Synergistic effects of Psidium guajava and copper nanoparticles reinforced hybrid Hydrogel for tissue engineering

Hydrogels are biopolymers proficient in engrossing much water in their 3D network structure. However, single-polymer hydrogels frequently experience poor physio-mechanical properties, confining their border applications. The present work concentrated on developing chemically crosslinked hydrogels us...

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Main Authors: D.V. Krishna, M.R. Sankar, P.V.G.K. Sarma, E.L. Samundeshwari
Format: Article
Language:English
Published: KeAi Communications Co., Ltd. 2025-04-01
Series:Advanced Industrial and Engineering Polymer Research
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Online Access:http://www.sciencedirect.com/science/article/pii/S2542504824000423
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author D.V. Krishna
M.R. Sankar
P.V.G.K. Sarma
E.L. Samundeshwari
author_facet D.V. Krishna
M.R. Sankar
P.V.G.K. Sarma
E.L. Samundeshwari
author_sort D.V. Krishna
collection DOAJ
description Hydrogels are biopolymers proficient in engrossing much water in their 3D network structure. However, single-polymer hydrogels frequently experience poor physio-mechanical properties, confining their border applications. The present work concentrated on developing chemically crosslinked hydrogels using the terpolymerization of gelatin (GEL), guar gum (GGM), and polyvinyl alcohol (PVA). Ethanolic extract of Psidium guajava leaf (EPG) and copper nanoparticles (CuNPs) were added to enhance the biomechanical properties of the developed hydrogels. Hydrogels' viscoelastic, mechanical, swelling, and cytotoxicity properties were assessed. All the hydrogels exhibited a porous-like structure with a swelling index of 230–280 %. A compressive strength of 5 MPa with splendid chondrocyte viability was noticed in the hydrogels comprised of EPG and CuNPs. The multiple interactions among the polymer chains impart better frequency and shear strain-dependent behavior. The time-dependent frictional behavior of hydrogel under the lubrication of artificial synovial fluid reveals the decreased coefficient of friction over time. The performance of the hybrid hydrogel enhanced with EPG and CuNPs was superior, making it a promising material for tissue engineering applications.
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issn 2542-5048
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publishDate 2025-04-01
publisher KeAi Communications Co., Ltd.
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series Advanced Industrial and Engineering Polymer Research
spelling doaj-art-97e502309ace4e1e92ff1117d0effeaa2025-08-20T02:24:59ZengKeAi Communications Co., Ltd.Advanced Industrial and Engineering Polymer Research2542-50482025-04-018226427810.1016/j.aiepr.2024.10.001Synergistic effects of Psidium guajava and copper nanoparticles reinforced hybrid Hydrogel for tissue engineeringD.V. Krishna0M.R. Sankar1P.V.G.K. Sarma2E.L. Samundeshwari3Department of Mechanical Engineering, Indian Institute of Technology Tirupati, 517619, Andhra Pradesh, IndiaDepartment of Mechanical Engineering, Indian Institute of Technology Tirupati, 517619, Andhra Pradesh, India; Corresponding author.Department of Biotechnology, Sri Venkateswara Institute of Medical Sciences Tirupati, 517501, Andhra Pradesh, IndiaDepartment of Biotechnology, Sri Venkateswara Institute of Medical Sciences Tirupati, 517501, Andhra Pradesh, IndiaHydrogels are biopolymers proficient in engrossing much water in their 3D network structure. However, single-polymer hydrogels frequently experience poor physio-mechanical properties, confining their border applications. The present work concentrated on developing chemically crosslinked hydrogels using the terpolymerization of gelatin (GEL), guar gum (GGM), and polyvinyl alcohol (PVA). Ethanolic extract of Psidium guajava leaf (EPG) and copper nanoparticles (CuNPs) were added to enhance the biomechanical properties of the developed hydrogels. Hydrogels' viscoelastic, mechanical, swelling, and cytotoxicity properties were assessed. All the hydrogels exhibited a porous-like structure with a swelling index of 230–280 %. A compressive strength of 5 MPa with splendid chondrocyte viability was noticed in the hydrogels comprised of EPG and CuNPs. The multiple interactions among the polymer chains impart better frequency and shear strain-dependent behavior. The time-dependent frictional behavior of hydrogel under the lubrication of artificial synovial fluid reveals the decreased coefficient of friction over time. The performance of the hybrid hydrogel enhanced with EPG and CuNPs was superior, making it a promising material for tissue engineering applications.http://www.sciencedirect.com/science/article/pii/S2542504824000423GelatinGuava leafTissue engineeringHydrogel
spellingShingle D.V. Krishna
M.R. Sankar
P.V.G.K. Sarma
E.L. Samundeshwari
Synergistic effects of Psidium guajava and copper nanoparticles reinforced hybrid Hydrogel for tissue engineering
Advanced Industrial and Engineering Polymer Research
Gelatin
Guava leaf
Tissue engineering
Hydrogel
title Synergistic effects of Psidium guajava and copper nanoparticles reinforced hybrid Hydrogel for tissue engineering
title_full Synergistic effects of Psidium guajava and copper nanoparticles reinforced hybrid Hydrogel for tissue engineering
title_fullStr Synergistic effects of Psidium guajava and copper nanoparticles reinforced hybrid Hydrogel for tissue engineering
title_full_unstemmed Synergistic effects of Psidium guajava and copper nanoparticles reinforced hybrid Hydrogel for tissue engineering
title_short Synergistic effects of Psidium guajava and copper nanoparticles reinforced hybrid Hydrogel for tissue engineering
title_sort synergistic effects of psidium guajava and copper nanoparticles reinforced hybrid hydrogel for tissue engineering
topic Gelatin
Guava leaf
Tissue engineering
Hydrogel
url http://www.sciencedirect.com/science/article/pii/S2542504824000423
work_keys_str_mv AT dvkrishna synergisticeffectsofpsidiumguajavaandcoppernanoparticlesreinforcedhybridhydrogelfortissueengineering
AT mrsankar synergisticeffectsofpsidiumguajavaandcoppernanoparticlesreinforcedhybridhydrogelfortissueengineering
AT pvgksarma synergisticeffectsofpsidiumguajavaandcoppernanoparticlesreinforcedhybridhydrogelfortissueengineering
AT elsamundeshwari synergisticeffectsofpsidiumguajavaandcoppernanoparticlesreinforcedhybridhydrogelfortissueengineering