Effect of γ-radiation-thermal coupling aging on the mechanical and radiolytic gas behavior of F2311 fluoroelastomer

In national defense, aerospace, and nuclear power fields, the service environments of polymer materials in equipment are complex and necessitate high requirements for their radiation resistance and thermal stability. Therefore, studying the aging behavior of polymer materials in a coupled radiation-...

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Main Authors: ZHANG Yiqian, DOU Ruiyang, LIU Qiang, HUANG Wei, YAN Shunping, CHEN Hongbing
Format: Article
Language:zho
Published: Science Press 2025-02-01
Series:Fushe yanjiu yu fushe gongyi xuebao
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Online Access:https://www.fs.sinap.ac.cn/zh/article/doi/10.11889/j.1000-3436.2024-0040/
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author ZHANG Yiqian
DOU Ruiyang
LIU Qiang
HUANG Wei
YAN Shunping
CHEN Hongbing
author_facet ZHANG Yiqian
DOU Ruiyang
LIU Qiang
HUANG Wei
YAN Shunping
CHEN Hongbing
author_sort ZHANG Yiqian
collection DOAJ
description In national defense, aerospace, and nuclear power fields, the service environments of polymer materials in equipment are complex and necessitate high requirements for their radiation resistance and thermal stability. Therefore, studying the aging behavior of polymer materials in a coupled radiation-thermal environment is crucial. In this study, F2311 rubber material was subjected to aging tests in the temperature range of 36-70 °C, with an absorbed γ dose of 20 kGy, 100 kGy, 200 kGy. The effects of the coupled temperature and absorbed dose on the mechanical properties of F2311 were investigated. The gaseous products released by the F2311 material and their kinetic laws were determined using gas-phase infrared spectra. The experimental results showed that the mechanical properties of the F2311 elastomer deteriorated rapidly in the radiation-thermal environment. Radiolytic outgassing was inevitable, and the gaseous products included corrosive halogen hydrides. Gas-phase infrared spectroscopy can quickly identify and quantitatively analyze gaseous products to trace and supervise the service reliability of equipment. This study is expected to provide a basis for the study of coupled multifactor aging and compatibility of fluorine rubber.
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series Fushe yanjiu yu fushe gongyi xuebao
spelling doaj-art-99a2f7ca9c5741cd812804226cf435102025-08-20T02:53:26ZzhoScience PressFushe yanjiu yu fushe gongyi xuebao1000-34362025-02-0143101020301020310.11889/j.1000-3436.2024-00401000-3436(2025)01-0040-09Effect of γ-radiation-thermal coupling aging on the mechanical and radiolytic gas behavior of F2311 fluoroelastomerZHANG Yiqian0DOU Ruiyang1LIU Qiang2HUANG Wei3YAN Shunping4CHEN Hongbing5Institute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, Mianyang 621900, ChinaInstitute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, Mianyang 621900, ChinaInstitute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, Mianyang 621900, ChinaInstitute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, Mianyang 621900, ChinaInstitute of General Engineering, China Academy of Engineering Physics, Mianyang 621999, ChinaInstitute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, Mianyang 621900, ChinaIn national defense, aerospace, and nuclear power fields, the service environments of polymer materials in equipment are complex and necessitate high requirements for their radiation resistance and thermal stability. Therefore, studying the aging behavior of polymer materials in a coupled radiation-thermal environment is crucial. In this study, F2311 rubber material was subjected to aging tests in the temperature range of 36-70 °C, with an absorbed γ dose of 20 kGy, 100 kGy, 200 kGy. The effects of the coupled temperature and absorbed dose on the mechanical properties of F2311 were investigated. The gaseous products released by the F2311 material and their kinetic laws were determined using gas-phase infrared spectra. The experimental results showed that the mechanical properties of the F2311 elastomer deteriorated rapidly in the radiation-thermal environment. Radiolytic outgassing was inevitable, and the gaseous products included corrosive halogen hydrides. Gas-phase infrared spectroscopy can quickly identify and quantitatively analyze gaseous products to trace and supervise the service reliability of equipment. This study is expected to provide a basis for the study of coupled multifactor aging and compatibility of fluorine rubber.https://www.fs.sinap.ac.cn/zh/article/doi/10.11889/j.1000-3436.2024-0040/fluoroelastomercoupled γ irradiation-heat agingmechanical propertyoutgassing behavioraging and compatibility
spellingShingle ZHANG Yiqian
DOU Ruiyang
LIU Qiang
HUANG Wei
YAN Shunping
CHEN Hongbing
Effect of γ-radiation-thermal coupling aging on the mechanical and radiolytic gas behavior of F2311 fluoroelastomer
Fushe yanjiu yu fushe gongyi xuebao
fluoroelastomer
coupled γ irradiation-heat aging
mechanical property
outgassing behavior
aging and compatibility
title Effect of γ-radiation-thermal coupling aging on the mechanical and radiolytic gas behavior of F2311 fluoroelastomer
title_full Effect of γ-radiation-thermal coupling aging on the mechanical and radiolytic gas behavior of F2311 fluoroelastomer
title_fullStr Effect of γ-radiation-thermal coupling aging on the mechanical and radiolytic gas behavior of F2311 fluoroelastomer
title_full_unstemmed Effect of γ-radiation-thermal coupling aging on the mechanical and radiolytic gas behavior of F2311 fluoroelastomer
title_short Effect of γ-radiation-thermal coupling aging on the mechanical and radiolytic gas behavior of F2311 fluoroelastomer
title_sort effect of γ radiation thermal coupling aging on the mechanical and radiolytic gas behavior of f2311 fluoroelastomer
topic fluoroelastomer
coupled γ irradiation-heat aging
mechanical property
outgassing behavior
aging and compatibility
url https://www.fs.sinap.ac.cn/zh/article/doi/10.11889/j.1000-3436.2024-0040/
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AT huangwei effectofgradiationthermalcouplingagingonthemechanicalandradiolyticgasbehavioroff2311fluoroelastomer
AT yanshunping effectofgradiationthermalcouplingagingonthemechanicalandradiolyticgasbehavioroff2311fluoroelastomer
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