Fermi contact couplings in fluoroalkylsubstituted -radicals. Relay charge effect of luмо and homo and its quantum chemical modeling by means of indo calculations
The new interpretation of physical phenomenon in EPR spectra of fluoroalkyl n-radicals was made. We named this phenomenon the relay charge effect of fluorine hyperfine coupling (RCE-F). The sharp relationship of Fermi contact spin density on 19F nucleus and the radical charge was found out. The orbi...
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MIREA - Russian Technological University
2007-10-01
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| Series: | Тонкие химические технологии |
| Online Access: | https://www.finechem-mirea.ru/jour/article/view/1338 |
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| author | D. M. Smekalkin B. K. Novosadov E. A. Polenov |
| author_facet | D. M. Smekalkin B. K. Novosadov E. A. Polenov |
| author_sort | D. M. Smekalkin |
| collection | DOAJ |
| description | The new interpretation of physical phenomenon in EPR spectra of fluoroalkyl n-radicals was made. We named this phenomenon the relay charge effect of fluorine hyperfine coupling (RCE-F). The sharp relationship of Fermi contact spin density on 19F nucleus and the radical charge was found out. The orbital origin of current effect was investigated. |
| format | Article |
| id | doaj-art-9802e4e65e7d4149981d00665f279e63 |
| institution | Kabale University |
| issn | 2410-6593 2686-7575 |
| language | Russian |
| publishDate | 2007-10-01 |
| publisher | MIREA - Russian Technological University |
| record_format | Article |
| series | Тонкие химические технологии |
| spelling | doaj-art-9802e4e65e7d4149981d00665f279e632025-08-20T03:56:23ZrusMIREA - Russian Technological UniversityТонкие химические технологии2410-65932686-75752007-10-012521271333Fermi contact couplings in fluoroalkylsubstituted -radicals. Relay charge effect of luмо and homo and its quantum chemical modeling by means of indo calculationsD. M. Smekalkin0B. K. Novosadov1E. A. Polenov2M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571МГУ им. М.В. ЛомоносоваM.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571The new interpretation of physical phenomenon in EPR spectra of fluoroalkyl n-radicals was made. We named this phenomenon the relay charge effect of fluorine hyperfine coupling (RCE-F). The sharp relationship of Fermi contact spin density on 19F nucleus and the radical charge was found out. The orbital origin of current effect was investigated.https://www.finechem-mirea.ru/jour/article/view/1338 |
| spellingShingle | D. M. Smekalkin B. K. Novosadov E. A. Polenov Fermi contact couplings in fluoroalkylsubstituted -radicals. Relay charge effect of luмо and homo and its quantum chemical modeling by means of indo calculations Тонкие химические технологии |
| title | Fermi contact couplings in fluoroalkylsubstituted -radicals. Relay charge effect of luмо and homo and its quantum chemical modeling by means of indo calculations |
| title_full | Fermi contact couplings in fluoroalkylsubstituted -radicals. Relay charge effect of luмо and homo and its quantum chemical modeling by means of indo calculations |
| title_fullStr | Fermi contact couplings in fluoroalkylsubstituted -radicals. Relay charge effect of luмо and homo and its quantum chemical modeling by means of indo calculations |
| title_full_unstemmed | Fermi contact couplings in fluoroalkylsubstituted -radicals. Relay charge effect of luмо and homo and its quantum chemical modeling by means of indo calculations |
| title_short | Fermi contact couplings in fluoroalkylsubstituted -radicals. Relay charge effect of luмо and homo and its quantum chemical modeling by means of indo calculations |
| title_sort | fermi contact couplings in fluoroalkylsubstituted radicals relay charge effect of luмо and homo and its quantum chemical modeling by means of indo calculations |
| url | https://www.finechem-mirea.ru/jour/article/view/1338 |
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