Synthesis Methods, Performance Optimization, and Application Progress of Metal–Organic Framework Material MIL-101(Cr)
MIL-101(Cr), a widely studied chromium-based metal–organic framework material consisting of chromium metal ions and terephthalic acid ligands, has attracted much attention due to its ultra-high specific surface area, large pore size, and excellent thermal, chemical, and aqueous stability. The outsta...
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| Format: | Article |
| Language: | English |
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MDPI AG
2025-05-01
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| Series: | Chemistry |
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| Online Access: | https://www.mdpi.com/2624-8549/7/3/78 |
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| author | Jiayao Chen Min Tang Saiqun Nie Pengcheng Xiao Tian Zhao Yi Chen |
| author_facet | Jiayao Chen Min Tang Saiqun Nie Pengcheng Xiao Tian Zhao Yi Chen |
| author_sort | Jiayao Chen |
| collection | DOAJ |
| description | MIL-101(Cr), a widely studied chromium-based metal–organic framework material consisting of chromium metal ions and terephthalic acid ligands, has attracted much attention due to its ultra-high specific surface area, large pore size, and excellent thermal, chemical, and aqueous stability. The outstanding properties and abundant unsaturated Lewis acid sites of this material have shown promising applications in aqueous phase adsorption, gas storage, separation, catalysis, drug delivery, and sensing. In this paper, we systematically review the synthesis technology and performance optimization strategy of MIL-101(Cr), discuss the advantages and limitations of various synthesis methods, such as traditional hydrothermal method, microwave-assisted hydrothermal method, template method, and solvent-thermal method, and summarize and analyze the optimization strategy of MIL-101 from the aspects of physical modification and chemical modification. In addition, this paper summarizes the latest application progress of MIL-101(Cr) in gas adsorption and separation, wastewater purification, pollutant removal, catalysis, and pharmaceutical delivery, and points out the current challenges and future development directions, to provide guidance and inspiration for the industrial application of MIL-101(Cr) and the development of new materials. |
| format | Article |
| id | doaj-art-96aa06f28b2c48a5b98b2a5b9db2e1f7 |
| institution | OA Journals |
| issn | 2624-8549 |
| language | English |
| publishDate | 2025-05-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Chemistry |
| spelling | doaj-art-96aa06f28b2c48a5b98b2a5b9db2e1f72025-08-20T02:24:19ZengMDPI AGChemistry2624-85492025-05-01737810.3390/chemistry7030078Synthesis Methods, Performance Optimization, and Application Progress of Metal–Organic Framework Material MIL-101(Cr)Jiayao Chen0Min Tang1Saiqun Nie2Pengcheng Xiao3Tian Zhao4Yi Chen5School of Packaging and Material Engineering, Hunan University of Technology, Zhuzhou 412007, ChinaSchool of Packaging and Material Engineering, Hunan University of Technology, Zhuzhou 412007, ChinaSchool of Packaging and Material Engineering, Hunan University of Technology, Zhuzhou 412007, ChinaSchool of Packaging and Material Engineering, Hunan University of Technology, Zhuzhou 412007, ChinaSchool of Packaging and Material Engineering, Hunan University of Technology, Zhuzhou 412007, ChinaSchool of Packaging and Material Engineering, Hunan University of Technology, Zhuzhou 412007, ChinaMIL-101(Cr), a widely studied chromium-based metal–organic framework material consisting of chromium metal ions and terephthalic acid ligands, has attracted much attention due to its ultra-high specific surface area, large pore size, and excellent thermal, chemical, and aqueous stability. The outstanding properties and abundant unsaturated Lewis acid sites of this material have shown promising applications in aqueous phase adsorption, gas storage, separation, catalysis, drug delivery, and sensing. In this paper, we systematically review the synthesis technology and performance optimization strategy of MIL-101(Cr), discuss the advantages and limitations of various synthesis methods, such as traditional hydrothermal method, microwave-assisted hydrothermal method, template method, and solvent-thermal method, and summarize and analyze the optimization strategy of MIL-101 from the aspects of physical modification and chemical modification. In addition, this paper summarizes the latest application progress of MIL-101(Cr) in gas adsorption and separation, wastewater purification, pollutant removal, catalysis, and pharmaceutical delivery, and points out the current challenges and future development directions, to provide guidance and inspiration for the industrial application of MIL-101(Cr) and the development of new materials.https://www.mdpi.com/2624-8549/7/3/78MIL-101(Cr)synthesis methodsoptimization strategiesapplication advances |
| spellingShingle | Jiayao Chen Min Tang Saiqun Nie Pengcheng Xiao Tian Zhao Yi Chen Synthesis Methods, Performance Optimization, and Application Progress of Metal–Organic Framework Material MIL-101(Cr) Chemistry MIL-101(Cr) synthesis methods optimization strategies application advances |
| title | Synthesis Methods, Performance Optimization, and Application Progress of Metal–Organic Framework Material MIL-101(Cr) |
| title_full | Synthesis Methods, Performance Optimization, and Application Progress of Metal–Organic Framework Material MIL-101(Cr) |
| title_fullStr | Synthesis Methods, Performance Optimization, and Application Progress of Metal–Organic Framework Material MIL-101(Cr) |
| title_full_unstemmed | Synthesis Methods, Performance Optimization, and Application Progress of Metal–Organic Framework Material MIL-101(Cr) |
| title_short | Synthesis Methods, Performance Optimization, and Application Progress of Metal–Organic Framework Material MIL-101(Cr) |
| title_sort | synthesis methods performance optimization and application progress of metal organic framework material mil 101 cr |
| topic | MIL-101(Cr) synthesis methods optimization strategies application advances |
| url | https://www.mdpi.com/2624-8549/7/3/78 |
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