Organocatalysis with carbon nitrides
Carbon nitrides, a distinguished class of metal-free catalytic materials, have presented a good potential for chemical transformations and are expected to become prominent materials for organocatalysis. This is largely possible due to their low cost, exceptional thermal and chemical stability, non-t...
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| Format: | Article |
| Language: | English |
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Taylor & Francis Group
2023-12-01
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| Series: | Science and Technology of Advanced Materials |
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| Online Access: | https://www.tandfonline.com/doi/10.1080/14686996.2023.2188879 |
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| author | Sujanya Maria Ruban Kavitha Ramadass Gurwinder Singh Siddulu Naidu Talapaneni Gunda Kamalakar Chandrakanth Rajanna Gadipelly Lakshmi Kantham Mannepalli Yoshihiro Sugi Ajayan Vinu |
| author_facet | Sujanya Maria Ruban Kavitha Ramadass Gurwinder Singh Siddulu Naidu Talapaneni Gunda Kamalakar Chandrakanth Rajanna Gadipelly Lakshmi Kantham Mannepalli Yoshihiro Sugi Ajayan Vinu |
| author_sort | Sujanya Maria Ruban |
| collection | DOAJ |
| description | Carbon nitrides, a distinguished class of metal-free catalytic materials, have presented a good potential for chemical transformations and are expected to become prominent materials for organocatalysis. This is largely possible due to their low cost, exceptional thermal and chemical stability, non-toxicity, ease of functionalization, porosity development, etc. Especially, the carbon nitrides with increased porosity and nitrogen contents are more versatile than their bulk counterparts for catalysis. These N-rich carbon nitrides are discussed in the earlier parts of the review. Later, the review highlights the role of such carbon nitride materials for the various organic catalytic reactions including Knoevenagel condensation, oxidation, hydrogenation, esterification, transesterification, cycloaddition, and hydrolysis. The recently emerging concepts in carbon nitride-based organocatalysis have been given special attention. In each of the sections, the structure–property relationship of the materials was discussed and related to their catalysis action. Relevant comparisons with other catalytic materials are also discussed to realize their real potential value. The perspective, challenges, and future directions are also discussed. The overall objective of this review is to provide up-to-date information on new developments in carbon nitride-based organic catalysis reactions that could see them rising as prominent catalytic materials in the future. |
| format | Article |
| id | doaj-art-98ac170cc1f542cbabc8dbd1233fe7ec |
| institution | Kabale University |
| issn | 1468-6996 1878-5514 |
| language | English |
| publishDate | 2023-12-01 |
| publisher | Taylor & Francis Group |
| record_format | Article |
| series | Science and Technology of Advanced Materials |
| spelling | doaj-art-98ac170cc1f542cbabc8dbd1233fe7ec2025-08-20T03:40:17ZengTaylor & Francis GroupScience and Technology of Advanced Materials1468-69961878-55142023-12-0124110.1080/14686996.2023.2188879Organocatalysis with carbon nitridesSujanya Maria Ruban0Kavitha Ramadass1Gurwinder Singh2Siddulu Naidu Talapaneni3Gunda Kamalakar4Chandrakanth Rajanna Gadipelly5Lakshmi Kantham Mannepalli6Yoshihiro Sugi7Ajayan Vinu8Global Innovative Centre for Advanced Nanomaterials (GICAN), College of Engineering, Science and Environment (CESE), School of Engineering, The University of Newcastle, Callaghan, AustraliaGlobal Innovative Centre for Advanced Nanomaterials (GICAN), College of Engineering, Science and Environment (CESE), School of Engineering, The University of Newcastle, Callaghan, AustraliaGlobal Innovative Centre for Advanced Nanomaterials (GICAN), College of Engineering, Science and Environment (CESE), School of Engineering, The University of Newcastle, Callaghan, AustraliaSchool of Chemical Engineering, University of New South Wales, Sydney, NSW, AustraliaDepartment of Chemical Engineering, University of Waterloo, Waterloo, Ontario, CanadaFlow Chemistry Division, Amar Equipment Pvt. Ltd, Mumbai, IndiaDepartment of Chemical Engineering, Institute of Chemical Technology, Mumbai, IndiaGlobal Innovative Centre for Advanced Nanomaterials (GICAN), College of Engineering, Science and Environment (CESE), School of Engineering, The University of Newcastle, Callaghan, AustraliaGlobal Innovative Centre for Advanced Nanomaterials (GICAN), College of Engineering, Science and Environment (CESE), School of Engineering, The University of Newcastle, Callaghan, AustraliaCarbon nitrides, a distinguished class of metal-free catalytic materials, have presented a good potential for chemical transformations and are expected to become prominent materials for organocatalysis. This is largely possible due to their low cost, exceptional thermal and chemical stability, non-toxicity, ease of functionalization, porosity development, etc. Especially, the carbon nitrides with increased porosity and nitrogen contents are more versatile than their bulk counterparts for catalysis. These N-rich carbon nitrides are discussed in the earlier parts of the review. Later, the review highlights the role of such carbon nitride materials for the various organic catalytic reactions including Knoevenagel condensation, oxidation, hydrogenation, esterification, transesterification, cycloaddition, and hydrolysis. The recently emerging concepts in carbon nitride-based organocatalysis have been given special attention. In each of the sections, the structure–property relationship of the materials was discussed and related to their catalysis action. Relevant comparisons with other catalytic materials are also discussed to realize their real potential value. The perspective, challenges, and future directions are also discussed. The overall objective of this review is to provide up-to-date information on new developments in carbon nitride-based organic catalysis reactions that could see them rising as prominent catalytic materials in the future.https://www.tandfonline.com/doi/10.1080/14686996.2023.2188879Carbon nitrideorganocatalysisKnoevenagel condensationesterificationcycloadditionhydrolysis |
| spellingShingle | Sujanya Maria Ruban Kavitha Ramadass Gurwinder Singh Siddulu Naidu Talapaneni Gunda Kamalakar Chandrakanth Rajanna Gadipelly Lakshmi Kantham Mannepalli Yoshihiro Sugi Ajayan Vinu Organocatalysis with carbon nitrides Science and Technology of Advanced Materials Carbon nitride organocatalysis Knoevenagel condensation esterification cycloaddition hydrolysis |
| title | Organocatalysis with carbon nitrides |
| title_full | Organocatalysis with carbon nitrides |
| title_fullStr | Organocatalysis with carbon nitrides |
| title_full_unstemmed | Organocatalysis with carbon nitrides |
| title_short | Organocatalysis with carbon nitrides |
| title_sort | organocatalysis with carbon nitrides |
| topic | Carbon nitride organocatalysis Knoevenagel condensation esterification cycloaddition hydrolysis |
| url | https://www.tandfonline.com/doi/10.1080/14686996.2023.2188879 |
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