Upcycling Scented Pandan Leaf Waste into High-Value Cellulose Nanocrystals via Ultrasound-Assisted Extraction for Edible Film Reinforcement

This study aims to optimize the parameters for the ultrasound-assisted extraction of cellulose nanocrystals (CNCs) from scented pandan leaf waste and to enhance the properties of edible films reinforced with CNC. The CNC extraction conditions were optimized using response surface methodology (centra...

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Main Authors: Benjamard Rattanamato, Nattapong Kanha, Prem Thongchai, Kanyasiri Rakariyatham, Wannaporn Klangpetch, Sukhuntha Osiriphun, Thunnop Laokuldilok
Format: Article
Language:English
Published: MDPI AG 2025-04-01
Series:Foods
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Online Access:https://www.mdpi.com/2304-8158/14/9/1528
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author Benjamard Rattanamato
Nattapong Kanha
Prem Thongchai
Kanyasiri Rakariyatham
Wannaporn Klangpetch
Sukhuntha Osiriphun
Thunnop Laokuldilok
author_facet Benjamard Rattanamato
Nattapong Kanha
Prem Thongchai
Kanyasiri Rakariyatham
Wannaporn Klangpetch
Sukhuntha Osiriphun
Thunnop Laokuldilok
author_sort Benjamard Rattanamato
collection DOAJ
description This study aims to optimize the parameters for the ultrasound-assisted extraction of cellulose nanocrystals (CNCs) from scented pandan leaf waste and to enhance the properties of edible films reinforced with CNC. The CNC extraction conditions were optimized using response surface methodology (central composite design) by varying two independent variables, including amplitude (25.86% to 54.14%) and ultrasonication time (11.89 min to 33.11 min). The optimal extraction conditions were 50% amplitude and 30 min ultrasonication, providing CNCs with the highest extraction yield (29.85%), the smallest crystallite size (5.85 nm), and the highest crystallinity index (59.32%). The extracted CNCs showed favorable physicochemical properties, including a zeta potential of −33.95 mV, an average particle diameter of 91.81 nm, and a polydispersity index of 0.26. Moreover, sweet potato starch (SPS)-based films incorporating various CNC concentrations (0, 2, 4, 6, and 8%) were fabricated. Increasing CNC concentrations improved key film properties, including thickness, moisture content, water vapor permeability, tensile strength, light transmittance, and color. Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), and scanning electron microscopy (SEM) analyses confirmed hydrogen bonding, crystallinity, and uniform CNC distribution within the film as CNC content increased. These findings highlight ultrasound-assisted extraction as an efficient method for producing high-quality CNCs from pandan leaf waste, offering sustainable nanofillers to enhance biodegradable edible films.
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spelling doaj-art-9a9b76272cf8461bb108ab81f0e9b4302025-08-20T02:24:47ZengMDPI AGFoods2304-81582025-04-01149152810.3390/foods14091528Upcycling Scented Pandan Leaf Waste into High-Value Cellulose Nanocrystals via Ultrasound-Assisted Extraction for Edible Film ReinforcementBenjamard Rattanamato0Nattapong Kanha1Prem Thongchai2Kanyasiri Rakariyatham3Wannaporn Klangpetch4Sukhuntha Osiriphun5Thunnop Laokuldilok6Faculty of Agro-Industry, Chiang Mai University, Chiang Mai 50100, ThailandFaculty of Agro-Industry, Chiang Mai University, Chiang Mai 50100, ThailandFaculty of Agro-Industry, Chiang Mai University, Chiang Mai 50100, ThailandFaculty of Agro-Industry, Chiang Mai University, Chiang Mai 50100, ThailandFaculty of Agro-Industry, Chiang Mai University, Chiang Mai 50100, ThailandFaculty of Agro-Industry, Chiang Mai University, Chiang Mai 50100, ThailandFaculty of Agro-Industry, Chiang Mai University, Chiang Mai 50100, ThailandThis study aims to optimize the parameters for the ultrasound-assisted extraction of cellulose nanocrystals (CNCs) from scented pandan leaf waste and to enhance the properties of edible films reinforced with CNC. The CNC extraction conditions were optimized using response surface methodology (central composite design) by varying two independent variables, including amplitude (25.86% to 54.14%) and ultrasonication time (11.89 min to 33.11 min). The optimal extraction conditions were 50% amplitude and 30 min ultrasonication, providing CNCs with the highest extraction yield (29.85%), the smallest crystallite size (5.85 nm), and the highest crystallinity index (59.32%). The extracted CNCs showed favorable physicochemical properties, including a zeta potential of −33.95 mV, an average particle diameter of 91.81 nm, and a polydispersity index of 0.26. Moreover, sweet potato starch (SPS)-based films incorporating various CNC concentrations (0, 2, 4, 6, and 8%) were fabricated. Increasing CNC concentrations improved key film properties, including thickness, moisture content, water vapor permeability, tensile strength, light transmittance, and color. Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), and scanning electron microscopy (SEM) analyses confirmed hydrogen bonding, crystallinity, and uniform CNC distribution within the film as CNC content increased. These findings highlight ultrasound-assisted extraction as an efficient method for producing high-quality CNCs from pandan leaf waste, offering sustainable nanofillers to enhance biodegradable edible films.https://www.mdpi.com/2304-8158/14/9/1528scented pandan leavesultrasonic-assisted extractioncellulose nanocrystalsresponse surface methodologysweet potato starchstarch/CNC film
spellingShingle Benjamard Rattanamato
Nattapong Kanha
Prem Thongchai
Kanyasiri Rakariyatham
Wannaporn Klangpetch
Sukhuntha Osiriphun
Thunnop Laokuldilok
Upcycling Scented Pandan Leaf Waste into High-Value Cellulose Nanocrystals via Ultrasound-Assisted Extraction for Edible Film Reinforcement
Foods
scented pandan leaves
ultrasonic-assisted extraction
cellulose nanocrystals
response surface methodology
sweet potato starch
starch/CNC film
title Upcycling Scented Pandan Leaf Waste into High-Value Cellulose Nanocrystals via Ultrasound-Assisted Extraction for Edible Film Reinforcement
title_full Upcycling Scented Pandan Leaf Waste into High-Value Cellulose Nanocrystals via Ultrasound-Assisted Extraction for Edible Film Reinforcement
title_fullStr Upcycling Scented Pandan Leaf Waste into High-Value Cellulose Nanocrystals via Ultrasound-Assisted Extraction for Edible Film Reinforcement
title_full_unstemmed Upcycling Scented Pandan Leaf Waste into High-Value Cellulose Nanocrystals via Ultrasound-Assisted Extraction for Edible Film Reinforcement
title_short Upcycling Scented Pandan Leaf Waste into High-Value Cellulose Nanocrystals via Ultrasound-Assisted Extraction for Edible Film Reinforcement
title_sort upcycling scented pandan leaf waste into high value cellulose nanocrystals via ultrasound assisted extraction for edible film reinforcement
topic scented pandan leaves
ultrasonic-assisted extraction
cellulose nanocrystals
response surface methodology
sweet potato starch
starch/CNC film
url https://www.mdpi.com/2304-8158/14/9/1528
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