Seed Characteristics and Terpene Variability of Mediterranean Fir Species (<i>Abies nebrodensis</i>, <i>A. pinsapo</i>, and <i>A. alba</i>)

Most fir species in the Mediterranean have small to medium-sized distributions, are often endemic and endangered, and are mainly found in relict areas, except for <i>Abies alba</i>. The IUCN Red List of Threatened Species identified <i>Abies nebrodensis</i> as the rarest coni...

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Main Authors: Waed Tarraf, Tolga İzgü, Carla Benelli, Gabriele Cencetti, Marco Michelozzi, Alfonso Crisci
Format: Article
Language:English
Published: MDPI AG 2025-03-01
Series:Plants
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Online Access:https://www.mdpi.com/2223-7747/14/6/892
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author Waed Tarraf
Tolga İzgü
Carla Benelli
Gabriele Cencetti
Marco Michelozzi
Alfonso Crisci
author_facet Waed Tarraf
Tolga İzgü
Carla Benelli
Gabriele Cencetti
Marco Michelozzi
Alfonso Crisci
author_sort Waed Tarraf
collection DOAJ
description Most fir species in the Mediterranean have small to medium-sized distributions, are often endemic and endangered, and are mainly found in relict areas, except for <i>Abies alba</i>. The IUCN Red List of Threatened Species identified <i>Abies nebrodensis</i> as the rarest conifer in the world, with only 30 adult trees remaining. Additionally, <i>Abies pinsapo</i> is threatened and limited to five fragmented locations in Spain and Morocco. This study aimed to characterize the seed terpene profiles of Mediterranean <i>Abies</i> species, such as <i>A. nebrodensis</i>, <i>A. pinsapo</i>, and <i>A. alba</i>, since morphological results showed minimal variation among the <i>Abies</i> populations examined. Terpenes were extracted using n-heptane and then analyzed by GC-MS. The chemical composition revealed the dominance of limonene and α-pinene as the main monoterpenes in all the species, while <i>A. nebrodensis</i> reported the considerable presence of germacrene D-4-ol and selina-6-en-4-ol as sesquiterpenes. The relative contents of most of the terpenes were significantly different among the species, and subsequent statistical multivariate analysis showed clear discrimination among three distinct groups. These results confirmed the suitability of the terpene profile as a potential tool to study chemotaxonomic differences between species from the same family. Moreover, the compounds identified can be interesting for further studies on plant defense against biotic stress to reduce the risk of species extinction caused by pests and diseases.
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spelling doaj-art-9844d87f0f2047bd9a1ab815a793355f2025-08-20T03:43:26ZengMDPI AGPlants2223-77472025-03-0114689210.3390/plants14060892Seed Characteristics and Terpene Variability of Mediterranean Fir Species (<i>Abies nebrodensis</i>, <i>A. pinsapo</i>, and <i>A. alba</i>)Waed Tarraf0Tolga İzgü1Carla Benelli2Gabriele Cencetti3Marco Michelozzi4Alfonso Crisci5Institute of BioEconomy (IBE), National Research Council (CNR), Via Madonna del Piano 10, 50019 Sesto Fiorentino, Florence, ItalyInstitute of BioEconomy (IBE), National Research Council (CNR), Via Madonna del Piano 10, 50019 Sesto Fiorentino, Florence, ItalyInstitute of BioEconomy (IBE), National Research Council (CNR), Via Madonna del Piano 10, 50019 Sesto Fiorentino, Florence, ItalyInstitute of Biosciences and Bioresources, National Research Council (IBBR), National Research Council (CNR), Via Madonna del Piano 10, 50019 Sesto Fiorentino, Florence, ItalyInstitute of Biosciences and Bioresources, National Research Council (IBBR), National Research Council (CNR), Via Madonna del Piano 10, 50019 Sesto Fiorentino, Florence, ItalyInstitute of BioEconomy (IBE), National Research Council (CNR), Via Madonna del Piano 10, 50019 Sesto Fiorentino, Florence, ItalyMost fir species in the Mediterranean have small to medium-sized distributions, are often endemic and endangered, and are mainly found in relict areas, except for <i>Abies alba</i>. The IUCN Red List of Threatened Species identified <i>Abies nebrodensis</i> as the rarest conifer in the world, with only 30 adult trees remaining. Additionally, <i>Abies pinsapo</i> is threatened and limited to five fragmented locations in Spain and Morocco. This study aimed to characterize the seed terpene profiles of Mediterranean <i>Abies</i> species, such as <i>A. nebrodensis</i>, <i>A. pinsapo</i>, and <i>A. alba</i>, since morphological results showed minimal variation among the <i>Abies</i> populations examined. Terpenes were extracted using n-heptane and then analyzed by GC-MS. The chemical composition revealed the dominance of limonene and α-pinene as the main monoterpenes in all the species, while <i>A. nebrodensis</i> reported the considerable presence of germacrene D-4-ol and selina-6-en-4-ol as sesquiterpenes. The relative contents of most of the terpenes were significantly different among the species, and subsequent statistical multivariate analysis showed clear discrimination among three distinct groups. These results confirmed the suitability of the terpene profile as a potential tool to study chemotaxonomic differences between species from the same family. Moreover, the compounds identified can be interesting for further studies on plant defense against biotic stress to reduce the risk of species extinction caused by pests and diseases.https://www.mdpi.com/2223-7747/14/6/892Sicilian firEuropean silver firSpanish firthreatened speciesconiferschemotaxonomic markers
spellingShingle Waed Tarraf
Tolga İzgü
Carla Benelli
Gabriele Cencetti
Marco Michelozzi
Alfonso Crisci
Seed Characteristics and Terpene Variability of Mediterranean Fir Species (<i>Abies nebrodensis</i>, <i>A. pinsapo</i>, and <i>A. alba</i>)
Plants
Sicilian fir
European silver fir
Spanish fir
threatened species
conifers
chemotaxonomic markers
title Seed Characteristics and Terpene Variability of Mediterranean Fir Species (<i>Abies nebrodensis</i>, <i>A. pinsapo</i>, and <i>A. alba</i>)
title_full Seed Characteristics and Terpene Variability of Mediterranean Fir Species (<i>Abies nebrodensis</i>, <i>A. pinsapo</i>, and <i>A. alba</i>)
title_fullStr Seed Characteristics and Terpene Variability of Mediterranean Fir Species (<i>Abies nebrodensis</i>, <i>A. pinsapo</i>, and <i>A. alba</i>)
title_full_unstemmed Seed Characteristics and Terpene Variability of Mediterranean Fir Species (<i>Abies nebrodensis</i>, <i>A. pinsapo</i>, and <i>A. alba</i>)
title_short Seed Characteristics and Terpene Variability of Mediterranean Fir Species (<i>Abies nebrodensis</i>, <i>A. pinsapo</i>, and <i>A. alba</i>)
title_sort seed characteristics and terpene variability of mediterranean fir species i abies nebrodensis i i a pinsapo i and i a alba i
topic Sicilian fir
European silver fir
Spanish fir
threatened species
conifers
chemotaxonomic markers
url https://www.mdpi.com/2223-7747/14/6/892
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