Analysis of CaF2 Precipitation Process in the Selected Static Mixers

In the paper, the analysis of the precipitation process of calcium fluoride in the selected static mixers was made. The Kenics and Koflo static mixers, as well as an empty pipe as a background, have been taken into consideration. The Kenics and Koflo types have been chosen as their inner shapes conv...

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Main Authors: Piotr Maria Synowiec, Magdalena Stec
Format: Article
Language:English
Published: Wiley 2019-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2019/6728492
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author Piotr Maria Synowiec
Magdalena Stec
author_facet Piotr Maria Synowiec
Magdalena Stec
author_sort Piotr Maria Synowiec
collection DOAJ
description In the paper, the analysis of the precipitation process of calcium fluoride in the selected static mixers was made. The Kenics and Koflo static mixers, as well as an empty pipe as a background, have been taken into consideration. The Kenics and Koflo types have been chosen as their inner shapes convenient for the realization of continuous precipitation processes as incrustation phenomenon and dangerousness of flow blocking are not as high as in other solutions. The main tasks were focused on the recognition of the precipitation kinetics (to get the knowledge of the relative supersaturation, nucleation sources, and mechanisms controlling the crystal growth), determination of conversion efficiency of the chemical reaction by which CaF2 is precipitated, the fluid dynamic conditions on crystal size distribution (CSD), and the identification of particles’ destruction sources as well. This paper is a primary work dedicated to the possibilities of a special treatment of the solid phase during its formation in order to obtain the required crystal size distribution (CSD) and to avoid the agglomeration when necessary. The results are very promising. As it will be shown, the special treatment of the precipitated solid substances in static mixers enables to create crystals with the required size and to eliminate the agglomeration phenomenon.
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spelling doaj-art-991f05a874d142aca20f3e936b208e6c2025-02-03T05:46:01ZengWileyJournal of Chemistry2090-90632090-90712019-01-01201910.1155/2019/67284926728492Analysis of CaF2 Precipitation Process in the Selected Static MixersPiotr Maria Synowiec0Magdalena Stec1Department of Chemical Engineering and Process Design, Faculty of Chemistry, Silesian University of Technology, Strzody 7, 44-100 Gliwice, PolandDepartment of Chemical Engineering and Process Design, Faculty of Chemistry, Silesian University of Technology, Strzody 7, 44-100 Gliwice, PolandIn the paper, the analysis of the precipitation process of calcium fluoride in the selected static mixers was made. The Kenics and Koflo static mixers, as well as an empty pipe as a background, have been taken into consideration. The Kenics and Koflo types have been chosen as their inner shapes convenient for the realization of continuous precipitation processes as incrustation phenomenon and dangerousness of flow blocking are not as high as in other solutions. The main tasks were focused on the recognition of the precipitation kinetics (to get the knowledge of the relative supersaturation, nucleation sources, and mechanisms controlling the crystal growth), determination of conversion efficiency of the chemical reaction by which CaF2 is precipitated, the fluid dynamic conditions on crystal size distribution (CSD), and the identification of particles’ destruction sources as well. This paper is a primary work dedicated to the possibilities of a special treatment of the solid phase during its formation in order to obtain the required crystal size distribution (CSD) and to avoid the agglomeration when necessary. The results are very promising. As it will be shown, the special treatment of the precipitated solid substances in static mixers enables to create crystals with the required size and to eliminate the agglomeration phenomenon.http://dx.doi.org/10.1155/2019/6728492
spellingShingle Piotr Maria Synowiec
Magdalena Stec
Analysis of CaF2 Precipitation Process in the Selected Static Mixers
Journal of Chemistry
title Analysis of CaF2 Precipitation Process in the Selected Static Mixers
title_full Analysis of CaF2 Precipitation Process in the Selected Static Mixers
title_fullStr Analysis of CaF2 Precipitation Process in the Selected Static Mixers
title_full_unstemmed Analysis of CaF2 Precipitation Process in the Selected Static Mixers
title_short Analysis of CaF2 Precipitation Process in the Selected Static Mixers
title_sort analysis of caf2 precipitation process in the selected static mixers
url http://dx.doi.org/10.1155/2019/6728492
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