Effects of Controlling the AZO Thin Film's Optical Band Gap on AZO/MEH-PPV Devices with Buffer Layer

Organic/inorganic hybrid solar cells were fabricated incorporating aluminum-doped zinc oxide (AZO) thin films of varying optical band gap in AZO/poly(2-methoxy-5-(2′-ethyl-hexyloxy)-p-phenylene vinylene) structures. The band gaps were controlled by varying the flow rates of Ar and O2 used to deposit...

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Main Authors: Jaehyoung Park, Ki-Chang Jung, Ari Lee, Hyojung Bae, Daehwa Mun, Jun-Seok Ha, Young-Bu Mun, E. M. Han, Hang-Ju Ko
Format: Article
Language:English
Published: Wiley 2012-01-01
Series:International Journal of Photoenergy
Online Access:http://dx.doi.org/10.1155/2012/614320
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author Jaehyoung Park
Ki-Chang Jung
Ari Lee
Hyojung Bae
Daehwa Mun
Jun-Seok Ha
Young-Bu Mun
E. M. Han
Hang-Ju Ko
author_facet Jaehyoung Park
Ki-Chang Jung
Ari Lee
Hyojung Bae
Daehwa Mun
Jun-Seok Ha
Young-Bu Mun
E. M. Han
Hang-Ju Ko
author_sort Jaehyoung Park
collection DOAJ
description Organic/inorganic hybrid solar cells were fabricated incorporating aluminum-doped zinc oxide (AZO) thin films of varying optical band gap in AZO/poly(2-methoxy-5-(2′-ethyl-hexyloxy)-p-phenylene vinylene) structures. The band gaps were controlled by varying the flow rates of Ar and O2 used to deposit the AZO. Devices with CdS buffer layer were also fabricated for improved efficiency. The effects of AZO optical band gap were assessed by testing the I–V characteristics of devices with structures of glass/ITO/AZO/MEH-PPV/Ag under AM1.5 illumination (100 mW/cm2). Efficiency was improved about 30 times by decreasing the AZO optical band gap, except in devices deposited without oxygen. A power conversion efficiency of 0.102% was obtained with the incorporation of a CdS buffer layer.
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series International Journal of Photoenergy
spelling doaj-art-981bc7be041b4a35a5bbacf2408b6e162025-02-03T05:50:12ZengWileyInternational Journal of Photoenergy1110-662X1687-529X2012-01-01201210.1155/2012/614320614320Effects of Controlling the AZO Thin Film's Optical Band Gap on AZO/MEH-PPV Devices with Buffer LayerJaehyoung Park0Ki-Chang Jung1Ari Lee2Hyojung Bae3Daehwa Mun4Jun-Seok Ha5Young-Bu Mun6E. M. Han7Hang-Ju Ko8Department of Advanced Chemicals and Engineering, Chonnam National University, Gwangju 500-757, Republic of KoreaDepartment of Advanced Chemicals and Engineering, Chonnam National University, Gwangju 500-757, Republic of KoreaDepartment of Advanced Chemicals and Engineering, Chonnam National University, Gwangju 500-757, Republic of KoreaDepartment of Advanced Chemicals and Engineering, Chonnam National University, Gwangju 500-757, Republic of KoreaDepartment of Advanced Chemicals and Engineering, Chonnam National University, Gwangju 500-757, Republic of KoreaDepartment of Advanced Chemicals and Engineering, Chonnam National University, Gwangju 500-757, Republic of KoreaTHELEDS Co., Gwangju 506-253, Republic of KoreaDepartment of Advanced Chemicals and Engineering, Chonnam National University, Gwangju 500-757, Republic of KoreaPhotovoltaic and Optoelectronic Device Center, Korea Photonics Technology Institute, Gwangju 500-460, Republic of KoreaOrganic/inorganic hybrid solar cells were fabricated incorporating aluminum-doped zinc oxide (AZO) thin films of varying optical band gap in AZO/poly(2-methoxy-5-(2′-ethyl-hexyloxy)-p-phenylene vinylene) structures. The band gaps were controlled by varying the flow rates of Ar and O2 used to deposit the AZO. Devices with CdS buffer layer were also fabricated for improved efficiency. The effects of AZO optical band gap were assessed by testing the I–V characteristics of devices with structures of glass/ITO/AZO/MEH-PPV/Ag under AM1.5 illumination (100 mW/cm2). Efficiency was improved about 30 times by decreasing the AZO optical band gap, except in devices deposited without oxygen. A power conversion efficiency of 0.102% was obtained with the incorporation of a CdS buffer layer.http://dx.doi.org/10.1155/2012/614320
spellingShingle Jaehyoung Park
Ki-Chang Jung
Ari Lee
Hyojung Bae
Daehwa Mun
Jun-Seok Ha
Young-Bu Mun
E. M. Han
Hang-Ju Ko
Effects of Controlling the AZO Thin Film's Optical Band Gap on AZO/MEH-PPV Devices with Buffer Layer
International Journal of Photoenergy
title Effects of Controlling the AZO Thin Film's Optical Band Gap on AZO/MEH-PPV Devices with Buffer Layer
title_full Effects of Controlling the AZO Thin Film's Optical Band Gap on AZO/MEH-PPV Devices with Buffer Layer
title_fullStr Effects of Controlling the AZO Thin Film's Optical Band Gap on AZO/MEH-PPV Devices with Buffer Layer
title_full_unstemmed Effects of Controlling the AZO Thin Film's Optical Band Gap on AZO/MEH-PPV Devices with Buffer Layer
title_short Effects of Controlling the AZO Thin Film's Optical Band Gap on AZO/MEH-PPV Devices with Buffer Layer
title_sort effects of controlling the azo thin film s optical band gap on azo meh ppv devices with buffer layer
url http://dx.doi.org/10.1155/2012/614320
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