Wildfire Smoke Demonstrates Significant and Predictable Black Carbon Light Absorption Enhancements

Abstract Black carbon (BC) is estimated to have the second largest anthropogenic radiative forcing in earth‐systems models (ESMs), but there is significant uncertainty in its impact due to complex mixing with organics. Laboratory‐generated particles show that co‐mixed non‐absorbing material enhances...

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Main Authors: James E. Lee, Kyle Gorkowski, Aaron G. Meyer, Katherine B. Benedict, Allison C. Aiken, Manvendra K. Dubey
Format: Article
Language:English
Published: Wiley 2022-07-01
Series:Geophysical Research Letters
Subjects:
Online Access:https://doi.org/10.1029/2022GL099334
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author James E. Lee
Kyle Gorkowski
Aaron G. Meyer
Katherine B. Benedict
Allison C. Aiken
Manvendra K. Dubey
author_facet James E. Lee
Kyle Gorkowski
Aaron G. Meyer
Katherine B. Benedict
Allison C. Aiken
Manvendra K. Dubey
author_sort James E. Lee
collection DOAJ
description Abstract Black carbon (BC) is estimated to have the second largest anthropogenic radiative forcing in earth‐systems models (ESMs), but there is significant uncertainty in its impact due to complex mixing with organics. Laboratory‐generated particles show that co‐mixed non‐absorbing material enhances absorption by BC by a factor of 2–3.5 as predicted by optical models. However, weak or no enhancements are often reported for field studies. The cause of lower‐than‐expected absorption is not well understood and implies a lower radiative impact of BC compared to how many ESMs currently treat aerosols. By analyzing BC aerosol particle‐by‐particle we reconcile observed and expected absorption for ambient smoke plumes varying in geographic origin, fuel types, burn conditions, atmospheric age and transport. Although particle‐by‐particle tracking is computationally prohibitive for sophisticated ESMs we show that realistic BC absorption is reliably estimated by bulk properties of the plume providing a suitable parameterization to constrain black carbon radiative forcing.
format Article
id doaj-art-993c664ef32140c8af40c577d4e4417e
institution DOAJ
issn 0094-8276
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publishDate 2022-07-01
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series Geophysical Research Letters
spelling doaj-art-993c664ef32140c8af40c577d4e4417e2025-08-20T03:14:16ZengWileyGeophysical Research Letters0094-82761944-80072022-07-014914n/an/a10.1029/2022GL099334Wildfire Smoke Demonstrates Significant and Predictable Black Carbon Light Absorption EnhancementsJames E. Lee0Kyle Gorkowski1Aaron G. Meyer2Katherine B. Benedict3Allison C. Aiken4Manvendra K. Dubey5Earth and Environmental Sciences Division Los Alamos National Laboratory Los Alamos NM USAEarth and Environmental Sciences Division Los Alamos National Laboratory Los Alamos NM USAEarth and Environmental Sciences Division Los Alamos National Laboratory Los Alamos NM USAEarth and Environmental Sciences Division Los Alamos National Laboratory Los Alamos NM USAEarth and Environmental Sciences Division Los Alamos National Laboratory Los Alamos NM USAEarth and Environmental Sciences Division Los Alamos National Laboratory Los Alamos NM USAAbstract Black carbon (BC) is estimated to have the second largest anthropogenic radiative forcing in earth‐systems models (ESMs), but there is significant uncertainty in its impact due to complex mixing with organics. Laboratory‐generated particles show that co‐mixed non‐absorbing material enhances absorption by BC by a factor of 2–3.5 as predicted by optical models. However, weak or no enhancements are often reported for field studies. The cause of lower‐than‐expected absorption is not well understood and implies a lower radiative impact of BC compared to how many ESMs currently treat aerosols. By analyzing BC aerosol particle‐by‐particle we reconcile observed and expected absorption for ambient smoke plumes varying in geographic origin, fuel types, burn conditions, atmospheric age and transport. Although particle‐by‐particle tracking is computationally prohibitive for sophisticated ESMs we show that realistic BC absorption is reliably estimated by bulk properties of the plume providing a suitable parameterization to constrain black carbon radiative forcing.https://doi.org/10.1029/2022GL099334biomass burningblack carbonabsorption enhancementradiative forcingaerosol
spellingShingle James E. Lee
Kyle Gorkowski
Aaron G. Meyer
Katherine B. Benedict
Allison C. Aiken
Manvendra K. Dubey
Wildfire Smoke Demonstrates Significant and Predictable Black Carbon Light Absorption Enhancements
Geophysical Research Letters
biomass burning
black carbon
absorption enhancement
radiative forcing
aerosol
title Wildfire Smoke Demonstrates Significant and Predictable Black Carbon Light Absorption Enhancements
title_full Wildfire Smoke Demonstrates Significant and Predictable Black Carbon Light Absorption Enhancements
title_fullStr Wildfire Smoke Demonstrates Significant and Predictable Black Carbon Light Absorption Enhancements
title_full_unstemmed Wildfire Smoke Demonstrates Significant and Predictable Black Carbon Light Absorption Enhancements
title_short Wildfire Smoke Demonstrates Significant and Predictable Black Carbon Light Absorption Enhancements
title_sort wildfire smoke demonstrates significant and predictable black carbon light absorption enhancements
topic biomass burning
black carbon
absorption enhancement
radiative forcing
aerosol
url https://doi.org/10.1029/2022GL099334
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AT kylegorkowski wildfiresmokedemonstratessignificantandpredictableblackcarbonlightabsorptionenhancements
AT aarongmeyer wildfiresmokedemonstratessignificantandpredictableblackcarbonlightabsorptionenhancements
AT katherinebbenedict wildfiresmokedemonstratessignificantandpredictableblackcarbonlightabsorptionenhancements
AT allisoncaiken wildfiresmokedemonstratessignificantandpredictableblackcarbonlightabsorptionenhancements
AT manvendrakdubey wildfiresmokedemonstratessignificantandpredictableblackcarbonlightabsorptionenhancements