Fabrication and Characterization of Nickel Chloride Doped PMMA Films

Films of PMMA and PMMA doped with NiCl2 with different contents were prepared using the casting technique. The optical properties of all films were investigated using spectrophotometric measurements of absorbance and transmittance in the wavelength range 200–800 nm. The change of the calculated valu...

Full description

Saved in:
Bibliographic Details
Main Authors: Wasan A. Al-Taa’y, Saad F. Oboudi, Emad Yousif, Mohammed Abdul Nabi, Rahimi M. Yusop, Darfizzi Derawi
Format: Article
Language:English
Published: Wiley 2015-01-01
Series:Advances in Materials Science and Engineering
Online Access:http://dx.doi.org/10.1155/2015/913260
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1832545385587933184
author Wasan A. Al-Taa’y
Saad F. Oboudi
Emad Yousif
Mohammed Abdul Nabi
Rahimi M. Yusop
Darfizzi Derawi
author_facet Wasan A. Al-Taa’y
Saad F. Oboudi
Emad Yousif
Mohammed Abdul Nabi
Rahimi M. Yusop
Darfizzi Derawi
author_sort Wasan A. Al-Taa’y
collection DOAJ
description Films of PMMA and PMMA doped with NiCl2 with different contents were prepared using the casting technique. The optical properties of all films were investigated using spectrophotometric measurements of absorbance and transmittance in the wavelength range 200–800 nm. The change of the calculated values of the optical energy gaps with increasing NiCl2 content has been interpreted in terms of the structural modifications of the PMMA matrix. The optical energy gap decreased from 3.6 to 3.05 eV with increasing the NiCl2 concentration to 0.4%. The effect of doping on the optical constants of films such as refractive index, extinction coefficient, real and imaginary parts of dielectric constant, optical conductivity, and skin depth has been reported. All these constants were increased with increasing NiCl2 concentration with the exception of skin depth which is different result.
format Article
id doaj-art-980e5cc8bb5c476d818724d739650666
institution Kabale University
issn 1687-8434
1687-8442
language English
publishDate 2015-01-01
publisher Wiley
record_format Article
series Advances in Materials Science and Engineering
spelling doaj-art-980e5cc8bb5c476d818724d7396506662025-02-03T07:25:55ZengWileyAdvances in Materials Science and Engineering1687-84341687-84422015-01-01201510.1155/2015/913260913260Fabrication and Characterization of Nickel Chloride Doped PMMA FilmsWasan A. Al-Taa’y0Saad F. Oboudi1Emad Yousif2Mohammed Abdul Nabi3Rahimi M. Yusop4Darfizzi Derawi5Department of Physics, College of Science, Al-Nahrain University, Baghdad, IraqDepartment of Physics, College of Science, Baghdad University, Baghdad, IraqDepartment of Chemistry, College of Science, Al-Nahrain University, Baghdad, IraqDepartment of Physics, College of Science, Al-Nahrain University, Baghdad, IraqSchool of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor, MalaysiaSchool of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor, MalaysiaFilms of PMMA and PMMA doped with NiCl2 with different contents were prepared using the casting technique. The optical properties of all films were investigated using spectrophotometric measurements of absorbance and transmittance in the wavelength range 200–800 nm. The change of the calculated values of the optical energy gaps with increasing NiCl2 content has been interpreted in terms of the structural modifications of the PMMA matrix. The optical energy gap decreased from 3.6 to 3.05 eV with increasing the NiCl2 concentration to 0.4%. The effect of doping on the optical constants of films such as refractive index, extinction coefficient, real and imaginary parts of dielectric constant, optical conductivity, and skin depth has been reported. All these constants were increased with increasing NiCl2 concentration with the exception of skin depth which is different result.http://dx.doi.org/10.1155/2015/913260
spellingShingle Wasan A. Al-Taa’y
Saad F. Oboudi
Emad Yousif
Mohammed Abdul Nabi
Rahimi M. Yusop
Darfizzi Derawi
Fabrication and Characterization of Nickel Chloride Doped PMMA Films
Advances in Materials Science and Engineering
title Fabrication and Characterization of Nickel Chloride Doped PMMA Films
title_full Fabrication and Characterization of Nickel Chloride Doped PMMA Films
title_fullStr Fabrication and Characterization of Nickel Chloride Doped PMMA Films
title_full_unstemmed Fabrication and Characterization of Nickel Chloride Doped PMMA Films
title_short Fabrication and Characterization of Nickel Chloride Doped PMMA Films
title_sort fabrication and characterization of nickel chloride doped pmma films
url http://dx.doi.org/10.1155/2015/913260
work_keys_str_mv AT wasanaaltaay fabricationandcharacterizationofnickelchloridedopedpmmafilms
AT saadfoboudi fabricationandcharacterizationofnickelchloridedopedpmmafilms
AT emadyousif fabricationandcharacterizationofnickelchloridedopedpmmafilms
AT mohammedabdulnabi fabricationandcharacterizationofnickelchloridedopedpmmafilms
AT rahimimyusop fabricationandcharacterizationofnickelchloridedopedpmmafilms
AT darfizziderawi fabricationandcharacterizationofnickelchloridedopedpmmafilms