Strain rate sensitivity metrics of PSU and PPSU high-performance polymers in extrusion-based additive manufacturing

High-performance polymers (HPPs), combined with material extrusion (MEX) additive manufacturing (AM), compile a powerful manufacturing system, suitable to meet the challenges of demanding industries. Their ability to undergo high strain rates is not well investigated yet. Herein, two HPPs, i.e., Pol...

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Main Authors: Nectarios Vidakis, Markos Petousis, Nikolaos Mountakis, Maria Spyridaki, Ioannis Valsamos, Emmanuel Kymakis
Format: Article
Language:English
Published: Elsevier 2025-09-01
Series:Results in Engineering
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Online Access:http://www.sciencedirect.com/science/article/pii/S2590123025019607
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author Nectarios Vidakis
Markos Petousis
Nikolaos Mountakis
Maria Spyridaki
Ioannis Valsamos
Emmanuel Kymakis
author_facet Nectarios Vidakis
Markos Petousis
Nikolaos Mountakis
Maria Spyridaki
Ioannis Valsamos
Emmanuel Kymakis
author_sort Nectarios Vidakis
collection DOAJ
description High-performance polymers (HPPs), combined with material extrusion (MEX) additive manufacturing (AM), compile a powerful manufacturing system, suitable to meet the challenges of demanding industries. Their ability to undergo high strain rates is not well investigated yet. Herein, two HPPs, i.e., Polysulfone (PSU) and Polyphenylsulfone (PPSU) were engaged to produce filaments, and a large amount of MEX AM fabricated specimens were examined under tensile tests with variable strain rate conditions. The aim was to thoroughly investigate the effect of strain rate (10 to 300 mm/min uniaxial elongation speeds) on the mechanical properties of these two high-performance polymers, considering the 3D printing structure on their response. Τheir yield, strength, modulus, and toughness were evaluated. Besides the thermal evaluation of the filaments, the samples were examined through scanning electron microscopy to document and identify their failure patterns. The findings indicate that both PSU and PPSU exhibit remarkable strain rate sensitivity. For the PSU polymer, the tensile strength decreased by almost 35 % (∼20 % Young’s modulus) at the highest test speed. For the PPSU, the respective value was ∼16 %, at 100mm/min and then decreased at higher strain rates. Young’s modulus increased by almost 30 % at 200mm/min and then decreased by almost 20 %. The enhanced molecular structure and thermal stability of PPSU enable it to surpass PSU in performance at high strain rates. Samples become more brittle with the increase of the strain rate. These results underscore the necessity for judicious material selection in the 3D printing process when designing components intended for high loading speeds.
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spelling doaj-art-9bc975aa23c04abd94a3a17d1f90315e2025-08-20T03:24:07ZengElsevierResults in Engineering2590-12302025-09-012710588910.1016/j.rineng.2025.105889Strain rate sensitivity metrics of PSU and PPSU high-performance polymers in extrusion-based additive manufacturingNectarios Vidakis0Markos Petousis1Nikolaos Mountakis2Maria Spyridaki3Ioannis Valsamos4Emmanuel Kymakis5Department of Mechanical Engineering, Hellenic Mediterranean University, Heraklion, 71410, Greece; Corresponding author.Department of Mechanical Engineering, Hellenic Mediterranean University, Heraklion, 71410, GreeceDepartment of Mechanical Engineering, Hellenic Mediterranean University, Heraklion, 71410, GreeceDepartment of Mechanical Engineering, Hellenic Mediterranean University, Heraklion, 71410, GreeceDepartment of Mechanical Engineering, Hellenic Mediterranean University, Heraklion, 71410, GreeceInstitute of Emerging Technologies (I-EMERGE) of HMU Center for Research & Development, Heraklion, Crete 71410, Greece; Department of Electrical & Computer Engineering, Hellenic Mediterranean University (HMU), Heraklion, Crete 71410, GreeceHigh-performance polymers (HPPs), combined with material extrusion (MEX) additive manufacturing (AM), compile a powerful manufacturing system, suitable to meet the challenges of demanding industries. Their ability to undergo high strain rates is not well investigated yet. Herein, two HPPs, i.e., Polysulfone (PSU) and Polyphenylsulfone (PPSU) were engaged to produce filaments, and a large amount of MEX AM fabricated specimens were examined under tensile tests with variable strain rate conditions. The aim was to thoroughly investigate the effect of strain rate (10 to 300 mm/min uniaxial elongation speeds) on the mechanical properties of these two high-performance polymers, considering the 3D printing structure on their response. Τheir yield, strength, modulus, and toughness were evaluated. Besides the thermal evaluation of the filaments, the samples were examined through scanning electron microscopy to document and identify their failure patterns. The findings indicate that both PSU and PPSU exhibit remarkable strain rate sensitivity. For the PSU polymer, the tensile strength decreased by almost 35 % (∼20 % Young’s modulus) at the highest test speed. For the PPSU, the respective value was ∼16 %, at 100mm/min and then decreased at higher strain rates. Young’s modulus increased by almost 30 % at 200mm/min and then decreased by almost 20 %. The enhanced molecular structure and thermal stability of PPSU enable it to surpass PSU in performance at high strain rates. Samples become more brittle with the increase of the strain rate. These results underscore the necessity for judicious material selection in the 3D printing process when designing components intended for high loading speeds.http://www.sciencedirect.com/science/article/pii/S2590123025019607Polysulfone (PSU)Polyphenylsulfone (PPSU)Additive Manufacturing (AM)Strain rateStrain rate sensitivity
spellingShingle Nectarios Vidakis
Markos Petousis
Nikolaos Mountakis
Maria Spyridaki
Ioannis Valsamos
Emmanuel Kymakis
Strain rate sensitivity metrics of PSU and PPSU high-performance polymers in extrusion-based additive manufacturing
Results in Engineering
Polysulfone (PSU)
Polyphenylsulfone (PPSU)
Additive Manufacturing (AM)
Strain rate
Strain rate sensitivity
title Strain rate sensitivity metrics of PSU and PPSU high-performance polymers in extrusion-based additive manufacturing
title_full Strain rate sensitivity metrics of PSU and PPSU high-performance polymers in extrusion-based additive manufacturing
title_fullStr Strain rate sensitivity metrics of PSU and PPSU high-performance polymers in extrusion-based additive manufacturing
title_full_unstemmed Strain rate sensitivity metrics of PSU and PPSU high-performance polymers in extrusion-based additive manufacturing
title_short Strain rate sensitivity metrics of PSU and PPSU high-performance polymers in extrusion-based additive manufacturing
title_sort strain rate sensitivity metrics of psu and ppsu high performance polymers in extrusion based additive manufacturing
topic Polysulfone (PSU)
Polyphenylsulfone (PPSU)
Additive Manufacturing (AM)
Strain rate
Strain rate sensitivity
url http://www.sciencedirect.com/science/article/pii/S2590123025019607
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