Method development and application for the analysis of chiral organic marker species in ice cores
<p>Glaciers are valuable environmental archives that preserve organic compounds from atmospheric aerosols that can be used as marker species for their respective emission sources. Most environmental studies do not distinguish between the enantiomers of chiral compounds, although these compound...
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Copernicus Publications
2025-01-01
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| Series: | Atmospheric Measurement Techniques |
| Online Access: | https://amt.copernicus.org/articles/18/421/2025/amt-18-421-2025.pdf |
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| author | J. Schäfer A. Beschnitt F. Burgay F. Burgay T. Singer T. Singer T. Singer M. Schwikowski M. Schwikowski M. Schwikowski T. Hoffmann |
| author_facet | J. Schäfer A. Beschnitt F. Burgay F. Burgay T. Singer T. Singer T. Singer M. Schwikowski M. Schwikowski M. Schwikowski T. Hoffmann |
| author_sort | J. Schäfer |
| collection | DOAJ |
| description | <p>Glaciers are valuable environmental archives that preserve organic compounds from atmospheric aerosols that can be used as marker species for their respective emission sources. Most environmental studies do not distinguish between the enantiomers of chiral compounds, although these compounds, mostly from biogenic sources, are very common in the atmosphere. We have developed a two-dimensional (2D) liquid chromatography (mLC–LC) method that allows the simultaneous determination of the chiral ratios of the monoterpene oxidation products <i>cis</i>-pinic acid and <i>cis</i>-pinonic acid in ice-core samples. The method combines a reversed-phase column in the first dimension and a chiral column in the second dimension in a simple instrumental setup with only one additional six-port valve. This novel method was successfully applied to selected ice-core samples from the Belukha Glacier in the Siberian Altai spread over the period 1870–1970 CE. The chiral ratio of <i>cis</i>-pinic acid showed fluctuating values, while the chiral ratio of <i>cis</i>-pinonic acid remained more constant with an excess of the (<span class="inline-formula">−</span>)-enantiomer.</p> |
| format | Article |
| id | doaj-art-961d6decd61e4da1a8ecf11e8ecfbc04 |
| institution | Kabale University |
| issn | 1867-1381 1867-8548 |
| language | English |
| publishDate | 2025-01-01 |
| publisher | Copernicus Publications |
| record_format | Article |
| series | Atmospheric Measurement Techniques |
| spelling | doaj-art-961d6decd61e4da1a8ecf11e8ecfbc042025-01-24T15:50:21ZengCopernicus PublicationsAtmospheric Measurement Techniques1867-13811867-85482025-01-011842143010.5194/amt-18-421-2025Method development and application for the analysis of chiral organic marker species in ice coresJ. Schäfer0A. Beschnitt1F. Burgay2F. Burgay3T. Singer4T. Singer5T. Singer6M. Schwikowski7M. Schwikowski8M. Schwikowski9T. Hoffmann10Department of Chemistry, Johannes Gutenberg University Mainz, 55099 Mainz, GermanyDepartment of Chemistry, Johannes Gutenberg University Mainz, 55099 Mainz, GermanyLaboratory of Environmental Chemistry (LUC), Paul Scherrer Institute, 5232 Villigen PSI, SwitzerlandOeschger Centre for Climate Change Research, University of Bern, 3012 Bern, SwitzerlandLaboratory of Environmental Chemistry (LUC), Paul Scherrer Institute, 5232 Villigen PSI, SwitzerlandOeschger Centre for Climate Change Research, University of Bern, 3012 Bern, SwitzerlandDepartment of Chemistry, Biochemistry and Pharmaceutical Sciences, University of Bern, 3012 Bern, SwitzerlandLaboratory of Environmental Chemistry (LUC), Paul Scherrer Institute, 5232 Villigen PSI, SwitzerlandOeschger Centre for Climate Change Research, University of Bern, 3012 Bern, SwitzerlandDepartment of Chemistry, Biochemistry and Pharmaceutical Sciences, University of Bern, 3012 Bern, SwitzerlandDepartment of Chemistry, Johannes Gutenberg University Mainz, 55099 Mainz, Germany<p>Glaciers are valuable environmental archives that preserve organic compounds from atmospheric aerosols that can be used as marker species for their respective emission sources. Most environmental studies do not distinguish between the enantiomers of chiral compounds, although these compounds, mostly from biogenic sources, are very common in the atmosphere. We have developed a two-dimensional (2D) liquid chromatography (mLC–LC) method that allows the simultaneous determination of the chiral ratios of the monoterpene oxidation products <i>cis</i>-pinic acid and <i>cis</i>-pinonic acid in ice-core samples. The method combines a reversed-phase column in the first dimension and a chiral column in the second dimension in a simple instrumental setup with only one additional six-port valve. This novel method was successfully applied to selected ice-core samples from the Belukha Glacier in the Siberian Altai spread over the period 1870–1970 CE. The chiral ratio of <i>cis</i>-pinic acid showed fluctuating values, while the chiral ratio of <i>cis</i>-pinonic acid remained more constant with an excess of the (<span class="inline-formula">−</span>)-enantiomer.</p>https://amt.copernicus.org/articles/18/421/2025/amt-18-421-2025.pdf |
| spellingShingle | J. Schäfer A. Beschnitt F. Burgay F. Burgay T. Singer T. Singer T. Singer M. Schwikowski M. Schwikowski M. Schwikowski T. Hoffmann Method development and application for the analysis of chiral organic marker species in ice cores Atmospheric Measurement Techniques |
| title | Method development and application for the analysis of chiral organic marker species in ice cores |
| title_full | Method development and application for the analysis of chiral organic marker species in ice cores |
| title_fullStr | Method development and application for the analysis of chiral organic marker species in ice cores |
| title_full_unstemmed | Method development and application for the analysis of chiral organic marker species in ice cores |
| title_short | Method development and application for the analysis of chiral organic marker species in ice cores |
| title_sort | method development and application for the analysis of chiral organic marker species in ice cores |
| url | https://amt.copernicus.org/articles/18/421/2025/amt-18-421-2025.pdf |
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