author | Shuyun Li Renjin Gao Hanyu Xue Yuchi Zhang Yuansong Ye Qi Lin Qingyou Zeng Linshishui Liu Changlin Cao Jianrong Xia |
| author_facet | Shuyun Li Renjin Gao Hanyu Xue Yuchi Zhang Yuansong Ye Qi Lin Qingyou Zeng Linshishui Liu Changlin Cao Jianrong Xia |
| author_sort | Shuyun Li |
| collection | DOAJ |
| description | The intumescent flame retardant has a high efficiency of carbonization, oxygen barrier, and thermal interruption effect, which is considered to be a promising green and environmentally friendly flame retardant. Herein, we demonstrated a new approach to improve the flame retardant performance of Chinese lacquer films by adding silicon modified ammonium polyphosphate (SAPP), leading to superior flame retardant. SAPP drastically raised the limiting oxygen index (LOI) from 20.1% to 30.6%, and at the same time, the impact resistance was increased from 7 cm to 20 cm without changing the hardness of the lacquer films. X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy were used to investigate the chemical components and morphology of the residual char of Chinese lacquer and SAPP composite films. The thermal degradation process of films was detected and analyzed by thermogravimetry and microcalorimetry, and the possible flame retardant mechanism was discussed. This simple approach opens up a new way to design for improved flame retardancy of organic film polymers. |
| format | Article |
| id | doaj-art-9c0000c5bd7d49c2b59da88182c08bc1 |
| institution | Kabale University |
| issn | 1687-8442 |
| language | English |
| publishDate | 2023-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Advances in Materials Science and Engineering |
| spelling | doaj-art-9c0000c5bd7d49c2b59da88182c08bc12025-02-03T06:48:31ZengWileyAdvances in Materials Science and Engineering1687-84422023-01-01202310.1155/2023/9973474Sustainable Flame Retardant Coatings Derived from Chinese Lacquer Blend with Synergistic Flame Retardant Silicon-Modified Ammonium PolyphosphateShuyun Li0Renjin Gao1Hanyu Xue2Yuchi Zhang3Yuansong Ye4Qi Lin5Qingyou Zeng6Linshishui Liu7Changlin Cao8Jianrong Xia9College of Environmental and Resource Sciences College of Carbon Neutral Modern IndustryFujian Engineering and Research Center of New Chinese Lacquer MaterialsFujian Engineering and Research Center of New Chinese Lacquer MaterialsFujian Engineering and Research Center of New Chinese Lacquer MaterialsFujian Engineering and Research Center of New Chinese Lacquer MaterialsFujian Engineering and Research Center of New Chinese Lacquer MaterialsFujian Jiaofa High Tech Co.Fujian Jiaofa High Tech Co.College of Environmental and Resource Sciences College of Carbon Neutral Modern IndustryFujian Engineering and Research Center of New Chinese Lacquer MaterialsThe intumescent flame retardant has a high efficiency of carbonization, oxygen barrier, and thermal interruption effect, which is considered to be a promising green and environmentally friendly flame retardant. Herein, we demonstrated a new approach to improve the flame retardant performance of Chinese lacquer films by adding silicon modified ammonium polyphosphate (SAPP), leading to superior flame retardant. SAPP drastically raised the limiting oxygen index (LOI) from 20.1% to 30.6%, and at the same time, the impact resistance was increased from 7 cm to 20 cm without changing the hardness of the lacquer films. X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy were used to investigate the chemical components and morphology of the residual char of Chinese lacquer and SAPP composite films. The thermal degradation process of films was detected and analyzed by thermogravimetry and microcalorimetry, and the possible flame retardant mechanism was discussed. This simple approach opens up a new way to design for improved flame retardancy of organic film polymers.http://dx.doi.org/10.1155/2023/9973474 |
| spellingShingle | Shuyun Li Renjin Gao Hanyu Xue Yuchi Zhang Yuansong Ye Qi Lin Qingyou Zeng Linshishui Liu Changlin Cao Jianrong Xia Sustainable Flame Retardant Coatings Derived from Chinese Lacquer Blend with Synergistic Flame Retardant Silicon-Modified Ammonium Polyphosphate Advances in Materials Science and Engineering |
| title | Sustainable Flame Retardant Coatings Derived from Chinese Lacquer Blend with Synergistic Flame Retardant Silicon-Modified Ammonium Polyphosphate |
| title_full | Sustainable Flame Retardant Coatings Derived from Chinese Lacquer Blend with Synergistic Flame Retardant Silicon-Modified Ammonium Polyphosphate |
| title_fullStr | Sustainable Flame Retardant Coatings Derived from Chinese Lacquer Blend with Synergistic Flame Retardant Silicon-Modified Ammonium Polyphosphate |
| title_full_unstemmed | Sustainable Flame Retardant Coatings Derived from Chinese Lacquer Blend with Synergistic Flame Retardant Silicon-Modified Ammonium Polyphosphate |
| title_short | Sustainable Flame Retardant Coatings Derived from Chinese Lacquer Blend with Synergistic Flame Retardant Silicon-Modified Ammonium Polyphosphate |
| title_sort | sustainable flame retardant coatings derived from chinese lacquer blend with synergistic flame retardant silicon modified ammonium polyphosphate |
| url | http://dx.doi.org/10.1155/2023/9973474 |
| work_keys_str_mv | AT shuyunli sustainableflameretardantcoatingsderivedfromchineselacquerblendwithsynergisticflameretardantsiliconmodifiedammoniumpolyphosphate AT renjingao sustainableflameretardantcoatingsderivedfromchineselacquerblendwithsynergisticflameretardantsiliconmodifiedammoniumpolyphosphate AT hanyuxue sustainableflameretardantcoatingsderivedfromchineselacquerblendwithsynergisticflameretardantsiliconmodifiedammoniumpolyphosphate AT yuchizhang sustainableflameretardantcoatingsderivedfromchineselacquerblendwithsynergisticflameretardantsiliconmodifiedammoniumpolyphosphate AT yuansongye sustainableflameretardantcoatingsderivedfromchineselacquerblendwithsynergisticflameretardantsiliconmodifiedammoniumpolyphosphate AT qilin sustainableflameretardantcoatingsderivedfromchineselacquerblendwithsynergisticflameretardantsiliconmodifiedammoniumpolyphosphate AT qingyouzeng sustainableflameretardantcoatingsderivedfromchineselacquerblendwithsynergisticflameretardantsiliconmodifiedammoniumpolyphosphate AT linshishuiliu sustainableflameretardantcoatingsderivedfromchineselacquerblendwithsynergisticflameretardantsiliconmodifiedammoniumpolyphosphate AT changlincao sustainableflameretardantcoatingsderivedfromchineselacquerblendwithsynergisticflameretardantsiliconmodifiedammoniumpolyphosphate AT jianrongxia sustainableflameretardantcoatingsderivedfromchineselacquerblendwithsynergisticflameretardantsiliconmodifiedammoniumpolyphosphate |